白腐菌处理染料废水影响因素的研究刘学艳

4642009　8DYESTUFFS　AND　COLORATIONVol.46　No.4August　2009　　:(1981—),,,,。[e-mail].　　　(河南农业大学生命科学学院,郑州　450002):白腐菌合成的木质素降解酶系对多种有机污染物都有很强的降解能力,因此在工业废水处理方面具有广泛的应用。本文介绍了黄孢原毛平革菌的降解机制和它在处理染料废水方面的研究,并探讨了它的应用前景。:黄孢原毛平革菌;木质素过氧化物酶;锰过氧化物酶;染料废水:X78　　　:A　　　:1672-1179(2009)04-057-3　　。(Phanerochaetechrysosporium)。,,。,。、,。,。1,,(、)[1,2],:、、。,3,(LigninPeroxidase,LiP)、(ManganesePeroxidase,MnP)(Laccase,Lac),。,LiPMnP。,[3],。,,H2O2(LiPMnP),,,、[4]。2,,,,、、。、、COD、,[5]。,,。2.1,。,,,;,,,。Cripps[6],LiP,,,。,。Pellinen[7],10g/L,COD50%,2g/L,,。Spadaro[8]14C,。2.2pH·57·Vol.46　No.4　DYESTUFFSANDCOLORATION464,25～45℃,,,,50℃。Ollikka[9]LiP,pH2.5～4.5。[10]LiPMnP,1L16ULiP21UMnP。pH,。COD。2.3。,,()。,。()。。,。,,。[11]。1990Cripps()[6]。PastiLiPMnP22,[11]。[12]:、、、。,;(1g/L),,90%。,H2O2。2.42.4.1。Asther[13]CNBr-LiP。[14]:,。,,7,,。2.4.2、、、、、、、。[15],,,,。[16],,,。[17],、、、、,[18]。[19],-。[20],。2.5,。[21]、、LiPMnP,,,LiP。Ⅰ。[22],,6。2.6、、、、。Knapp[23]。Vasude-van[24],80,,。,。3·58·Vol.46　No.4刘学艳,等　20098,。,。,,,:、、、。,,。,。[1]PeraltaZamoraP.,DeMoraesS.G.,EspositoE.,etal.Decolori-zationofpulpmilleffluentswithimmobilizedligninandmanganeseperoxidasefromPhanerochaetechrysosporium[J].Environ.techn-ol.,1998,19(5):521-528.[2]BumpusJA,BrockBJ.BiodegradationofcrystalvioletbythewhiterotfungusPhanerochaetechrysosporium[J].Appl.Environ.Mi-crobiol.,1988,54(5):1143-1150.[3]SzczynskeS,paszczynskiA,PastiGrigsbyM.B.,etal.Newpathwayfordegradationofsulfonatedazodyesbymicrobialperoxida-sesofphanerochaetechrysosporiumandstreptomyceschromofuscus[J].Journ.Bacterial,1994,176(5):1339-1347.[4],,.[J].,2003,29(5):53-57.[5],.[J].,2008,(3):19-22.[6]CrippsC,BumpusJA,AustSD.Biodegradationofazoandheter-ocyclicdyesbyPhanerochaetechrysosporium[J].AppliedandEn-vironmentalMicrobiology,1990,56(4):l114-l118.[7]RellinenJ,YinCF,JoyceTW,etal.Treatmentofchlorinebleachingeffluentusingawhite—rotfungus[J].JBiotechnol,1988,8(1):67-76.[8]SpadaroJT,GoldMH,RenganathanV.DegradationofazodyesbythelignindegradingfungusPhanerochaetechrysosporium[J].Appl.Environ.Mircrobiol.1992,58(8)(1):2397-2401.[9]OllikkaP,AlhonmakK,LeppanenVM,etal.Decolorizationofazo,triphenylmethane,heterocyclic,andpolymericdyesbyligninperoxidaseisoenzymesfromPhanerochaetechrysosporium[J].Appl.Environ.Microbiol.,1993,59(12):4010-4016.[10].[D].,2003.[11]PastiMB,PaszczynskiA,GoszczynskeS.InfluenceofAromaticsubstitutionpatternsonazodyedegradabilitybystreptomycesspp.andPhanerochaetechrysosporium[J].ApplEnviron.Microbiol.1992,58(11):3605-3613.[12].[D].,1999.