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0，、，、，，、，，[1]。、、,。，，[2]，。Fenton，UV2。Fenton/UV，：KANG[3]Fenton/UV；[4]Fenton/UV；KIM[5]Fenton/UV；[6]Fenton/UV；[7]Fenton/UV。，Fenton/UV，。1。，ρ（CODCr）2000mg/L，。1。Fenton/UV，*，(,621010)：Fenton/UV，：pH=2.5，ρ（Fe2+）=400mg/L，H2O2[V(H2O2)=30%]24mL/L，V（H2O2）4mL/L，45min，6，UV=5h，5L。:，ρ(CODCr)2100mg/L110mg/L，CODCr95%，GB8978—1996《》。。：；Fenton/UV；；:X7:A:1674-4829（2009）06-0006-04：2009-07-28：（：NO.3）；.：（1985-）,，，，，.*：.StudyonTreatmentofMetalWorkingFluidsWastewaterbyFenton/UVZHOUNai-lei，WANGZhong-qi，XUXu-dongAbstract：ThemetalworkingfluidswastewaterthatproducedinthemetalmanufactureindustrywastreatedbytheadvancedoxidationtechnologyofFenton/UV.Throughtheorthogonalexperiment,theoptimalconditionfortheexperimentwasacquired,thatwas:initialpH=2.5，ρ（Fe2+）=400mg/L，afteruniformmixingaddingH2O2（30%）24mL/Linall，eachtimeaddingH2O24mL/L，theintervalofeachtimebeing45minutes，andadding6times.ThetotaltimeofUVeffectwasabout5hours.Meanwhile,accordingtotheoptimalconditiontheenlargingexperimentof5Lwasmade.BoththelittleexperimentandenlargingexperimentshowthatattheoptimalconditiontheCODcrconcentrationofeffluenceisreducedtoabout110mg/Lfrom2100mg/L,andeachindexofthetotaleffluencereachesthesecondlevelof“IntegratedWastewaterDischargeStandard”(GB8978-1996).Theoptimalconditiondatahasthereferencevalueinprojects.Keywords：Metalworkingfluids；Fenton/UV;Advancedoxidationtechnology；Orthogonalexperiment226200912EnvironmentalScienceandTechnologyVol．22No．6Dec．20092262：FeSO4·7H2O(AR)，H2O2(30%)(AR)，K2Cr2O7(AR)，H2SO4(AR)，NaOH(AR)，Ag2SO4(AR)，（NH4）2Fe(SO4)2·6H2O(AR)，PAM(AR)，。：SGY-，；PH211，；DD60-2F，。：CODCr；pHPH211。3Fenton/UVFenton/UVFenton。Fenton，，，H2O2，，[8-10]：（1）H2O2，·OH∶H2O2+hν→2·OH（2）Fe2+，Fe3+，Fe3+Fe（OH）2+，Fe（OH）2+Fe2+，·OH：Fe（OH）2++hν→·OH+Fe2+H2O2，Fenton：Fe2++H2O2→Fe3++OHˉ+·OHFe3++H2O2→Fe2++HO2+H+，，Fe(C2O4)+,Fe(C2O4)ˉ,Fe(C2O4)33-，，，：2[Fe(C2O4)n]3-2n+hν→2Fe2++(2n-1)C2O42-+CO2Fe2+H2O2Fenton。Fenton/UV，。4FentonUV/H2O2，CODCr。Fenton[11]，：ρ（Fe2+）=500mg/L，30%H2O215mL/L，ρ（CODCr）=2000mg/L，ρ（CODCr）=1130mg/L,43.5%，。UV/H2O2UV500W，H2O220g/L,4h，ρ（CODCr）=2000mg/L，ρ（CODCr）=1550mg/L，22.5%，。2Fenton/UV。5，pH，ρ（Fe2+），H2O2UV43[13－14]，2。，300W，500mL，ρ（CODCr）2000mg/L3。,R1R3R2R4，，Fenton/UV：pHH2O2ρ（Fe2+）UV。A1C3B2D1。pH=2.5，H2O220mL/L，ρ（Fe2+）=400mg/L，UV3h。