不同预处理方式对污泥厌氧发酵的影响

20149459doi10．6041/j．issn．1000-1298．2014．09．031*112231．1001932．1000833．100079。、、。、、。、。。X703A1000-1298201409-0187-122013-12-042014-01-04*“”2012BAD14B03、[e-mail][e-mail]、。201233401.42m32200t1。。80%、、2。。、、3。、、、、、4。、20～30d、。EPS、EPS、、、。。、。1、、、5。。115－6。1Tab．1Contentofdifferentsludgecharacteristicsindicators15－6/%/%/%60～9060～8020～4060～8861～7525～3930～6030～6040～70、、、、、、、4。26－7。2Tab．2Organicingredientsofsludge/%402011631192。、、。2。、、67%、64%、97%65%8。、9。。20。3。3VS、。796%～97%0.2L/g34.5%0.58L/gBattimelli10COD38%。。、11。。。3Tab．3SludgemesophilicanaerobicfermentationparametersandindexesinsomewastewatertreatmentplantspH/%/m3·kg－1/m3·m－3/kg·m－3·d－1/%7.1～7.40.8071.2133.5～70.112－136.5～7.530～398.51.082414557～830～4515－176.5～7.5506～101.0～2.030～50187.0～7.540～450.7540～451512.14195.9～7.5508.23615－16700.9351.620－216.6～7.27～9301622400.50～0.684.5～6.04523881201432EPS7。EPS。EPS。、、1124。3.1、。、、H2O2124。4Tab．4Comparisonoftreatmenteffectofchemicalpretreatments/COD/TSO30.1g/g33℃110220mL/SCOD+100%250.1g/g82173mL/SCOD+110%260.15g/g150367mL/gSCOD+145%270.05g/g35℃TS31%59%+90%280.045g/g35℃TS85%280.16g/g35℃COD38%58%+53%10H2O215g/L16%292g/gCOD52.2%70.1%+34%302g/gCOD52.2%74.6%+43%300.07g/g75%VS57%310.3g/gNaOH37℃COD32%42%+31%327g/LNaOH37℃3657mL/L5037mL/L337g/LNaOH37℃290mL/g520mL/g341.6g/LNaOH35℃VS94%351.65g/LKOHpH1035℃30%291.65g/LKOHpH1035℃88mL/SCOD154mL/g293.1.1、。pH。Jeongsik33NaOH35℃CODNaOHNaOH7g/LCOD43.2%36.6L/m341.5L/m3。NaOH、KOH、MgOH2CaOH2pH12SCOD39.8%、36.6%、10.8%15.3%36NaOH、KOHCaOH2。37。、pH。3.1.29819DNA、ＲNA、、。O338O3、。1028。Bougrier390.16g/g2.25Weemaes250.16g1.82.2。Bougrier27EPS、。3.1.3H2O2H2O2。H2O22g/gSCOD35%30。H2O2、、H2O240－41。3.2、、。、、5。5Tab．5Effectsofdifferenttemperaturesonanaerobicdigestionperformanceofdifferentkindsofsludgeanaerobic、70℃7d37℃26%4270℃7d55℃4270℃9h55℃58%43180℃60min37℃90%32170℃60min35℃45%29170℃30min50%44170℃30min35℃51%45170℃30min40%～50%4670℃4d37℃16%4270℃7d55℃86%4270℃2d55℃48%4750～65℃2d35℃25%483.2.1。60～270℃165～180℃42－4347－55。Li50170℃30～60minVS60%Dwyeret51170～190℃170～190℃52。5354。55120～150℃。09120143.2.22。EPS56OH·HO2·H·。·H+O→2HO2·O·+H2→O·OH+·OH·OH+·→OHH2O2657。Apul5824kHz、400WSCOD50mg/L2500mg/L。Tiehm5930～120min63.6%VS45.8%50.3%。Xu607%～8%。2。6152。Tiehm59EPS41kHz7.5～150minEPSSCOD30、60150minSCOD4.7%、13.1%23.7%。Li62。、、、63。6Tab．6Effectsofdifferentultrasonicpretreatmentsonanaerobicdigestionofsewagesludge8000kJ/kg31kHzCSTＲ37℃VS31%646250kJ/kg20kHz35℃51%6520kHz200W30min37℃138%66200W9kHz30min36℃VS210mL/g345mL/g673.6kW31kHzCSTＲ37℃VS45.8%50.3%+9%6813.7W/cm220kHz60sCSTＲ35℃45%6920kHz180W60s35℃24%7041kHz150minCSTＲ35℃VS21.5%33.7%+36%7120kHz0.33W/mL20min35℃TS200.2mL/g408.8mL/g7220kHz7000～15000kJ/kg35℃40%7320kHz108000kJ/kg37℃84%7420kHz9690kJ/kg36℃44%753.2.32。