[13]AstherM,MeunierJC.Immobilizationasatoolforthestabiliza-tionofligninperoxidaseproducedbyPhanerochaerechrysosporiumINA-12[J].AppliedBiochemistryAndBiotechnology,1993,38(12):57-67.[14].[D].,2004.[15],,.[J].:,1999,33(2):133-135.[16],,,.[J].,2001,14(1):41-44.[17],,.[J].,2002,21(4):[18],,,.[J].,2004,20(3):60-65,69.[19],,,.-[J].,2008,30(5):33-37.[20],,,.[J].,2002,22(1):7-11.[21],,,.[J].,2002,2(5):459-464.[22],.[J].,2002,3(8):83-87.[23]KnappJS,NewbyPS,ReeceLP.Decolorizationofdyesbywood-rottingbasidiomycetefungi[J].EnzymeandMicrobialTech-nology,1995,17(7):664-668.[24]Vasudevan,B,1984,MSThesis.Theeffectofnitrogen,miner-alanddetergentadditiononthedecolorizationofbleachplantefflu-entsintheMyCoRprocess[D].MSThesis,NorthCarolinaStateUniversity,Raleigh,NC.AStudyonInfluncingFactorsofDyeingWasterwaterTreatedwithWhiteRotFungiLIUXue-yan　XUShu-xia　ZHANGShi-min　WUKun(CollegeofLifeScience,HenanAgriculturalUniversity,Zhengzhou　450002,HenanChina)Abstract:Whiterotfungicouldexcreteligninasesystem,whichhasstrongabilitytodegradevariousorganicpollutants.So,ithaspromisingfutureinthetreatmentofindustrialwastewater.Thedegradingmechanismofthefungiwas(下转第56页)·59·Vol.46　No.4　DYESTUFFSANDCOLORATION464NaCl,NaCl90%,,KCl。　　Na2SO460%90%,40%10%,NaCl、KCl2∶1。5,Na2SO4,KCl。　　5　Na2SO4Na2SO4Na2SO4(%)NaCl(%)KCl(%)(%)(%)()236026.613.341.2137.323-42470201037.7834.554257516.68.337.7033.03-4268013.46.737.9634.454278510538.1434.53428906.63.340.8737.164　　KE-4R,,。,,,。4(1)NaCl、KCl、Na2SO4KE-4R,KCl。(2)NaCl、KCl、Na2SO4KE-4R,KCl,NaCl、Na2SO4。(3)KClKCl,NaCl、Na2SO4。KCl80%,,。(4),。[1].[M].:,2005:95.[2].()[J].,2007(4):23-31.[3],,.[J].,2007,18(4):25-28.[4],.[J].,2005(7):78-81.[5]Nahed.S.E.Ahmed.Theuseofsodiumedateinthedyeingofcot-tonwithreactivedyes[J].DyesandPigments,2005,65(3):221-225.[6]GurumalleshPrabuH.,SundrarajanM..Effectofthebio-salttriso-diumcitrateinthedyeingofcotton[J].J.ColorationTechnology,2002,118(3):131-134.[7],,,.[J].,2007,28(2):67-70.[8],,,.[J].,2007,48(4):21-25.AStudyonComplexesofInorganicSaltsUsedasAccelerantsofReactiveDyestuffSHIZhen-dong　SHIWei-ming(DepartmentofTextileandClothing,WuyiUniversity,Jiangmen529020,GuangdongChina)Abstract　Potassiumchloride,sodiumchlorideandsodiumsulfatewereusedasaccelerantsinthedyeingofcottonwithC.I.ReactiveYellow84respectively.Theresultsshowedthattheacceleratingeffectofpotassiumchloridewassuperiorthantheothers.Severalserieswerecomplexedwiththesesalts,andonesaltwascontainedineachseriesasamainingredientandchangedfrom50%to90%inweight.Itwasfoundthattheacceleratingeffectoftheseriesofcomplexesmainlycontainingpotassiumchloridewasbetterthanth