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。。*2014ZZ0062。*510640。。X793A1671－4571201406－0155－07。《》GB3544—2008。。COD、。、、1。2。、、、、、、、、、、、3。、、4。5。、。11．1、、。1．1．1。、。90%、、BODCOD。。1．1．2、、、551《》2014336、、pH。、、、、、。1．1．3。、、、、COD。。1．261。2。、、、3。4。BOD/COD0．150．255。。22．12．1．115%。0℃、0．1MPa2．14g/L－111℃－192℃。。。7。2．1．2。1。1/V·OH·OH+H++e→H2O2．80O3O3+2H++2e→O2+H2O2．07H2O2H2O2+2H++2e→H2O1．77HClOHClO+2H++2e→2Cl－+H2O1．63Cl2Cl2+2e→2Cl－1．358。。8。、、、、。。。9。2．210·OHCO2H2O。2．2．1V116.5°π。、、、11。2．2．212O3+H2O→2HO·+O2①O3+OH－→O·－2+HO2·②O3+HO·→O2+HO2·O－2·+H+③O3+HO2·→2O2+HO·④651PaperScience＆Technology2014Vol．33No．62HO2·→O2+H2O2⑤pH。pH＜4pH＞10。pH=7。·OHCO2H2O。106109M－1S－1·OH。·OH13①·OH②③·OH。2．32．3．1pHpHTOC、CODBOD/COD。。pH14。2．3．2TOC。15。2．3．3。。。2．3．4TOC、COD。TOC、COD。BOD/COD。16。2．42．4．11·OH2、、、·OH3O3O2O3O34O356。2．4．212TOCCOD3。2．5、、。Fenton。751《》2014336CO2H2OTOCCOD、。。123UV、H2O2AOP。17。2．5．1、。。SchmidtT18—87%97%CODcr97%BOD5。LeilaBijan19—CODcr50%80%。2．5．22．07V。W．DelosSantosＲamosa20—0．0670．29。21—20min1618minCODcrSS99%。2．5．3UV、H2O2AOPAdvancedoxidationprocessesAOP1987Glaze。、、。Glaze·OHAOPsAOPAOPO3/UV、O3/H2O2、UV/H2O2、H2O2/Fe2+Fenton22O3/UVO3/H2O2。Torrades23/TOCCODcrAOX。24O3/H2O2COD300mg/L95．250mg/L35045NTU。3CODTOC。。O3/H2O2、UV/O3、UV/H2O2、UV/H2O2/O3、TiO2/UVCWAO·OH。851PaperScience＆Technology2014Vol．33No．6、。804。3．1。Fe2+、Mn2+、Ni2+、Co2+、Cd2+、Cu2+、Ag+、Cr3+、Zn2+d。·OH。·O－2·O－2O3·O－3·OH25。1983L．Forni26Fe2+Fe2+O3Fe3+O－3·OH。·OHFe2+Fe+3OH－。2000Ｒ．dreozzi27pH=3Mn4+O3。25℃30minO30Mn4+22%。。3．2、、。。。B．Legub28·OH。·OH。·OHCO2H2O。329①②③。·OH。M．Ernst30Al2O3、、、4。Al2O387．5%。17TiO212minCODcr96．88%54．38%12．31%21．74%BOD5/CODcr0．350．21。Al、Cu、Mn、Fe、Ti、、。。4951《》2014336“”。。。12、34。1．J．2010251102－107．2GottschalkCLibraJASaupeA．Ozonationofwaterandwastewa-terJ．WeinheimWiley－VCH200030－35．3．J．2003129－31．4．—J．2001271626－29．5ＲivasFJCarbajoMBeltránFJetal．Perovskitecatalyticozona-tionofpyruvicacidinwateroperatingconditionsinfluenceandki-neticsJ．AppliedCatalysisBEnvironmental2006621/293－103．6．J．200524558－60．7KreetachatTDamrongsriMPunsuwonVetal．Effectsofozonationprocessonlignin－derivedcompoundsinpulpandpapermillefflu-entsJ．J．Hazard．Mater20071421/2250．8FontanierVFarinesVAlbetJetal．StudyofcatalyzedozonationforadvancedtreatmentofpulpandpapermilleffluentsJ．WaterＲes2006402303．9MezaPＲFelissiaFEAreaMC．ＲeductionoftherecalcitrantCODofhighyieldpulpmillseffluentsbyAOP．Part1．Combinationofo-zoneandactivatedsludgeJ．Bioresources2010621053．10ＲosalＲGonzaloMSＲodriguezAetal．Catalyticozonationoffenofibricacidoveralumina－supportedmanganeseoxideJ．J．Hazard．Mater20101831/3271．11．D．2006．12MasscheleinW．J．