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2007269CHEMICALINDUSTRYANDENGINEERINGPROGRESS1263163318X503X937A10006613200709126306HazardanalysisofsurfactantsinecosystemWANGBaohuiZHANGXuejiaJIWeiKUANGLiHANHuijunSchoolofChemistry&ChemicalEngineeringDaqingPetroleumInstituteDaqing163318HeilongjiangChinaAbstractSurfactantsarewidelyusedinproductionanddailylife.Mostofthemareinevitablydischargedintotheenvironmentandcausedamagetotheenvironment.Theenvironmentalimpactofsurfactantsinwaterandsoilissummarized.Theeffectsofsurfactantonanimalplantandhumanbeingareanalyzedindetail.Itisveryimportanttostudytheenvironmentalsafetyofsurfactantsatpresent.Keywordssurfactanthazardsoilwaterbiodegradation1Hammer[1][2]LASLASKile[3]CMCDDT1,2,3CMC50mg/kg90%189%500mg/kg45[4]pH2007032620070423196004596503498Emailwangbaohui60@163.comDOI:10.16085/j.issn.1000-6613.2007.09.0242007261264pH100mg/LLASpH0.2LAS50mg/LLAS[5]21mg/LCMC[67]33.1POD[8]SODCATPOD[9]LAS1LAS[10]410A1LASLAS10mg/L20mg/LLAS1mg/L10mg/L3.2[11]22[1217]/mgL196h-LC506.296h-LC503.45.996h-LC504.772h-LC50515348h-LC503.7491265[18][19]3.3[20]LAS8mg/L5mg/L2mg/LLASLAS33[21][22][23]LAS15mg/LLAS50mg/L[24]A13+CMC[25][26][27]3.4[28]Mieure[29]Kimerle[30]LAS10mg/L1.32.5g/kgC14C124SODMDANO[34]4DNADNA[31]LASLAS[32]T-65ALC5058.64mg/LT-65A[33]3.5200726·1266·3[35]LAS3.6CMC[36]100mg/L500mg/L[37]pH7pHZigterman[38]Regan[39]43LAS3ω-β-α-1Tiehm[40]Richard[41]CMC2[42]3Jurek[43]NPEMakit[44]NPENPE4Vieney[45]PAHs[46]Waiters[47]591267[1].[J].2005233325-331.[2].LAS[J].200122157-61.[3]KileDEChiouCT.WatersolubilityenhancementsofDDTandtrichlorobenzenebysomesurfactantsbelowandabovethecriticalmicelleconcentration[J].Enviran.Sci.Technol.1989237832-838.[4].[J].200314112072-2076.[5].[D].2005.[6]MichaelAL.River-waterbiodegradationofsurfactantsinliquiddetergentsandshampoos[J].WaterResearch199125111425-1429.[7].[J].199812429-31.[8].SOD[J].199719112-13.[9].[D].2001.[10].[D].2000.[11]KiikuchiMWakabayashiA.Effectsofsurfactantsonaqueticorganisms[J].SeitaiKagaku197914195-209.[12].LAS[J].1988962-8.[13]MckimJM.Toxicityofalinearallylatesulfonatedetergenttolarvaeoffourspeciesoffreshwaterfish[J].BulletinofEnvironmentalContaminationandToxicology1975141l-7.[14]DolanJM.TheLethalityofanintactanddegradedLASmixturetobluegillsunfishandasnail[J].WaterPollutionControlFederationJournal197648112570-2577.[15].[J].2006291126-28.[16]WakabayashiAKiikuchiMLnoueWetal.Bioaccumulationprofileofsodiumlinearalkylbeuzenesulfonateandsodiumalkylsulfonateincarp[J].Chemosphere1978711917-924.[17].[J].199912311-13.[18].[J].2005242213-215.[19].[J].200623157-60.[20].LAS[J].199413258-62.[21].[J].200123474-75.[22].PAHs[J].200020199-102.[23].Cd[J].19989195-100.[24].LASCd[J].20042361070-1072.[25].A13+[J].200117250-52.[26].3[J].2000195315-316.[27]BussottiFBottacciAGrossoniPetal.CytologicalandstructuralchangesinPinuspineaL.needlesfollowingtheapplicationofananionicsurfactant[J].PlantCellEnviron.1997204513-520.[28].[J].20055638-43.[29]MieureJPWatersJHoltMSetal.Terrstrialsafetyassessmentoflinearalkylbenzenesulfonate[J].Chemosphere199021251-262.[30]KimerleRAZhangYYKorteFetal.Aquaticandterrestrialseco-toxicologyoflinearalkylbenzenesulphonate[J].TensideSurf.Det.1989262167-176.[31].DNA[J].200511641.[32].[J].199421524-25.[33].T-65A[J].199311119-21.[34].[J].200523346.[35].[J].199819276-77.[36]RochFAlexanderM.Biodegradationofhydrophobiccompoundsinthepresenceofsurfactant[J].Environ.Taxicol.Chem.1995141151-1158.[37]TiborCZoltonIIstvonneN.Effectsofnonionictensidesonthegrowthofsomesoilbacteria[J].Appl.Microbiol.Biotechnol.199135115-118.[38]ZigtermanGJWJSchotanusKErnsterEBHW.Nonionicblockpolymersurfactantsmodulatethehumoralimmuneresponseagainststreptococcuspneumoniae-derivedhexasaccharide-proteinconjugate[J].Infect.Immun.19895792712-2718.[39]ReganSLJavasuriyaNFabianowskW.Supramolecularsurfactantsamphiphilicpolymersdesignedtodisruptlipidmembranes[J].Biochem.2007261268Biophys.Res.Commun.1989159566-571.[40]TiehmAStieberMWemerP.Surfactantenhancedmobilizationandbiodegradationofpolycyclicaromatichydrocarbonsinmanufacturedgasplantsoil[J].EnvironmentalScienceandTechnology19973192570-2576.[41]RichardEMWilliamPI.Effectsofanonionicsurfactantonbiodegradationofphenanthreneandhexadecaneinsoil[J].ToxicologicalandEnvironmentalChemistry1998181927-1931.[42]DeanSMJinYChaDKetal.Phenanthrenedegradationinsoilsco-inoculatedwithphenanthrene-degradingandbiosurfactantproducingbacteria[J].JournalEnvironmentalQuality2001301126-1133.[43]JurekPGregoryWP.Biodegradationandsecondaryeffluenttoxicityofethoxylatedsurfactants[J].WaterResearch1990248965-972.[44]MakitHOkamuraHAoyamaI.Halogenationandtoxicityofthebiodegradtionproductsofanonionicsurfactantnonylphenolethoxylate[J].Environ.Taxicol.Chem.1998174650-654.[45]VineyIBewleyRJF.Preliminarystudiesonthedevelopmentofamicrobiologicaltreatmentforpolychlorinatedbiphenyls[J].Arch.Environ.Contam.Toxical.199019789-796.[46].[J].200030422-24.[47]WaterJFeijtelJ.Lethalityofaminocarbandcomponentsofaminocarbfomou-lationtojusenueatlanticsalnoonmarineinvertebratesandfreshwaterclam[J].Chemosphere199530101939-1956.2007589Ni-WRh