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112Vol.1,No.12200712ChineseJournalofEnvironmentalEngineeringDec.2007PPCPs(,100084)(PPCPs),,PPCPs,PPCPsPPCPsPPCPs,PPCPs;,X508A167329108(2007)1220001209Progressofthestudiesonoccurrenceandfateofnewemergingmicro2pollutants2PPCPsinmunicipalwastewatersZhouHaidongHuangXiaWenXianghua(StateKeyLaboratoryofEnvironmentalSimulationandPollutionControl,DepartmentofEnvironmentalScienceandEngineering,TsinghuaUniversity,Beijing100084)AbstractPharmaceuticalandpersonalcareproducts(PPCPs)arenewlyidentifiedmicro2pollutantsintheenvironmentintherecentdecade.Theirenvironmentalriskisthethemajorconcerntillnow.Somerecentsur2veysshowedthatavarietyofPPCPswithdifferentconcentrationsexistedintheeffluentofmunicipalwastewatertreatmentplants(MWTPs),whichisoneofimportantwaysforPPCPsenteringintotheenvironment.ThispaperreviewsthestudiesontheoccurrenceandfateofPPCPsinthemunicipalwastewaterinconsideringtheanalyticaltechniquesforPPCPsinthemunicipalwastewater,theoccurrenceandbehaviorofPPCPsinMWTPsandthere2movalmethodforPPCPs.Besides,thecurrentstatusofstudiesonPPCPsinChinaisintroduced.SuggestionstofuturestudydirectionsonPPCPsinChina,especiallythoseinmunicipalwastewater,arehighlightedinordertoattractmoreattentiontoPPCPsinmunicipalwastewaterandfurthertherelatedinvestigations.Keywordspharmaceuticalandpersonalcareproducts(PPCPs);municipalwastewater;micro2pollutant;occurrenceandfate:(20721140019):2007-06-06;:2007-09-25:(1971),,,:E2mail:zhouhaidong@tsinghua.edu.cn,,,ng/Lg/L(pharmaceuticalandper2sonalcareproducts,PPCPs)[15]80,ng/L[6]PPCPs,(),[7,8]PPCPs,,,PPCPs,PPCPs,PPCPs[4],,1[5,9],,PPCPs[2,3,10,11]Vieno[12],5:(ibupro2fen)(naproxen)(ketoprofen)(diclofenac)(bezafibrate)5,5:01040142012301400114g/L;,25%,,,2500ng/L,35,,g/L[13,14]PPCPs,,PPCPs,PPCPs,PPCPs,PPCPs,1PPCPs,,,PPCPs,,,PPCPs(GC)(HPLC),1PPCPs,LC,LC/MSLC/MS/MS;,GC/MSLC/MS/MS,,ng/L,,,,,,GC/MSPPCPs,(acetylsalicylicacid)(ortho2hydroxyhippuricacid)(gentisicacid)[5],,,,(),PPCPs2PPCPs2.1PPCPs(2),PPCPs,PPCPsPPCPs;,(SRT)[11]2.2PPCPsPPCPs:CO2;(PPCPs);Layton[39]14C,4,,14C2172(14C2E2),84%,4%24h,70%80%14C2E2,14C2E290%212:PPCPs1PPCPsTable1AnalyticaltechniquesofsometypicalPPCPsinmunicipalwastewatersacetylsalicylicacidSPEGC/MS[15]salicylicacidSPEGC/MS[16]acetaminophenSPEGC/MS[17]ibuprofenSPEGC/MS[9]diclofenacSPEGC/MS/MS[18]clarithromycinPLELC/MS/MS[19]sulfamethoxazoleSPEHPLC/MS/MS[20]PLELC/MS/MS[19]norfloxacinASE+SPELC/FLD[21]SPELC/MS/MS[22]chloramphenicolSPEHPLC/DAD/FLD[13]clofibricacidSPEGC/MS[23]SPELC/MS/MS[24]bezafibrateSPEHPLC/MS/MS[20]