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:2008-03-11:(1984-),,,,.:1004-4280(2008)02-0030-05李宜娟,李彦春(,250353):,-,-,,,。:;;:X506 :ATheresearchdevelopmentinnewprocessesofammonia-nitrogenwastewaterbiologicaltreatmentLIYi-juan,LIYan-chun(SchoolofLightChemistryandEnvironmentEngineering,ShandongInstituteofLightIndustry,Jinan250353,China)Abstract:Thispaperintroducessomebiologicalprocessestoremoveammonia-nitrogeninwatersimply,in-cludingSHARON,SND,ANAMMOXandSHARON-ANAMMOX.Thecharacteristicsoftheseprocessesandtheirdevelopmentsarealsointroducedinbrief.Keywords:ammonia-nitrogen;biologicaltreatment;newtechnology0 ,,,。,、,,,,,。,,。、,。、、。、、、、A/OA2/O。:,,;;。。。1 -(SHARON):NH+4※NO-2※NO-3※NO-2※N2,,,,22 22008 6 JOURNALOFSHANDONGINSTITUTEOFLIGHTINDUSTRYVol.22 No.2June. 2008,,NO-3、NO-2。,,[1,2]:(1),;(2),,;(3)25%,;(4)40%,C/N;(5),,50%。1975Voct[3]HNO2—。HNO2,;Delft,,NO-2SHARON。,,[4];KHaniki[5](pH),(NH2OH);Jetten[6],,,,;[7]SBR,,、;[8]SBR,SBR,1.401.86,60min25min;[9]A/O,pH、、、,,。2 (SND),。,、、,,、。。SND,[10,11]:(1)。,,/。,。(2)。/,。(3)。,,SND,。,。,SND/。SND,,。,、,。,NH+4,。SND:(1);(2);(3)。。HyungSeokYoo[12],,/SND,;[13],,pH8.2,30℃;[14],C/N、,NO-2,C/N;[15]SND,(C:N:P)(60～140):5:1;[16]C/NDO,,312,:CODCr、NH3-N244～500mg/L4514～5212mg/L、DO=1.0～3.0mg/L、CODCr/NH3-N=5～10,CODCr、NH3-N87.1%～91.0%、75.1%～94.7%;[17]DO、,DO0.5mg/L,,。3 (ANAMMOX)ANAMMOX,,。,,。1977Broda[18]、;1995Mulder[19],,;1996Graaf[20];Schmidt[21](NO2);1997,StraousM[22]ANAMMOX,82%99%;[23]SBR,,pH7.55,31℃;[24]、pH,,pH30～35℃,pH7.5～8.3;[25]pH,pH,,,pH30℃7.80。,:、、,,,。,NO-2。4 ,,,0.1mg/L,,[26]。2080,。,,,。,。,。2,2,3,5。,,0.67NmolN2/NmolNH3,0.4,[26]。Muller[27]。,0.30kPa,58%。,;[28]SBR,DO0.4mg/L0.5mg/L,,,;[29],,,0.5mg/L,66.0%;[30],,:、;[31]SBR(BAF),,CODCr。,CODCr,15℃,210mg/L。32 225 SHARON-ANAMMOXKlemedtsson[32]SHARON-ANAMMOX,56%～38%,,8%。Jettern[33]SHARON-ANAMMOX。SHARONANAMMOX,NO-2ANAMMOXNO-2,NH+4。NH+4-N83%。[34],—,NH+4/NO-2。[35]SHARON-ANAMMOX,,。,SHARONANAMMOX:4165KgO2/KgN,4～5KgCODCr/KgN;117KgO2/KgN,。6 ,:(1),,,;(2)SND,,,,;(3),,CO2;(4),,SND,。SHARON,。SHARON,;,、SND。,,。,。,,,。:[1] ,,,.[J].,2001,17(5):24-28.[2] ,,,.-[J].,2000,16(2):29-31.[3] ,.[J].,2001,16(4):38-39.[4] HellingaC,etal.TheSHARONprocess:aninnovativemethodforni-trogenremovalfromammoniumrichwastewater[J].Wat.Sci.Tech.,1998,37(9):135-142.[5] HanikiK,etal.NitificationatLowLevelofDissolvedOxygenwithandwithoutOrganicLoadinginaSuspendedGrowthReactor[J].Wat.Res.,1990,24(3):297-302.[6] YangL,AllemanJE.InvestigationofBatchwiseNitriteBuild-upbyanEnrichedNitirficationCulture[J].Wat.Sci.Tech.,1992,26(5-6):997-1005.[7] ,,,.DO[J].,2004,20(5):13-16.