常温下低氨氮污水的短程硝化启动研究张昭

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1111111121.1001242.15009015~28℃DO=0.10~1.0mg/LA/O。2020d70%80%0.08kgNH+4-N/m3·d。。DO、、HRTSRTNOB。。X703A1000-4602201209-0035-05508780038092006QAK2010052008ZX07208-003-003、2008ZX07420-004-001、2008ZX07208-005-003ykj-2011-4764、ykj-2011-4765、ykj-2011-4766Start-upExperimentofShortcutNitrificationforLowAmmoniaNitrogenWastewateratRoomTemperatureZHANGZhao1LIDong1ZHONGHang1LIULi-qian1ZHOULi-jun1SUNYu1WUDi1ZHANGJie121.KeyLaboratoryofBeijingforWaterQualityScienceandWaterEnvironmentRecoveryEngineeringBeijingUniversityofTechnologyBeijing100124China2.StateKeyLaboratoryofUrbanWaterResourceandEnvironmentHarbinInstituteofTechnologyHarbin150090ChinaAbstractTheeffluentofanA/Oprocessremovingphosphorousfrommunicipalwastewaterwasusedastheinfluentofapilot-scaleplugflowreactor.Undertheconditionsofroomtemperature15to28℃andlimitedoxygenDO=0.10to1.0mg/Lthenitrifyingsludgewasinoculatedandshortcutnitrificationwasstartedbysequencingbatchandcontinuousflowmethods.Inthesequencingbatchreac-torthestrategyofreal-timecontrolofaerationdurationwastaken.After20continuouscycles20dtheammoniaoxidationratewasover70%thenitrosationratewasover80%andtheremovalloadreached0.08kgNH+4-N/m3·dshowingthattheinitialstart-upofshortcutnitrificationwasa-·53·28920125CHINAWATER&WASTEWATERVol.28No.9May2012chieved.Therelativelyhighsludgeloadingrateaswellasthedelayofaerationmadeshortcutnitrificationunstabletothepointofcrashing.InthecontinuousflowreactoreliminatingnitriteoxidizingbacteriaNOBbycontrollingdissolvedoxygenDOaerationmodehydraulicretentiontimeHRTsludgeretentiontimeSRTandotherparameterswasdifficult.Meanwhiledramaticallyincreasingtheorganicloadingcausedlimitedsludgebulkingbutwhenorganicloadingwasreducedsludgebulkinggraduallydisappearedandnitrificationperformancewasnotaffected.Keywordsshortcutnitrificationstart-upsequencingbatchcontinuousflowdissolvedoxygenplugflowlowammonianitrogenwastewaterC/N。、、。25%、40%、50%1~5。。、、。。A/O、。11.11。41.2m32.0m×0.6m×1.0m。300L。。。1Fig.1Schematicdiagramofshortcutnitrificationreactor。0.5h、14~18.5h、1.0h、0.5h、3.5~8h。1.2。100L5700mg/LMLSS=500mg/L600L6650mg/LMLSS=3500mg/L。A/O1COD。1Tab.1CharacteristicsofinfluentCOD/mg·L-1NH+4-N/mg·L-1NO-2-N/mg·L-1NO-3-N/mg·L-1pHTP/mg·L-130~7043~900~1.990~2.707.50~8.030.2~1.0·63·289.watergasheat.com1.3NO-2-NN-1--NO-3-NpH、DOWTW。22.12.1.114.8~19.6℃53~90mg/L。>50%。、2。2、Fig.2Variationofinfluentandeffluentammonianitriteammoniaoxidationrateandnitriteoxidationratewithtime260%16%10mg/L60mg/L。AOB14h18.5h85%36%。14~18h75%1250%。、pH“”NOB。DO<1.0mg/LAOBDONOBAOBDO。2070%80%0.06~0.10kgNH+4-N/m3·d3。3Fig.3Variationofammoniaremovalratewithtime70%25mg/L。70%DOAOBNOBNOBNO-2-NNOB10h4。4NO-3-NFig.4VariationofeffluentNO-3-Nwithtime2.1.238。、4.178mgNH+4-N/h·L2.378mgNO-2-N/h·L。·73·.watergasheat.com289DO2.50mg/L1h0.25mg/L5。DO2“”pH18h>95%pH“”。DO、ORPpH。5DO、ORP、pHFig.5VariationofDOORPandpHduringtypicalcycle75%50%。。2.1.34h2、4A、B、C70%52%。65%50%NOBDO。MLSS25~60250mg/L100mg/L0.41kgNH+4-N/kgMLSS·d0.50~0.60kgNH+4-N/kgMLSS·d。AOBNOB。7035%45mg/L22mg/L。40%~60%10%。。、80%AOBNOBDO、。。AOBNOB。2.22.2.122.0~26.8℃。AOBNOBDOAOBNOB644、3、2、1L/minDO0.50、0.30~0.40、0.15~0.25、0.05~0.10mg/L。1d80%。HRT7~45HRT10~11h46~93HRT7~9h。20d1mg/L。NOBAOB。AOBYAOBLmNH+4-NNOB7。2144、0.5、3、0.5L/minDO0.30~0.50、0~0.05、0.10~0.20、0~0.05mg/L///1mg/L。55~601.5mg/L0.50mg/L。。、、3。①·83·289.watergasheat.com、FAFA<0.50mg/L②DO、HRTAOBNOBDO。2.2.2SRTSV15%~25%SVI60~120mL/g。20~8045dSRTNOB。870MLSS3500mg/L2000mg/L。7550L/hCOD150~200mg/L1DO0.40mg/L0.20mg/LSV19%30%SVI84mL/g132mL/g。DO、30%2d2SV25%6d19%。。25~28℃AOBNOBSRTAOBNOB。SRT。DO、SRT、FA。。3①2020d70%80%0.08kgNH+4-N/m3·d。②14.8~19.6℃AOBNOBAOBDO。③DO、、HRTSRTNOB。。1GalíADostaJvanLoosdrechtMCMetal.BiologicalnitrogenremovalvianitriteofrejectwaterwithaSBRandChemostatSHARON/denitrificationprocessJ.IndEngChemRes200645227656-7660.2BartroliACarreraJPerezJ.Bioaugmentationasatoolforimprovingthestart-upandstabilityofapilot-scalepartialnitrificationbiofilmairliftreactorJ.BioresourTechnol201110264370-4375.3NittamiTOotakeHImaiYetal.Partialnitrificationinacontinuouspre-denitrificationsubmergedmembranebio-reactoranditsnitrifyingbacterialactivityandcommunitydynamicsJ.BiochemEngJ2011552101-107.4WangLAZhuJMillerC.Thestabilityofaccumulatingnitritefromswinewastewaterinasequencingbatchreac-torJ.ApplBiochemBiotechnol20111633362-372.5.J.20104081156-1162.6.NO-2J.200930185-90.7WuChang-yongPengYong-zhenWangShu-yingetal.Effectofsludgeretentiontimeonnitriteaccumulationinreal-timecontrolbiologicalnitrogenremovalsequencingbatchreactorJ.ChineseJournalofChemicalEngineer-ing20113512-517.8BaeWBaekSChungJetal.Optimaloperationalfac-torsfornitriteaccumulationinbatchreactorsJ.Biodeg-radation2001125359-366.1986-。E-mail7626926sea@163.com2012-01-10·93·.watergasheat.com289

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