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20043ENVIRONMENTALSCIENCETRENDSNo13,2004(,,410082),(CWPO)H-,,MnO2-CuO-CeO2-Fe2O3,,pH=57,30min,COD80%,90%(CWPO);;;H-:X13112:A:1003-2347(2004)03-0029-03,,,,,,1MnCuCeSnAgBiFeZnTi,:(H2O2),,(CatalyticWetHydrogenPeroxideOxidationCWPO),21111CTL-12,721,WXY-401,HJ-3,PHS-2,S-570();;COD,,;1121pH,,,,;,,,123,,Al2O3,,(),10%3,,pH1113H-J-,H-(1--8--3,6-,C10H8O7S7NNa,341,,),:COD=2380mg/L,pH518;=271mg/L;286;SS=192mg/L11430min,H-COD,转载(%)2AMnO2-SnO2-Ag2O-Bi2O34501111BCuO-ZnO-CoO-Cr2O35501111CMnO2-CuO-CeO2-Fe2O35001111DMnO2-CuO-TiO2-ZrO255011112:,C,B:MnCuH2O2OH,MnCu,Fe;Ce,,;Mn4+/Mn3+Ce4+/Ce3+Fe3+/Fe2+,,TiO2ZrO2,,,5C,21113C,,C1C2C3C4,,33,CC4,COD30min85%,,21221211pHH+H2O2,HO6,pH,44,,,,CuOFe2O3,H+,:CuO+2H+=Cu2++H2OFe2O3+6H+=2Fe3++3H2OH2O2,,,,,,OH-H2O2,,,,pH21212pHCODH2O2,H-pH,CODpH5pH,,COD85%,pHOH中国科技论文在线=5721213COD,,C4,H-pH=610,,,66,,COD,,M,;,,,H2O2,,COD,,,,,,801040110g/g,3040min,COD3CWPOH-:C4,0110g/g,COD103104mg/L,pH510710,3040min,CWPOCOD,Fenton,,,,,COD9H2O2,,,,,,CODBOD5/COD,,10,1,.J..1999,20(2):4245.2,.J.,1994,15(5):8688.3,.M..:,2001.90-1314MantzavinosDetal.CatalyticWetOxidationofp-CoumaricAcid:PartialOxidationIntermediates,ReactionPathwayandCatalystLeachingJ.AppliedCatalysisB:Environmental,1996,7:379396.5H.Debellefontaine...TreatmentofOrganicAqueousWastes:WetAirOxidationAndWetPeroxideOxidationJ.EnvironmentalPollution,1996,92(2):155163.6,,,.CuJ.,2000,21(4):8285.7,M..2002,604611.8DevlinHR,HarrisII.MechanismoftheOxidationofAqueousPhenolwithDissolvedOxygen,IndJ.Eng.Chem.Fundam.1984,23(4):387392.9FraserJAL.HydrogenPeroxideinMunicipal,LandfillandIndustrialEfluentTreatmentJ.EfluentWaterTreat,1984,24(5):184188.10,.J..1995,3(2):35.:(1962-),,,中国科技论文在线