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206200712POLLUTIONCONTROLTECHNOLOGYVo.l20,No.6Dec.,2007,((),257061):,//,,:;/;/;/:X7031:AApplicationofAdvancedOxidationTechnologieswithO3toWastewaterTreatmentLIJing,LIUGuorong(CollegeofMachineryandElectronicChinaUniversityofPetrolum,Dongying,Shangdong257061,China)Abstract:Anewozonationtechnologyisdevelopedrecently,whichisusedtoremoveorganicpollutants.Theapplicationofozonationtechnologytowastewatertreatmentinrecentyears,includingozoneoxidation,O3/H2O2,O3/UV,ozonereinforcementwithactivatedcardonarereviewed,andtheircharacteristics,principlesandresearchprogressaredescribed.Anefficienttreatmentalternativeforwastewaterisprovidedbytheozonationtechnology.Keywords:advancedoxidationtechnology;ultravioletradiation;hydrogenperoxide;activatedcarbon:2007-07-23:(1983),,,,(2.07V,,),,,(AOTs),(AOPs),,(2.80V),,[1]11.1,,[2,3],[4]BODCOD,Part[5],32.4mg/L,3min,[6],10h,pH7~8,COD86.6%,98.4%,pH7,OH,[7][8]:5620616L/h1kg/hpH=10,2h,COD60%,[9],10~20mg/L,5~20min,COD40%BOD70%SS60%20%80%90%[10],,10~100m,2000~40005,,,,[11],,[12,13]1.2O3/UVUV/O3,[14,15][16]:O3+hO+O2O3+h+H2OH2O2+O2O+H2O-OHH2O2+h-OH70,Garrison,UV/O3,,UV/O3,,[17,18][19]UV/O3:120W,(O3)10mg/LpH6.7180min,TOC95%/[20]CCl4:2h,CCl490%UV/O3(PCBs)[21],[22];Peyton[23][24,25],UV/H2O2,UV/O3,O3H2O2O3/UVTNT[26],,O3/UVTNTO3/UVO3,,Jun-ichiroHayashi[27],O3/UV101.3O3/H2O2O3/H2O2,CO2H2O[16]:O3+OHHO2+O2OH+H2O2HO2+H2OHO2O2+H+H2O2,,O3/H2O22~200[28][29,30],O3H2O2,PO3,,[31]:PO3,,O3O3O3H2O2,,pH7Alisafarzadeh[32]O3/H2O2MTBE()MTBE,20,,,,MTBE2.0mg/L,,MTBE95%,2001MTBE,,;,,MTBEAlisafarzadehO3/H2O2MTBE,,UV/H2O2,O3/H2O220071257MTBE,;MTBE,MTBEO3/H2O2,UV/H2O21/3,O3/H2O2UV/H2O2,,,Br-Br-BrO-,Br-BrO-,O3/H2O2,H2O2,Br-,,1.4/[33],,3,,/3;,,/5,,1,[34],,,O3/H2O2O3/UV,,,,,,3,/,,,(2.80V)35%,,,:,;,,,,,[][1].[J].,1997,15(4):265-268.[2]BdlfahdelH,RatekA,QuedermiA,eta.lRemoveofColourandOrganicMattersinIndustrialPhosphiricAcidbyOzoneEffectonActivatedCarbonTreatment[J].Proceedingsofthe21thWorldCongressoftheInternationalOzoneAssociation,1995,1(2):501-508.[3]HchurcheleyJ.OzoneforDyeWasteColourRemova:lFourYearsOperationatLeekSTW,OzoneSci-ence&Engineering[J].JounalofInternationalOzoneAssociation,1998,20:111.[4]HostachyJ-C,1enonG,PisicchioJ-L,eta.lReductionofPulpandPaperMillPountionbyOzoneTreatme-ant[J].WatSciTochJoumalofIAWQ,1997,35(2-3):261-268.[5].[J].,1997(2):32-34.[6],,.[J].,1999(10):16-17.[7],,.[J].,1999,18(1):13-15.[8],.[J].,2000,15(2):18-19.[9]Won-TaeShin,XandraGaranzuay,SotiraYiacoum,ieta.lKineticsofSoilOzonation:anExperimentalandNumericalInvestigation[J].JournalofContaminantHydrology,2004,72:227-243.[10]ChenaYH,ChangaCY,ChiuCY,eta.lDynamicBehaviorofOzonationwithPollutantinaCountercurrentBubbleColumnwithOxygenMassTransfer[J].WaterResearch,2003,37:2583-2594.[11].[J].,2001,21(5):310.[12],.[J].,2003,8(14):89-91.(116)116206,,55.1C-orbalC-Orbal/,,,,:30%~40%,20%~30%,25%~30%,30%C-Orbal,,,1500,1400,5.21m,,5.5kW,,,,,,,,,,,,5.3,,,(57)[13],,.[J].,2003,22(1):9-12.[14]FernandoS,GarciaEinschlag,LucianoCarlos,eta.lCapparell.iCompetitionKineticsUsingt-heUV/H2O2Process:aStructureReactivityCorrelationfortheRateConstantsofHydroxylRadicalsTowa-rdNitroaromaticCompounds[J].Chemosphere,2003,53:1-7.[15],,,.-[J].,2004,Vol(No):192-195.[16].Fenton[D]:,[].[17]StevenTS.OzonationandUVIrradiation:anIntroductionandExamplesofCurrentApplications[J].AQuaculturalEngineering,2003,28:21-36.[18]./[J].,2003,23(5):284-297.[19],[M].:,200112.[20],,.UV/O3CCl4[J].,1997,14(2):54-56.[21],.[J].,2001(6):104-106.[22],,,.O3/UV[J].,1996,15(4):313-319.[23]PeytonGR,HuangFY,BurlesonJL,eta.lDestructionofPollutantsinWaterwithOzonecombinationwithUltravioletRadiation,GeneralPrinciplesandOxidationofTetrachlorethylene[J]EnvironSciTechno,l1982,16:448-453.[24]KearneyPC,MuldoonMT,SomichCJ.UV-ozonationofElevenMajorPesticidesasDisposalPretreatment[J].Chemsophere,1987,16:2321-2330.[25]PreisS,KamenevS,KallasJ,eta.lAdvancedOxidationAgainstPhenolicCompoundsinWasteWaterTreatment[J].OzoneSci&Engng,1995,17:399-418.[26].TNT[J].,2001,27(10):53-56.[27],,.[J].,2004,18(3):5-8.[28],,.[J].,1998,17(4):5153.[29]RamirezIM,AsquezMT.RemovalandTransformationofRecalcitrantOrganicMaterfromStabilize-dSalineLandfillLeachatesbyCoagulationOzonationCouplingProcesses[J].WaterResearch,2004,38:2359-2367.[30]NiwootiW,VeronicaP.MetalStrategiesforAlkalinityandpHControlforOzonatedShrimpPondWater[J].AquaculturalEngineering,2004,30:1-13[31]MuthukumarM,SelvakumarN.StudiesontheEfectofInorganicSaltsonDecolourationofAcidDyeEfuentsbyOzonation[J].DyesandPigments,2004,62:221-228.[32]Alisafarzadeh.O3/H2O2TreatmentofMethy-tert-Butyl-Ether(MTBE)IncontaminatedWaters[J].WasteResearch,2001,35(15):3706-3714[33].[J].,2002,20(4):278-280.[34]Jans,UrsHoigne,Jurg.ActivatedCarbonBlackCatalyzedTransformationofAqueousOzoneIntoOHRadicals[J].Ozone:ScienceandEngneeri-ng,1998,20(1):67-89.