[8] ,,,.SBR[J].,2004,20(6):9-11.[9] ,,,.A/O()[J].,2006,26(5):703-709.[10] JettenMS.M.,StrousM.etal..Theanaerobicoxidationofammo-nium.FEMSMicrobiol.Rev.,1999,(2):421-437.[11] ,,.[J].,1998,24(12):6-9.[12] HyungSeokYoo,etal.Nitrogenremovalfromsyntheticwastewaterbysimultaneousnitrificationanddenitrification(SND)vianitriteinanintermittentlyaeratedreactor[J].WaterResearch,1999,33(1):145-154.[13] ,,,.[J].,2000,18(5):17-19.[14] ,.COD/NH4-N[J].,2000,22(1):18-21.[15] ,,,./(SND)[J].,2001,19(4):17-20.[16] ,,,.SBR[J].,2005,23(4):29-32.[17] ,,,.[J].,2005,33(11):1-5.[18] ,,Jetten,.ANAMMOX[J].,1998,18(4):367-372.332,:[19] MulderA,etal.AnaerobicAmmoniumOxidationDiscoveredinaDenitrifyingFluidizedBedReactor[J].FEMSMicrobiolEcol,1995,(16):177-184.[20] GraafAA,etal.AutotrophicgrouwthofAnaerobicAmmonium-OxidizingMicroorganismsinaFluidizedBedReactor[J].Microbiolo-gy,1996,(142):2187-2196.[21] SchmidtIngo,BockEberhard.AnaerobicAmmoniaOxidationwithNitrogenDioxidebyNitrosomonasEutropha[J].ArchMicrobiol,1997,(167):106-111.[22] StraousM,etal.Ammoniumremovalfromconcentratedwastestreamswiththeanaerobicammoniumoxidation(ANAMMOX)processindif-ferentreactorconfigurations[J].WaterResearch,1997,31(8):1955-1962.[23] ,.[J].,2006,32(9):30-33.[24] ,,,.、pH[J].,2006,27(4):691-695.[25] ,,,.pH[J].,2006,24(3):5-8.[26] ,.[J].,2003,29(1):17-19.[27] MullerEB,etal.SimultaneousNHOxidationandNProductionatReducedO2TensionsbySewageSludgeSubculturedwithChemolithotrophicMedium[J].Biodegradation,1995,(6):339-349.[28] ,,,.[J].,2000,26(4):17-20.[29] .[J].,2004,23(2):70-74.[30] ,,,.[J].,2006,15(5):905-908.[31] ,.SBR-BAF[J].,2006,24(5):10-11.[32] KLENEDTSSON。AutotrophicAmmoniumOxidizingBacteriainSwedishMorHumus[J].SoilBiologyandBiochemistry,1999,31:839-847.[33] JettenMSM,HornSJ,VanloosdrechtMCM.Wat.Sci.Tech,1997,35(9):171-180.[34] ,,,.-[J].,2006,22(15):40-43.[35] ,,,.-[J].,2005,24(5):34-37.(10)2.3 DSCDSC3。3 PEGTg1(600)2(2000)3(6000)4(10000)5(20000)Tg(℃)2.621.840.570.36-13.8 3PEG,。PEG,-OH,-COOH,,Tg。2.4 PEGAA,,PEGAA0.5%,;,。,,,,;,,,,。2.5 ,,,5h,。,,,。:[1] PJ.Flory,PrinciplesofPolymerChemistry[M],CornellUniversityPress,Ithaca,NewYork,1953.[2] H.C.Chiu,A.T.Wu,YF.Lin,Synthesisandcharacterizationofacrylicacid-containingdextranhydrogels,Polymer[J],2001,42(4):1471-1479.[3] X.Z.Zhang,D.Q.Wu,C.C.Chu,Synthesis,characterizationandcontrolleddrugreleaseofthermosensitiveIPN-PNIPAAmhydro-gels,Biomaterials[J]2004,25(17):3793-3805.[4] ,.,[J].1995,4(1):205-212.[5] J.Han,Z.J.Liu,Studiesonphasetransitionprocessesofradiationsynthesizedhydrogels,Radi