ρ（CODCr）2000120ρ（BOD）34030ρ（）3025ρ（）0.61.0/1000801mg·L-1(B)ρ（Fe2+）/（mg·L-1）300400500(C)v（H2O2）/(mL·L-1)121620(D)UV/h3452.53.54.5(A)pH2123456789K1K2K3k1k2k3R111222333157430194344524.71006.31448.0R1=4344123123123298028703087993.3956.71029.0R2=30871232313123502312723081167.31042.3769.3R3=3502123312231286430163057954.71005.31019.0R4=3057ρ（CODCr）/（mg.L-1）66155036310827081229123716121495ACBDA1C3B2D1DCBA3L9(34)Fenton/UV7200912CODCr：pH7，Fe3+,Fe2+，PAM，1.5mg/L，，CODCr。CODCr，pHFenton/UV，pH2.5CODCrpH4.5。CODCr，Fenton，H2O2，H2O2。，。H2O2，，43，4，，300W，500mL，ρ（CODCr）2000mg/L，1pH=2.5，ρ（Fe2+）=400mg/L，H2O220mL/L，3h，H2O2，5。2,R1R3R4R2，，Fenton/UV：H2O2。A2B2C3。H2O24mL/L，45min，6。645min，4.5h13h，，H2O2，45min。2：Fenton/UV100。H2O2（）Fenton./UVCODCr，1CODCr81.9%294.8%。Fenton，H2O2：H2O2+H2O2→2H2O+O2,H2O2，。61、2，pH=2.5，ρ（Fe2+）=400mg/L，H2O224mL/L，H2O24mL，45min，6，UV5h，500mL，CODCr2000mL/L，2，110mg/L101mg/L。。1、2，，H2O2Fenton，45minH2O2Fenton，H2O2。，Fenton，。Fenton/UV。7，CODCr。1，，ρ（CODCr）=2117mg/L，5L3，2。。1Fenton/UV123456789K1K2K3k1k2k3MAXRa111222333729.2420.9433.3243.1140.3144.4R1=729.2123123123550.0545.9487.5183.3182.0162.5R2=550b123231312645.9466.7470.8215.3155.6156.9R3=645.9c123312231595.8529.2458.4198.6176.4152.8R4=595.8ρ（CODCr）/（mg.L-1）312.5229.2187.5104.2150.0166.7133.3166.7133.3abca2b2c25L9(34)(a)H2O2/mL345(b)/min304560(c)/45648226100806040200COD/%1Fenton2UV/H2O23Fenton/UV（1）4Fenton/UV（2）5Fenton/UV（）22：3，。。，H2O2180minCODCr，，225min，ρ（H2O2）24mg/LCODCr，，[14]。8FentonUV/H2O2，Fenton/UV，CODCr。3CODCr，CODCr95%，Fenton/UV，。3CODCr(CODCr)/100mg/L，：，；，1m360；，，；，2~5m3，。，。[][1]，，，.[J].，2005(10):132-133.[2].[J].2006(6):28-30.[3]KANGSF,WANGTH.Decolorizationanddegradationof2,4-dinitrophenolbyFentonreagent[J].EnvironSciHealthA,1999（34）:935-950.[4].UV/Fenton[J].,2002(2):29-32.[5]KIMSM.EffectofFentonandphoto-Fentonreactionsonthedegradationandbiodegradabilityofnitrophenolinwatertreatment[J].ApplCatalBEnviron.1994,3:295-305.[6],,，.UV/Fenton[J].,2006,35(01):23-25.[7],,.UV/Fenton[J].,2001,17(01):35-38.[8]WAK,XIEY,ZHAOJ，etal.Photo-Fentondegradationofadyeundervisiblelightirradiation[J].MolCatal,1999,11(4):77-84.[9]MALETZKY,BAUERR.ThePhoto-Fentondegradationofnitrogencontainingorganiccompounds[J].CheMosphere，1998,37:899-909.[10]，，,.Photo-Fenton[J].,2000,18(4):357-365.[11]，,.Feneton[J].，2007，20（52）：111-113．[12]，.[J].，1995(1):52-55.[13].[J].，1997，3(27):69-73.[14]HILALN,BUSCAG,ROZADAF,etal.Useofactivatedcarbontopolisheffluentfrommetalworkingtreatmentplant:comparisonofdifferentstreams[J].Desalination,2005,185(3):297-306.(）H2O2/mL3025201510502500200015001000500010015020025030035050ρ(CODCr)/(mg·L-1)/minρFenton/UV9