磁化水的物理化学性能

261()Vo1.26,No.119992JournalofHunanUniversity(NaturalSciencesEdition)Feb.1999X(,,410082),pH,,,,LL,,,Q55.8,Q64PhysicalandChemicalPropertiesofMagnetizedWaterZhuYuanbaoYanLiushuiCaoZhixiangWeLingfeiChenZongzhang(CollegeofChemistryandChemicalEngineering,HunanUniv,410082,Changsha,PRChina)AbstractInthispaper,theconductivity,pH,dissoivedoxygen,density,evaporativ2ityandIR,NMR,UVspectrumofmagnetiewaterundervariousmagnetizedconditionhavebeenstudied.ItisfoundthatpH,dissoivedoxygenandevaporativityareincreased,UVabsorptionpeakanddensityaredecreased,andthechangeofconductivityofmag2neticwaterdependsonmagneticstrenth.Thesolubilutyofcalciumcarbonatein150mTmagneticfieldremarkablyisincreasedandnoremarkabledifferenceforIRorNMRspectumexists,comparingwiththenon2magneticwater.Apossiblemechanismforthestructralchangeofmagueticwaterisproposed.Keywordsmagnetizedwater,conductivity,dissoivedoxygen,magneticfield,[1].,,,L[13],,L,,,LpH,,LX:1998208210.,,60,©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(45mT)L1.1,150mT,80mT(45mT)4h,L1L1JpH(25)ömTJö(Lsõcm-1)pHJö(Lsõcm-1)pH(45)1.706.02187.87.882.205.94201.27.56-0.50+0.08-13.4+0.32805.906.74221.07.545.286.63213.27.12-0.62+0.11+7.8+0.421501.966.16207.87.532.206.02218.47.38-0.24+0.14-10.6+0.151,(45mT),150mT;80mT,LLpH,L1.280mT,pH,12L,3,pH,L,L:;L1.370min,,3L,L210mL,L,2L22()1999©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(2h,19)ögög0mT55mT80mTQö(gõcm-3)0mT55mT80mT9.957120.026220.023120.02111.006911.006671.006479.956920.026520.025320.02511.006961.006841.006829.956820.026620.023820.02351.006981.006701.006673É.Ê.Ë.a.b.,,L,L3,,,L,,,10min,3L321:©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(23)gömin80mT55mT80mT066.4504-66.2946-61.1041--64.08391066.44990.000466.29330.001361.10360.000564.08210.00182066.44950.000466.29240.000961.10260.001064.08010.00203066.44890.000666.29110.001361.10190.000764.07920.00094066.44860.000366.28990.001261.10080.001164.07800.00125066.44820.000466.28900.000961.10010.000764.07630.00176066.44790.000366.28780.001261.09980.000364.07570.00066066.44790.000366.28780.001261.09980.000364.07570.00061h-0.0024-0.0068-0.0043-0.0082,,,L,L4[2]36h0.25mLömin150mTDO,4L4DO(mgõL-1)ömT$DO$DODO100%(20)4509.93,10.21,10.04,10.07,10.129.27,9.27,9.26,9.29,9.2610.079.270.808.6(25)15008.65,8.70,8.76,8.76,8.758.08,8.17,8.38,8.34,8.348.728.260.465.64(25)É.Ê.(150mT)4,150mT,L,L5,,CaCO3,L150mT,LL4L42()1999©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[3]51.69%L,,,Ca2+L6150mT24h,L80mT5200mT,LShimadzuUV2265,,190230nm,193nmL,,L5LL7,,LL,,LLL?,L,(H2O)nxH2O+(H2O)n-x,L,,,;,,,;(32)521:©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.),L,460,L2),,L3),,L4),:40LmL1,..:,1989.192..:,1990.2373KitaY,WatanabeN,FujiY.Chemicalcompositionandcrystalstructureofgraphitefluoride.JAmerChemSoc,1979,101(4):383238414LagowRJ,BadachhapeRB,WoodJL,etal.Somenewsyntheticapproachestographite2flnoridechemistry.JChemSocDaltonTrans,1974,12:12681273(25),,,LBurtonDaly,L,:B+OHH(OHH)nOHHA-,L,pH,,,L,,,L,,,,L1...:,1982.1192..:,1975.313,.:.3.:,1980.2623()1999©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.