UnitprocessesindrinkingwatertreatmentM．NewYorkMarcelDekker199254－100．13．D．200512－13．14BijanLMohseniM．UsingozonetoreducerecalcitrantcompoundsandtoenhancebiodegradabilityofpulpandpapereffluentsJ．Wat．Sci．Tech2004503173．15BijanLMohseniM．Integratedozoneandbiotreatmentofpulpmilleffluentandchangesinbiodegradabilityandmolecularweightdis-tributionoforganiccompoundsJ．WaterＲes200539163763．16．J．201332555－61．17．TiO2D．2011．18AssalinMＲAlmeidaEDDuranN．CombinedsystemofactivatedsludgeandozonationforthetreatmentofKraftE1effluentJ．Int．J．Environ．Ｒes．PublicHealth2009631145．19LeilaB．JMohseniM．IntegratedozoneandbiotreatmentofpulpmilleffluentandchangesinbiodegradabilityandmolecularweightdistributionoforganiccompoundsJ．WaterＲesearch2005393763－3772．20ＲamosaW．D．SPoznyakTChairezIetal．Ｒemediationoflig-ninanditsderivativesfrompulpandpaperindustrywastewaterbythecombinationofchemicalprecipitationandozonationJ．Jour-nalofHazardousMaterials2009169428－434．21．—J．200121134－36．22HordernB．KZioekMNawrockiJ．Catalyticozonationandmeth-odsofenhancingmolecularozonereactionsinwatertreatmentJ．AppliedCatalysisBEnvironmental200346639－669．23TorradesFPeralJPerezMetal．Ｒemovaloforganiccontami-nantsinbleachedkrafteffluentsusingheterogeneousphotocatalysisandozoneJ．TappiJ200184663．24．O3/H2O2J．201238375－7983．25．J．200727178－82．26ForniLBahnemannDHartEJ．MechanismofFeⅡinitiateddecompositionofozoneinaqueoussolutionJ．J．Phys．Chem1982862255－259．27AndreozziＲSimonaMMarottaＲ．N－methyl－p－aminophenolmetolozonationinaqueoussolutionkineticsmechanismandtoxicologicalcharacterizationofozonizedsamplesJ．WaterＲe-search200034184419－4429．28LegubeBLeitnerKVelN．Catalyticozonationapromisingad-vancedoxidationtechnologyforwatertreatmentJ．CatalysisTo-day199953361－72．29Kasprzyk－HordernBZióekMNawrockiJ．Catalyticozonationandmethodsofenhancingmolecularozonereactionsinwatertreat-mentJ．AppliedCatalysisBEnvironmental2003464639－669．30ErnstMLurotFSchrotterJC．Catalyticozonationofrefractoryor-ganicmodelcompoundsinaqueoussolutionbyaluminumoxideJ．AppliedCatalysisBEnvironmental200447115－25．061PaperScience＆Technology2014Vol．33No．6ProgressofPulpMillEffluentAdvancedTreatmentwithOzoneChengZhengYangＲen-dangYangFeiStateKeyLabofPulp＆PaperEngineeringSouthChinaUniversityofTechnologyGuangzhou510640GuangdongChinaAbstractInthispaperthepropertiesofozoneandbasicmechanismsofozonationweredescribedindetailtherecentresearchprogressofthepulpingeffluenttreatmentwithozonationandcatalyticozonationtechnologywasreviewedTheexistingproblemsaboutozonationwerealsopointedout．Catalyticozonationbysupportsandsuppo