172172ethinylestradiolSPELC/MS[25]LSE+GPCGC/MS[26]mestranolSPELC/DAD[27]diatrizoateSPELC/MS/MS[28]iomeprolUSE+SPELC/MS/MS[29]iopromideSPELC/MS/MS[30](AHTN)tonalideSPMELSEGC/MSGC/MS[31][32](HHCB)gallaxolideLLEGC/MSGC/MS[32][33]muskketoneLSE+GPC+SPEHRGC/MS[34]muskxyleneLSE+GPC+SPEHRGC/MS[35]caffeinSPEGC/MS[36]ifosfamideSPELC/MS/MS[37]propanololSPELC/MS/MS[36]carbamazepineSPEGC/MS[38]:LLE;LSE;SPME;SPE;GPC;USE;PLE;DAD;FLDHRGC14C255%65%,95%,14C2172(14C2EE2)1/25,24h,40%14C2EE214CO214C2E2,,EE214C(benzylpenicillin),(ceftriaxone)(trimethoprim)[40],25%,PPCPs,PPCPs,,(AHTN)(HHCB)213815g/g,61615g/g,2114g/g(AHTN)615g/g(HHCB),5,01200145g/g[29]PPCPs,,PPCPsTernes[41],,31Kd,Kd100L/kg,5%,Kd450L/kg,pHKd49005300L/kg,,50%60%PPCPs,,Miao[42](carbamazepine,CBZ)510,1122H210,112(CBZ2EP)1122H210,112(CBZ2DiOH)22(CBZ22OH)32(CBZ23OH)10,1122H2102(CBZ210OH)()CBZCBZ22OHCBZ23OHCBZ2DiOH6916119116715g/kg();,258113144131514g/kg2PPCPsTable2SometypicalPPCPsfoundinmunicipalwasterwatertreatmentplants(g/L)(g/L)acetylsalicylicacid12CAS,CAS+,Logoon13.70.106,2002[11]49++0.22,1996[16]sulfamethoxazole20.08,2001[3]30.01,2001[3]ibuprofen60.490.11,2004[25]1+3.590.15,2002[39]50.750.05,20012003[2]diclofenac3+FeCl31.21.1,20022004[46]7+,A2O0.350.27,2003[47]carbamazepine1356.1251.0,2003[45]30++2.1,1996[16]60.0480.112,2004[25]gemfibrozil20.70,2001[3]49++0.40,1996[16]metoprolol3Fe+1.130.99,2004[48]naproxen131281175,20012002[33]31.97,2001[3]2CAS0.092,2002[10]clofibrate10.8,2001[3]triclosan2CAS0.015,2002[10]50.510.026,20012003[2]ketoprofen1+0.580.18,1997[49]estrone12CAS,CAS+,Logoon0.02950.0076,2002[11]60.0440.017,2001[50]caffeine11470.19,2000[15]157.433.7,2002[51](AHTN)tonalide41.230.76,2001[34]12CAS,CAS+,Logoon2.0310.751,2002[11](HHCB)gallaxolide43.181.69,2001[34]12CAS,CAS+,Logoon0.8040.274,2002[11]iopromide16.609.30,20012002[33]diatrizoate1FeCl2+3.34.1,1998[32]CBZ5,CBZ29%,,CBZ,CBZ2DiOH,PPCPs412:PPCPsCarballa[30]PPCPs(283),,,30%50%;E2,20%;()(35%75%),70%90%,65%,60%,E265%[43],,70%(+),30%(FeCl3+),;;,27%;,19%,4%,8%,20%(mefe2namicacid),40%30%,4%3PPCPsPPCPs()[50,51];(AOP),O3H2O2/O3[52]ClO2[53][54][3]UV[42];[55];[56]Ternes[50],(),E2E1,E1EE2,,EE2PPCPs[51],,,,20%60%(AOPs),PPCPsAOPs(OH),PPCPsO3AOPsTernes[52]O3O3/UVO3/H2O2,,PPCPs(55242142)O31015mg/L,18min,,PPCPsO315mg/L,14%,80%O3/UVO3/H2O2,O3ClO2UV,PPCPsClO2[53]EE2,,,,UV,,HHCB,AHTNUV[42],,UV,,,,PPCPsNowotny[55](PAC)1048PAC10mg/L(),,,70mg/L,()1%PAC100mg/L,80%Cartinella[56](DCMD)(FO)E1,E2(MD),()MD,,DCMDMD,()51(),,FO,RODCMD29915%,;FO,77%99%4PPCPs2003,,2004,6700,16000,28000t(60%),10000t(65%),,70%[13](OTC)