臭氧移动床生物膜组合工艺深度处理制革综合废水中试陈华东

－121131.2500132.2500133.250013－、COD、UV254、20mg/L40min。MBBＲ15h－COD、、GB18918—2002《》ACOD41～50mg/L、0.5～0.7mg/L、10～20。STUDYONADVANCEDTＲEATMENTOFLEATHEＲINTEGＲATEDWASTEWATEＲBYO3-MBBＲPＲOCESSChenHuadong1YuHongxia2WangＲui1TengLong1YinXiuzhen31.EnvironmentalEngineeringCoLtdShandongAcademyofEnvironmentalScienceJinan250013China2.ShandongAcademyofEnvironmentalScienceJinan250013China3.ShandongGeologicalProspectingInstituteofChinaChemicalGeologyandMinesGeneralBureauJinan250013ChinaAbstractApilot-scaleprocesscombinedozonewithmovingbedbiofilmreactorMBBＲwasappliedintheadvancedtreatmentofleatherintegratedwastewaterofaleatherindustryparkinHebeiProvince．TheeffectofozonedosageandcontacttimeontreatmentefficiencyofCODUV254andchromaticitycolorwasinvestigated．Theresultsshowedthatthebesttreatmentconditionswereozonedosageof20mg/Lcontacttimeof40min．OntheseconditionsaswellasMBBＲ’sHＲTof15htheeffluentofO3-MBBＲprocessmetthefirstlevelAcriteriaspecifiedintheDischargeStandardofPollutantforMunicipalWastewaterTreatmentPlantGB18918—2002withCODof41～50mg/LNH3－Nof0.5～0.7mg/Landchromaticitycolorof10～20．Keywordsleatherintegratedwastewateradvancedozoneoxidationprocessmovingbedbiofilmreactoradvancedtreatment2016－05－22、Cr3+、、、、1。COD、、。－O3-MBBＲ23-6COD、。MBBＲ、7、8、9、10。MBBＲ。012201634“－/A/O”。CODρCOD80～100mg/L、ρ6～10mg/L。GB18918—2002《》A。O3-MBBＲ、、、UV254。11.1、50%30%20%“－/A/O”COD、、A1。1COD/mg·L－1/mg·L－1SS/mg·L－1pH400～80040～70200～50080～1007～9A/O80～1005～1020～3040～607～9≤50≤5≤10≤306～91.2－1。A/OCF-G-3-30。MBBＲ。MBBＲ4000～5000mg/L30%15h3～5mg/L。11.310.5m3/h10204060mg/L40minCOD、UV254、。230405060minCOD、UV254、。3O3-MBBＲCOD、、。1.41COD。11。2UV254。－UV7651cm254nm365nm12。3。11。4。11。22.12.1.1CODCOD2。COD80～100mg/L10204060mg/LCOD45～67mg/L27.66%、37.61%、41.82%、43.36%。COD13O3-BAF。20mg/L60mg/LCOD5.75%1411220163420mg/L。—■——●——△—。2COD2.1.2UV254UV2543。UV2540.839～0.94510204060mg/LUV2540.187～0.477cm－151.23%、66.75%、71.51%、75.80%COD。UV254CODUV25415CCCOUV25416Wang17。20mg/L。—■——●——△—。3UV2542.1.34。80～10010204060mg/L5～2079.97%、85.59%、91.53%、92.25%。10mg/L2018。40mg/L。COD20mg/L。—■——●——△—。42.22.2.1CODCOD5。COD86～99mg/L20mg/L30405060minCOD51～66mg/L30.61%、36.82%、38.97%、40.66%。COD40minCODCOD40min。—■——●——△—。5COD2.2.2UV254UV2546。UV2540.85～0.99cm－120mg/L30405060minUV2540.27～0.37cm－164.89%、65.62%、66.96%、67.84%。UV254UV254212201634。COD40min。—■——●——△—。6UV2542.2.37。80～10020mg/L30405060min10～2085.57%、85.25%、86.46%、84.52%。。COD40min。—■——●——△—。72.3－2.3.1COD20mg/L40minMBBＲ15hO3-MBBＲCOD8。COD83～97mg/LCOD52～60mg/LMBBＲCOD41～50mg/LCOD46.51%～52.08%。O3-MBBＲCODA。2.3.220mg/L40min—■——●——▲—MBBＲ。8O3-MBBＲCODMBBＲ15hO3-MBBＲ9。5.6～9.7mg/L5.5～9.7mg/LMBBＲ0.5～0.7mg/L90.87%～94.02%。19MBBＲO3-MBBＲA。—■——●——▲—MBBＲ。9O3-MBBＲUV2542.3.320mg/L40minMBBＲ15hO3-MBBＲ10。80～10010～20MBBＲ10～20。MBBＲO3-MBBＲA。31COD、UV25420mg/LUV254、312201634—■——●——▲—MBBＲ。10O3-MBBＲCOD。20mg/L。2COD40minCODUV254、。40min。3O3-MBBＲCOD、、GB18918—2002ACOD41～50mg/L、0.5～0.7mg/L、10～20MBBＲ。1．M．20101-10.2Beltran-HerediaJTorregrosaJDonminguezJＲetal．Kineticsofthereactionbetweenozoneandphenolicacidspresentinargo-industrialwastewatersJ．WaterＲesearch20013541007-1085.3．J．2010312363-367.4SomensiCASimionattoELBertoliSLetal．Useofozoneinapilot-scaleplantfortextilewastewaterpre-treatmentPhysico-chemicalefficiencydegradationby-productsidentificationandenvironmentaltoxicityoftreatedwastewaterJ．JHazardMater20101751/3235-240.5Arslan．Treatbilityofasimulateddispersedye-bathbyferrousironcoagualtionozonationandferrousiron-catalyzedozonationJ．JHazardMater2001853229-241.6BilaDMMontalvOAFSilvaACetal．OzonationofalandfillleachateevaluationoftoxicityremovalandbiodegradabilityimprovementJ．JHazardMater20051172/3235-242.7．MBBＲJ．201023436-37.8JahrenSJＲintalaJAOdegaardH．AerobicmovingbedbiofilmreactortreatingthermomechanicalpulpingwhitewaterunderthermophilicconditionsJ．WaterＲesearch20023641067-1075.9JingJieyingFengJieLiWenyingetal．ＲemovalofCODfromcokingplantwastewaterinthemovingbedbiofilmsequencingbatchreactoJ．KoreanJChemEng2009262564-568.10．MBBＲD．2007.11．M．4．2002.12．UV254J．2006122-24.13．－J．20137124799-4804.14．/J．2007232181-84.15．/J．2006261132-36.16．J．200733230-33.17WangShutaoMaJunLiuBaicangetal．DegradationcharacteristicsofsecondaryeffluentofdemesticwastewaterbycombinedprocessofozonationandbiofiltrationJ．HazardMater20081501109-114.18．J．200523433-36.19．//J．2009251573-75.1979－。櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅櫅[e-mail]15410．J．2013391173-76.11．/J．2015314744-750.12．J．200925541-44.13．ZetaJ．20102339-11.14CornwelDAＲamonGL．ＲecyclestreameffectsonwatertreatmentC//Proc．ofAWWA．Denver1993312-328.15ZahnowJCJoeranMUlrikeF．Parrical-basedmodelingofaggregationandfragmentationprocessFractal-likeaggregatesJ．PhysD2004240882-893.1990－。[e-mail]1973－。[e-mail]412201634