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223Vol.22,No.320069JournalofShanghaiUniversityofElectricPowerSep.2006:1006-4729(2006)03-0249-053:2006-08-23:(P1304).1,1,2(1.,200090;2.,310032):,H2O2,,.:;;:TQ085+.4;TQ123.2:ANewTechnologyStudyonOzoneMethodsAppliedtoIndustrialWastewaterTreatmentZHENGHong2ai1,ZHANGDa2quan1,PANLi2li2(1.SchoolofThermalPower&EnvironmentalEngineering,ShanghaiUniversityofElectricPower,Shanghai200090,China;2.CollegeofBiology&EnvironmentalEngineering,ZhejiangUniversityofTechnology,Hangzhou310032,China)Abstract:Researchanddevelopmentaboutionizationmethodsappliedtoindustrialwastewatertreatmentinforeigncountriesarereviewedinthispaper.Ontheotherhand,thetechnologiesofOzonecombinedwithultrasound,UV,H2O2andactivatedcarbonappliedinwatertreatmentareintroducedinthispaper.Themethodcandeposeofwasterwaterwithoutpollutionandcanbeoperatedconveniently.Itindicatesthationizationtechnologyhaswideapplicationprospectsinwatertreatment.Keywords:Ozone;ultrasound;activatedcarbon20062005,,.,.,[1],,,pH,.,,,,,[2].,[3].,.©1994-2007ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[3],[46].11.1.,(D)(OH)(R).D,;R,.[7,8],.,.1.2,.[9,10],[11],..BODCOD,,.,32.4mg/L,3min,[12].(OH),.,;.,10h,pH78,COD86.6%,98.4%[13].,pH7,O3OH,[14].:[15].16L/h1kg/h,pH10,2h,COD60%.,.,10100m,20004000,5,,.,,[16].,,[17].,.,,,[18].,.(AOTs),(AOPs),,(2.80V).2,O3UV,H2O2,Fe3+[19]..2.1,[20]..,,.I[21].:I,I0522006©1994-2007ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[22].23.1;2;32(),,.,.2.2O3/UVO3/UV,().O3/UV2070,.80,O3/UV,,,,,,,.,O3/UV,.,,CO2.,B/C.O3/UVTNT[23].TNT,,,254nm,O3/UVTNT.,,.pHTNT,,pHTNT.2.3O3/H2O2O3/H2O2,,CO2.H2O2,,O3/H2O22200,[24].,O3H2O2[25,26].PO3,;PO3,,,O3.pH7,O3O3,H2O2,HO2-,..AlisafarzadehO3/H2O2MTBE()[27].MTBE,20,,,,MTBE2.0mg/L.,,MTBE95%,2001,MTBE;,,.MTBE,.AlisafarzadehO3/H2O2MTBE,[27],UV/H2O2.:O3/H2O2MTBE;MTBE,.O3/H2O2,UV/H2O21/3,O3/H2O2152:©1994-2007ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[28]:,Br-Br-BrO-,Br-BrO-..O3/H2O2,H2O2,Br-,,.2.4/,OH-,,OH.,OH,.,,.,,/3[29].,,/3,../5,,1..,Jans[30].,,,O3/H2O2O3/UV.O3.,,:O3+();O3++;O3+;O3+;O3+H2O2+UV;O3+[31].3,,.,.,.:[1],.[J].,1997,(6):28233.[2].[J].,1992,(12):1462149.[3].[J].,1997,15(4):2652268.[4]HoigneJ.ChemistryofAqueousOzoneandTransformationofPollutantsbyOzonationandAdvancedOxidationProcess[J].TheHandbookofEnvironmentalChemistry,1998,21(8):842141.[5]CamelV,BermondA.TheUseofOzoneandAssociatedOxi2dationProcessesinDrinkingWaterTreatment[J].WaterResearch,1998,32(11):320823222.[6]BdlfahdelH,RatekA,QuedermiA,etal.RemoveofColourandOrganicMattersinIndustrialPhosphiricAcidbyOzone2EffectonActivatedCarbonTreatment[J].Proceedingsofthe21thWorldCongressoftheInternationalOzoneAssociation,1995,(2):498.[7]ChurcheleyJH.OzoneforDyeWasteColourRemoval:FourYearsOperationatLeekSTW[J].OzoneScience&Engineering.1998,20(1):1112120.[8]HostachyJC,lenonG,PisicchioJL,etal.ReductionofPulpandPaperMillPountionbyOzoneTreatmeant[J].WaterSci.Tech,1997,35(2):2612268.[9]BdlfahdelH,RatekA,QuedermiA,etal.RemoveofColorandOrganicMattersinIndustrialPhosphiricAcidbyOzone2EffectonActivatedCarbonTreatment[J].Proceedingsofthe21thWorldCongressoftheInternationalOzoneAssociation,1995,(2):5012508.[10]ChurcheleyJH.OzoneforDyeWasteColourRemoval[J].InternationalOzoneAssociation,1998,20:124.[11]HostachyJC,LenonG,PisicchioJL,etal.ReductionofPulpandPaperMillPountionbyOzoneTreatmeant[J].WaterSci.Tech,1997,35(2):270.[12].[J].,1997,(2):32234.[13],,.[J].,1999,(10):16217.[14],,.[J].,1999,18(1):13215.2522006©1994-2007ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[15],.[J].,2000,15(2):18219.[16].[J].,2001,21(5):310.[17],.[M].:,2003.11.[18].[M].:,2001.248.[19]RG,A.[M]..:,1991.81.[20].[J].,2000,20(9):58260.[21],,,.[J].,1999,15(11):124.[22]Henderson.MethodofApplyingOzoneandSonicEnergytoSterilizeandOxidizeWaster[P].US:1977,40(3):32.[23].TNT[J].,2001,27(10):53256.[24],,.[J].,1997,(12):16219.[25],,.[J].,1998,17(4):51253.[26]ZhongLi.DegradationofOrganicPollutantsbytheAdvan2cedOxodationProcesses[J].ChinaJouralEngineering,1999,7(2):1102115.[27]Alisafarzadeh.O3/H2O2TreatmentofMethy2tert2Butyl2Ether(MTBE)inContaminatedWaters[J].WasteResearch,2001,35(15):370623714.[28].[J].,2000,26(5):11214.[29],,,./[J].,2000,20(2):1592162.[30]Jans,Urshoigne,Jurg.ActivatedCarbonBlackCatalyzedTran2sformationofAqueousOzoneintoOH2radicals[J].Ozone,ScienceandEngneering,1998,20(1):67289.[31]StevenT,Summerfelt.OzonationandUVIrradiationanIntr2oductionandExamplesofCurrentApplications[J].AquacuralEngineering,2003,28:21236.(248):[1],,,.[M].:,2002.1722174.[2].[M].:,1998.2072218.[3].[J].,2000,8(4):4472453.[4].[J].,2003,23(1):32235.[5],.[J].,2000,17(6):21223.[6],,.[J].,2004,18(1):20222.352:©1994-2007ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.