超滤纳滤工艺在高盐印染废水处理中的应用及脱盐效果分析焦涛

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+(,210036):+,、pH,。:NaCl,CODTOC80%;5∶2,,63.4%60.3%,93.8%;pHCODTOC77.2%93.6%,98.4%,,9500mg/L563mg/L,94%,。:;;:X7:B:1674-4829(2010)06-0004-040,,,,。,。,2006,40×109m,30%。6,COD4,,,,,、,[1]。,,,、、COD、BOD/COD,、,、、,,、、[2-4]。、,,、、、、:2010-09-06:(1981-),,,,,.ApplicationofUltrafiltrationandNanofiltrationProcessinTreatmentofDyeingWastewaterwithHighSaltandItsDesaltingEffectJIAOTaoAbstract:Inthedyeingwastewatertreatmentprocessofultrafiltrationandnanofiltration,thetypeofsaltandpHofwastewaterwerechangedtoanalyzetheeffectsofrelevantfactorsonthewastewatertreatment.TheresultsshowthatthetotalremovalratesofCODandTOCaremorethan80%,respectively,byusingthemixtureofNaClconcentrationasthemainauxiliarywashing.Whenalkalinevatdyewastewaterinwhichsulfateisthemainadditiveandthefirstformedrinsewateraremixedby5∶2involume,thenanofiltrationprocesscanremoveelectricalconductivityandsaltwell,theremovalratesare63.4%and60.3%,respectively,andtherateofcolorremovalis93.8%.AfteradjustingpH,forthedyevattotalwastewater,thetotalremovalratesofCODandTOCare77.2%and93.6%,respectively,andtherateofcolorremovalis98.4%,meanwhile,itsdesaltingeffectiswell.Inthisprocesstotalsaltvolumecandecreasefrom9500mg/Lto563mg/L,andthedesalinationratearrivetoabout94%,whichcanreducethevolumeofsaltinthedischargedwastewater.Keywords:Ultrafiltration;Nanofiltration;Dyeingwastewater236201012EnvironmentalScienceandTechnologyVol.23No.6Dec.201023657606380208063.95320106049.081.6CODCr50364320659.1164987.4857.582.6TOCρρρ/%/%mg·L-12CODTOCρρ/%,[5-10]。+。+,,,。11.1:(1):。,,()。(2):,250L,5∶2,250L,80L。(3):H2SO4pH6.34,,。1.2,,:,;,,,、,、,、。,。1NF,2,2NF。1。22.12.1.1,1。2.1.2CODTOC,,CODTOC2,2。2,COD63.9%,TOC59.1%。COD49.0%;TOC57.5%。CODTOC,CODTOC80%,。2.1.3312、321423,3。3+,99%,3,,,,。2.1.44。4,NaCl,5.35%。11ρ(TOC)/(mg·L-1)367~503/(μs·cm-1)38.4~40.5ρ(CODCr)/(mg·L-1)3400~5760/3000~4500+/%/%4500510042006.710000899.899.830003125250016.75099.999.932142/%352010122.25。5,5∶2,pH12,ρ(TOC)441mg/L,ρ(CODCr)5330mg/L,,8/%/%/%/%pH6.346.726.79-8.487.65-8.569.05--ρ(TOC)3022882952.384958.380.218867.4-77.2ρ(CODCr)29903090231022.7815047579.489314868.893.6ρ(SO42-)29702050191035.71030078459.063215580.291.9ρ(Cl-)40026225735.8160279-6662712.9-ρ(Na+)3850358035607.51380071280.0173024665.493.1/(μs·cm-1)137001370013800-58300332075.97300137058.790.1ρ()9500110009310-3570089691.9140056337.294.9/5121020128754100893.832275.098.4ρ()369093--8-238--mg·L-1pH6.34ρ(TOC)302ρ(CODCr)2990ρ(SO42-)2970ρ(Cl-)400ρ(Na+)3850/(μs·cm-1)13700ρ()9500/512ρ()367mg·L-1TOCCOD37.6%14.4%。75%。SO42-,Cl-,Na+,,。6。