超高分子量聚乙烯碳纳米管复合材料的研究进展

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/31,2,2,3,4(1,230039;2,242300;3,230039;4,230026):/,/,:;;;ResearchProgressonUltrahighMolecularWeightPolyethylene/CarbonNanotubesComposite3XUGuo-yong1,2,CHENJin-yang2,ZHANGYu-chuan3,ZHUQing-ren4(1CenterofModernExperimentalTechnology,AnhuiUniversity,AnhuiHefei230039;2AnhuiZhongdingSealingCo.,Ltd.,AnhuiNingguo242300;3SchoolofChemistry&ChemicalEngineering,AnhuiUniversity,AnhuiHefei230039;4HefeiNationalLaboratoryforPhysicalSciencesattheMicroscale,UniversityofScienceandTechnologyofChina,ChineseAcademyofSciences,AnhuiHefei230026,China)Abstract:Thecharacteristicandtheapplicationofultrahighmolecularpolyethylene/carbonnanotubeswerere2viewed.Basedoncomparisonandanalysisoftherecentresearchresults,suggestionsofdevelopmentandapplicationinthisareawereputforward.Keywords:ultrahighmolecularpolyethylene;carbonnanotubes;composites;mechanism:(1975-),,,20E-mail:gyxu@mail.ustc.edu.cn(UHMWPE)7080,,UHMWPE;,0197g/cm3;,,;,1500h,80%,,-150;,UHMWPE,,UHMWPEIijima[1],,,,,,,UHMWPE1UHMWPEUHMWPE4DSM,1DSM1999AlliedSignalHoneywell,DSM,,DSM(Toyobo)DSMUHMWPEDSMDSM,52009376©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(Mitsui)Tekmilon3:,DSMHoneywellUHM2WPEHoneywellASTMD2256UHMWPE,UHMWPE(316Gpa19GPa)[2],UHMWPE;;,UH2MWPE[3-5],UHMWPEP1Smith,M1Matsuo[6-8],,UHMWPE,UHMWPE2/(CNTs),(SWNTs)(MWNTs),,,,,(1/3;2/3),,,,,UHMWPE,CNTsUHMWPE,UHMWPE,UHMWPEM1Matsuo,Y1Bin[9-12]MWNTs,MWNTs/UHMWPE,MWNTs[9-12][10][11][10-11],UHMWPECNTs15wt%,MWNTs/UHMWPE100,58GPa,10-3S/cm;150-,MWNTsUHMWPEP1Gao[13]MWNTs,MWNTs/UHMWPE,1wt%MWNTsUHMWPE,UHMWPE,MWNTs/UH2MWPE[14],5wt%MWNTsUHMWPE,MWNTs,S.Rastogi[15]SWNTsUHMWPE,SWNTs/UHMWPE,UHMWPESWNTs,SWNTsUHM2WPEXie[16]-(--)-(MA-SEBS),CNTs/UHMWPE;CNTsMA-SEBSUHMWPE[17]MWNTsUHMWPE,MWNTs/UHMWPE,1wt%MWNTsUHMWPE,013wt%MWNTs[18-20],CNTs(),UHMWPECNTs,,UHMWPEUHMWPE,MWNTs/UHMWPE,,,,UHMWPE,3UHMWPE,,,,UHMWPE,UHMWPE/(11)62009376©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[8]JunyanDai,ChristopherKOber,LinWang1OrganoelementResistsforEUVLithography1[9]J1PabloBravo-Vasquez,Young-JeKwark1InorganicPolymerResistsforEUVL1[10]Young-JeKwark,J1PabloBravo-Vasquez,andChristopherK1Ober1NovelSiliconContainingPolymersasPhotoresistMaterialsforExtremeUVLithography1[11]J1PabloBravo-Vasquez,Young-JeKwark1SiliconBackbonePoly2mersasEUVResists1[12]TakeoWatanabe,YasuyukiFukushima1CAResistwithsidechainPAGgroupforEUVresist[J]journalofphotopolymerscienceandtechnolo2gy1[13]KimR1Dean1,KennethE1Gonsalves1Effectsofmaterialdesignonex2tremeultraviolet(EUV)resistOutgassing1[14]AnujaDeSilva,DrewFormanandChristopherK1Ober1MolecularGlassResistsforEUVLithography1(6)[1]IijimaS.Helicalmicrotubesofgraphiticcarbon[J].Nature,1991,354(6348):56-58.