大港南部油田回注污水结垢性与配伍性研究尹先清

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pH,MAP。(3),,50mg/L。[][1],.[J].,1998(4):21-23.[2],,.[J].,2002,22(9):9-11.[3].[M].:,2003:93-97,135-145.[4],,.[M].:,2007:78-90.[5],,,.[J].,2007,14(1):61-64.[6]StratfulI,ScrimshawMD,LesterJN.Conditionsinfluencingtheprecipitationofmagnesiumammoniumphosphate[J].WaterResearch,2001.35(17):4191-4199.[7],.[J].,2006,34(3):34-36.[8],.[J].,2003,22(2):166-171.[9],,,.[J].,2006,32(5):78-78.[10]RozicM,Cerjan-StefanovicSC,KurajicaS,etal.Ammoniacalnitrogenremovalfromwaterbytreatmentwithclaysandzeolites[J].WaterResearch,2000,34(14):3675-3681.ScalingtendencyandcompatibilityoftherecycledwastewaterinjectionintheSouthofDagangOilFieldYinXianqing1,ZhengQiong1,LiMei1,LiuJian1,ShiZhanzhong2,MaLijun2,ZhaoMing2,BanYanhua2(1.YangtzeUniversity,Jingzhou434023,China;2.ExplorationandDevelopmentResearchInstitute,PetroChinaDagangOilfieldCo.,Tianjin300280,China)1,1,1,1,2,2,2,2(1.,434023;2.,300280)[],,,。36,Ca2+、Mg2+、HCO3-,HCO3-,SISAI。:(85℃)7d,;(55℃),,。[];;;[]TQ085+.4[]A[]1005-829X(2008)10-0024-03Abstract:ThetreatedwateratthesouthernplantsofDaganghasbeenusedasthesourceofinjectionwaterfortheSouthofDagangOilField.Ifthetreatedwaterdoesnotmeettherequirementsofthequalifiedinjectionwaterstan-dard,thecarbonatescalingwillmaketheinjectionpressureincreaseandinfluencetheoilfieldproductionseriously.ThroughtheresearchonthesixkindsofwatersamplesfromthreeareasofthesouthofDagong,thetwoareasGuanlianandZaoliancontainafewofscalingionsofCa2+,Mg2+,HCO3-,butXierlianhaslotsofionsofHCO3-.ItisforecastthatGangxiinjectionwaterhascertainscalingtendency,basedontheCaCO3saturatedindexSIandstabilityindexSAI.Theexperimentalresultsofcompatibilityshowthatwhenthetemperatureoftheoillayeris85℃,keepinginclosedvesselfor7d,precipitationdoesnotoccurinthetwogroupsofwatersamplesfromthesouthernareas.AftermixingdifferentvolumesofGangxistratumwaterandinjectionwaterat55℃,itisfoundthatprecipitationoccursat55℃,itsturbiditygoesupandthecompatibilityispoor.Keywords:oilfieldproducedwater;injectionwaterinoilfield;scaling;compatibility2810200810IndustrialWaterTreatmentVol.28No.10Oct.,2008[](1983—),2007,。:022-26689132,E-mail:tony1718@163.com。[]2008-06-12()!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!24,,,,,,、,,1510~3130m1439~3050m。,、,。131。1,2,3、、,,、、,。22.1SISAI。〔1~3〕:SI=pH-pHs(1):pH———pH;pHs———pH;SI———。SI<0CaCO3,,;SI>0CaCO3,,;SI=0CaCO3,。SAI=2pHs-pH(2)SAI<6;SAI>7。2.26SI、SAI、IDe-bge-Hückel3γ〔4〕3。1123969-227-233-7-2K+101.1271.00121.2587.7538.5241.42Na+7621.256471.509684.129430.381894.902073.95Ca2+333.10125.32738.75468.3250.2910.72Mg2+58.0038.0074.0086.0040.5013.50Cl-12875.0010125.0017375.0016375.001350.001125.00SO42-5.002.0018.001.002.002.00HCO3-655.00890.00492.50335.003330.003320.00CO32-00000334.44CaCl2MgCl2CaCl2CaCl2NaHCO3NaHCO3pH7.367.987.377.547.867.9021648.4717722.8228503.6226783.456706.216921.03:pH、,mg/L。2/(mg·L-1)/μm/(mg·L-1)SRB/mL-1TGB/mL-1/(mg·L-1)/(mm·a-1)≤5~7≤3.5≤15~20<110<102≤0.5<0.0764.726.911.31×1021×100.750.0655.875.25.83×1021×1020.550.07113.634.1(316.23)34.53.5×1037×1020.690.045、、36CaCO3969-227-233-7-2γ(Ca2+)0.2700.2880.2470.3810.4060.411γ(Mg2+)0.3300.3460.3110.3150.4490.453γ(HCO3-)0.6700.6870.6480.6530.7730.776I0.3750.3010.5040.4700.0940.090SI-0.82-0.35-0.78-0.530.40-0.21SAI9.008.688.938.607.068.32:γ(Ca2+)、γ(Mg2+)、γ(HCO3-)Ca2+、Mg2+、HCO3-。,:2008-10,28(10)4000mg/L,,CaCl2,MgCl2;;,。SY/T5329—1994《》,3,2。25··,。、,,,;,;,,;,;,,,;;,,。,SS、BOD5、,。———,.CN1010778173,,,SI0,,CaCO3;SAI8,CaCO3,。3,。36,,168h,,4。[](1962—),2000,。:0716-8060933,E-mail:jzyinxq@126.com。[]2008-03-03!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!2008-10,28(10)4,、,、168h,,;,,,,,,。4(1)4000mg/L,CaCl2,MgCl2;;,。(2),,,;,CaCO3。(3),,,,;。[][1],,,.[M].:,1995:95-102.[2].[M].:,2000:145-186.[3].[M].3.:,1995:39-44.V()∶V()0∶11∶22∶33∶22∶11∶0/NTU0.30.90.40.80.61.285℃/NTU0.10.20.30.91.01.127-23/NTU1.31.10.80.30.1085℃/NTU1.81.51.40.70.20.13-7-2/NTU4.25.46.79.211.413.255℃/NTU6.96.66.09.813.114.2929-24168h26

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