曹妃甸老化油处理技术研究曾浩见

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300450。。80℃4∶15%m∶mHPAA=1∶1+0.05%BK-01220V90min。0.6%0.2%50mg/L。2017-04-24。。、FPSO1-2。。1、、。、。FPSO30000m30.5%。22.1HAAKE10s-11。1170℃100mPa·s80℃59.46mPa·s。2.280℃1h100mL3000r/min10min。105℃800℃1。1/%/%/%6S22.010.00.562.3HAAKE2002。2520177.DOI:10.13534/j.cnki.32-1601/te.2017.04.0022W/O。33.1、3-4。。3.2。、。SJ-01SJ-02、SD-02、、80℃。。3.3Fe2+、FeS、5。ICS9002pH7.8。Ca2+、Mg2+、Fe2+、Ba2+、Sr2+Fe2+、。2/mg·L-1/mg·L-1Na+1378.0Cl-2216.0K+32.730SO42-0.823Ca2+27.910HCO3-1708.0Mg2+3.885CO25.000Ba2+0.802H2S0Sr2+2.039Fe2+0.1073.46。NaCl、MgCl2、AlCl3、AlNO33。。3.5FPSO。7。44.18。100mL70.05%80℃24h。3。。BK-01。4.2。。520mL80mL80℃12h4。4HEDPHPAAHPAAHEDP、。HPAA1∶15%。6ADVANCESINFINEPETROCHEMICALS1843mL2h6h12h16h20h24hBK-01057101010PA-EH023344Y135000000NB-02088888NE4121000000PE2157044444XZ-11-130022334mL1h4h8h16h20h24hHCl12153030303051325252727HPAA31323262626HEDP318252525254.35%m∶mHPAA=1∶1+0.05%BK-014∶1。BK-01。80mL80℃12h5。7%0.5%。5mL1h3h5h7h9h12h0.05%BK-01+5%12233232323250.5%。。9-10。YDT-Ⅱ220V80℃90min34。6。0.6%0.2%。6/%/mg·L-1/%0.623.30.234616S22.0%10.0%0.56%。720177.W/O。2。35%m∶mHPAA=1∶1+0.05%BK-014∶1。0.6%23.3mg/L0.2%。1.J.2014331247-48.2.J.20151819.3.J.201542365-6671.4.J.2010273337-341.5.FeSJ.2001184317-319341.6.D.2008.7.D.2009.8.、D.2010.9.J.2015401122-125.10.J.2012191131-134142.ResearchonAgingOilTreatmentTechnologyofCaofeidianOilfieldZENGHaojianTIELeileiLIXiangOilfieldProductionDepartmentofChinaOilfieldServicesLimitedTianjin300450AbstractThemaincausesfortheemulsificationofagedoilwereidentifiedbyanalyzingthebasicphysicalpropertiesandmicromorphologyoftheagedoilofCaofeidianOilfield.AformulationofemulsionsplitterwasidentifiedandelectricaldehydratingtechniquewasusedtotreattheagedoilofCaofeidianOilfield.Theresultsofstudyhaveshownthatthetreatmenttemperatureis80℃theoil-waterratiois41theformulationofemulsionsplitteris5%removermaceticacidmHPAA=11+0.05%BK-01thevoltageofelectricaldehydratingis220Vandtimeofelectricaldehydratingis90min.Theagedoilcontains0.6%ofwaterandtheoilcontentinwaterislessthan50mg/Laftertheagedoilistreatedwiththisformulationofemulsionsplitteratsuchconditionsindicatingthattheagedoilrecoveryandtreatmentrequirementscanbesatisfiedandthegoalofreducingagedoilandconvertingitintoresourcecanberealized.Keywordsagedoilcausesforemulsificationemulsionbreaking櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃櫃Caofeidian48.9×10-3mN/mwhenthemassratioofsulfonategeminisurfactantDS14-2-143#betainesurfactantand5#visco-elasticitynon-ionicsurfactantis532andthemassfractionofthesurfactantpreparedis0.4%.Thisfoamsystemhasgoodheatresistanceandsalinitytolerancepropertiesandisoilresistanttoalessextent.Keywordssulfonategeminisurfactantinterfacialtensionhighfoamstabilityoilresistancepropertyheatresistanceandsalinitytolerance8ADVANCESINFINEPETROCHEMICALS184

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