[2]TashiroK,KobayashiM,TadokoroH.CalculationofThree-Dimen2sionalElasticConstantsofPolymerCrystals.1.MethodofCalculation[J].Macromolecules,1978,11(5):908-913.[3],,,.[J].,1997,20(6):22-24.[4],,,.[J].,2001,14(1):76-801[5]WangX,LiH,JinR.Synchronoustougheningandreinforcingofpoly2propylenewithultrahighmolecularweightpolyethyleneviameltblend2ing:mechanicalproperties,morphologyandrheology.JApplPolymSci,2006,100(5):3498-3509.[6]SmithP,LemstraPJ.Ultra-drawingofhighmolecularweightpoly2ethylenecastfromsolution[J].ColloidPolymSci,1980,258(7):891-894.[7]OgitaT,KawaharaY,NakamuraRetal.DrawabilityofUltrahighMo2lecularWeightPolyethyleneSingle-CrystalMats[J].Macromole2cules,1993,26(17):4646-4651.[8]ZhuQR,HongKL,QiRRetal.Microphasestructureand13CNMRrelaxationparametersinUHMWPE[J].ScienceinChinaSer.B,1995,25(4):350-357.[9]BinY,KitanakaM,ZhuDetal.DevelopmentofHighlyOrientedPo2lyethyleneFilledwithAlignedCarbonNanotubesbyGelation/Crystalli2zationSolutions[J].Macromolecules,2003,36(16):6213-6219.[10]ChenQ,BinY,MatsuoM.CharacteristicsofEthylene-MethylMeth2acrylateCopolymerandUltrahighMolecularWeightPolyethyleneCom2positeFilledwithMultiwallCarbonNanotubesPreparedbyGelation/CrystallizationfromSolutions[J].Macromolecules,2006,39(19):6528-6536.[11]BinY,YamanakaA,ChenQetal.Morphological,ElectricalandMe2chanicalPropertiesofUltrahighMolecularWeightPolyethyleneandMultiwallCarbonNanotubeCompositesPreparedinDecalinandParaffin[J].PolymJ,2007,39(6):598-609.[12]XiY,YamanakaA,BinYetal.ElectricalPropertiesofSegregatedUl2trahighMolecularWeightPolyethylene/MultiwalledCarbonNanotubeComposites[J].JApplPolymSci,2007,105(5):2868-2876.[13]RuanSL,GaoP,YangXGetal.Tougheninghighperformanceultra2highmolecularweightpolyethyleneusingmultiwalledcarbonnanotubes[J].Polymer,2003,44(19):5643-5654.[14]RuanSL,GaoP,YuTX.Ultra-stronggel-spunUHMWPEfibersreinforcedusingmultiwalledcarbonnanotubes[J].Polymer,2006,47(5):1604-1611.[15]ZhangQ,LippitsDR,RastogiS.DispersionandRheologicalAspectsofSWNTsinUltrahighMolecularWeightPolyethylene[J].Macromole2cules,2006,39(2):658-666.[16]XieXL,AloysK,ZhouXP,etal.Ultrahighmolecularmasspoly2ethylene/carbonnanotubecomposites-Crystallizationandmeltingproperties[J].J.Therm.Anal.Calorim,2003,74(1):317-323.[17],,./UHMWPE[J].,1998,26(1):1-3.[18]XuGuoyong,WuWei-Tai,WangYusong,etal.Functionalizedcar2

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