pH12.068.978.24ρ(TOC)ρ(CODCr)ρ(SO42-)ρ(Cl-)ρ(Na+)/(μs·cm-1)ρ()//%-27580311358.945609540238047.86801370043236.5608180624-404013100162059.91970023600722063.41200014900476060.32050205012893.86mg·L-1/%/%38.4381.0435.17.638.592.432.410.822.34.565.35/(μs·cm-1)ω()/%/%4/%pH121212.06-ρ(TOC)441300027537.6ρ(CODCr)533015200456014.4ρ(SO42-)348114680-ρ(Cl-)31787.6608-ρ(Na+)395048604040-/(μs·cm-1)187002040019700-ρ()1220029000120001.6/81908190205075.05mg·L-16,128,4760mg/L。,,/0.2Pa/0.19Pa,3min,90L/h54L/h,,,,。2.32.3.1H2SO4pH6.34,,。518~530,7,pH,SO42-,COD。2.3.28。8,H2SO4pH6.34,SO42-680mg/L2970mg/L,SO42-35.7%,75%,。6236[12]LINY,WALMSLEYAR,ROSENBP.Anarsenicmetal-lochaperoneforanarsenicdetoxificationpump[J].PNAS,2006,103(42):15617-15622.[13]SELCKH,FORBESVE.Therelativeimportanceofwateranddietforuptakeandsubcellulardistributionofcadmiuminthedeposit-feedingpolychaete,CapitellaspI[J].MarineEnvironmentalResearch,2004(57):261-279.[14]STEENREDEKERE,CAMPENHOUTK,BERVOETSL,etal.Blust.SubcellulardistributionofCdintheaquaticoligochaeteTubifextubifex,implicationsfortrophicavail-abilityandtoxicity[J].EnvironmentalPollution,2007(148):166-175.[15]STORELLIMM,MARCOTRIGIANGO.Subcellulardis-tributionofheavymetalsinliversandkidneysofStenellacoeruleoalbaandTursiopstruncatesfromtheMediterraneanSea[J].BaselineMarinePollutionBulletin,2002(44):71-81.[16]LUISE,HEMANDEZ,ESTHERL,RODRIGUEZ,etal.Influenceofcadmiumontheuptake,tissueaccumulationandsubcellulardistributionofmanganeseinpeaseedlings[J].PlantScience,1998(132):139-151.[17],.[J].,2008,27(2):452-456.[18],.[J].,2005(2):1-5.[19],,.[J].,2006,27(2):147-151.[20],.[J].,2008,18(2):29-32.[21],.[J].,2009,24(5):19-22.[22],,,.Hg2+[J].,2009,37(33):16727-19728.[23],,.[J].,2009,28(1):31-37.()(3)!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!+2,ρ()563mg/L,ρ(SO42-)155mg/L,,,,ρ()9500mg/L563mg/L,94%,。ρ(TOC)67.4mg/L,ρ(CODCr)148mg/L,77.2%93.6%。3(1)NaCl,CODTOC80%,,99%,,5.35%。(2)5∶2,pH12,,63.4%60.3%,93.8%。(3)pHCODTOC,77.2%93.6%,,98.4%。,9500mg/L563mg/L,94%,。[][1],,.[J].,2005,31(8):46-48.[2],,.[J].,2000,26(10):33.[3],,,.[J].,2006(4):63-65.[4]SCHOEBERLP.Treatmentandrecyclingoftextilewastewater-casestudyanddevelopmentofarecyclingconcept[J].Desalination,2005,171(2):173-183.[5],,.TiO2[J].,2000(1):79-82.[6],,.PDMDAAC-[J].,2005,31(12):16-19.[7]MARCUCCIM,NOSENZOG,CAPANNELLIG,etal.Treatmentandreuseoftextileeffluentsbasedonnewultrafiltrationandothermembranetechnologies[J].Desalination,2001(138):75-82.[8]MARCUCCIM,CIARDELLIG,MATTEUUCCiIA,etal.Experimentalcampaignsontextilewastewaterforreusebymeansofdiffere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