、。76－77。Eskicioglu7850～96℃1919。Park77600kJ/LSCODTCOD8.5。Eskiciogluc7850、7596℃SCOD/TCOD9.1%12.1%、21.0%24.1%、、79、。3.2.4EPS。、。Dohanyos8025d85%。15%81。Onyeche8230%。Baier8321d10%。、84。3.32、。N-NAG-NAMB-1485。7。86AT07-1TSSAT07-1。Barjenbruch8788Barjenbruch10%4hSCODTCOD6.4%30.9%7.750.7。。8990。、。7Tab．7Effectsofbio-pretreatmentsonanaerobicdigestionofsewagesludge/AT07-186Clostridiumbifermentans0.16mg/g1.8mg/g91MyxococcusxanthusxanthusATCC25232VSS9.8%62%92、29%93CellulaseEPronaseEVSS20%80%TSS80%94SCOD/TCOD6.4%30.9%88TSS/TS26%48%10%87953.463。。、、。29120143.4.1。SCOD。Jeongsik33120℃30minSCODTCOD34.3%SCOD67.8%。Heonh96TS3%45mmol/LNaOH25、3555℃SCOD28%、31%38%66%、73%88%45mmol/LNaOH。Vlyssi97CaOpH8、9、101150、60、70、8090℃pH1190℃VSS45%SCOD70g/L15dVSS46%0.28L/g。、、。3.4.23.4.2.1H2O2H2O2OH—H2O298。Eski99、H2O2H2O21g/gSCODTCOD15.0%24.1%。Eski99120℃H2O2TS24%H2O2OH—。120℃100℃-。3.4.2.2、。Dogan100pH10、11、1212.5SCODTCOD0.5%18%、0.27%、0.34%0.37%pH12-18.9%TSS、VSSCOD24.9%、35.5%30.3%22%。、、、H2O2、+H2O2+55SCOD15.8%、15.0%、13.7%、19.2%15.0%H2O2。3.4.3。/、。101、、SCOD、VSS、VSS、16.0%、22.1%VSS51.5%～54.5%。1021.5W/mL、pH11TCOD、VSVSS29.6%、58.9%28.6%。EPS3919。Iwona103NaOH0.1、0.2、0.3、0.4、0.50.6g/gSCOD26、33、43、50、5354。4、、、、。。1。。2。EPS。3VS。4。。5。6。、。1．———、、J．2013630－31．2．J．2006241221－24．TaiMingqingJiaDongfangZhangLilietal．ＲesearchanddevelopmentondisposalofsewagesludgeJ．ChinaＲesourcesComprehensiveUtilization2006241221－24．inChinese3．J．200032279－85．4ＲafDewiLiseAppelsJanBaeyensetal．PeroxidationenhancesthebiogasproductionintheanaerobicdigestionofbiosolidsJ．JournalofHazardousMaterials20071463577－581．5．J．201036153－157．6．J．199732176－181．7．J．2006222395－98．DaiQianjinLiYiFangXianjin．StudyonanaerobicdigestionofexcessactivatedsludgefrommunicipalwastewatertreatmentplantJ．ChinaWaterWastewater200624395－98．inChinese8．J．2006243140－142．WangJingLuZongwenTianShunetal．ExistingstateanddevelopmentofsludgyresearchesindomesticandforeignJ．MunicipalEngineeringTechnology2006243140－142．inChinese9．J．200826215－219．10BattimelliAMilletCDelgenèsJPetal．Anaerobicdigestionofwasteactivatedsludgecombinedwithozonepost-treatmentandrecyclingJ．WaterScience＆Technology200348461－68．11．J．200420731－33．MuYanyanYuXinZhengZhengetal．ＲesearchprogressonpretreatmentmethodofanaerobicsludgedigestionJ．ChinaWater＆Wastewater200420731－33．inChinese12．J．201130444－47．WeiHaijuanJiangLingyanWangGangetal．Exper