:1001-3849(2003)03-0036-03 ① (Ⅰ)李 健, 张惠源, 尔丽珠(, 300457) :介绍了我国治理电镀废水的发展历程,较系统地评述了电镀重金属废水的各种治理技术——化学法、吸附法、离子交换法、电解法、膜分离法等的应用现状与发展趋势及其近年来在电镀废水治理技术的组合应用和多元综合防治技术的兴起与应用趋势。 :重金属;电镀废水;治理技术:X781.1 :A DevelopmentofTreatmentTechnologyforElectroplatngWasteWaterContainingHeavyMetal(Ⅰ) LIJian,ZHANGHui-yuan,ERLi-zhu(TianjinTEDASewageTreatmentPlant,TIanjin 300457,China) Abstract:ThedevelopementcourseofthetreatmenttechnologyforelectroplatingwastewaterinChinaisintroduced.Thecurrentappliationsituationanddevelopmenttrendofelectroplatingwastewatertreatmenttechnologies,suchaschemicalmethod,adsorption,ionexchange,electrolysis,membraneandsoon,aresystematicallycommented.Itisalsopointedoutthatthecombinationapplicaitonoftheabovetreatmentmethodsisthetendencytothedevelopmentcomprehensivetreatmenttechnology.Keywords:heavymetal;electroplatingwastewater;treatmenttechnology 、。,199425。,,,、,。1 、、。,、,。,,,·36· May2003 PlatingandFinishing Vol.25No.3①:2002-05-13: (1960-),,,,,. 、。,:2050,,,;,206070,,,,;,207080,,、,、,;,208090,,,,,;,2090,,、,,。2 2.1 ,。、、,,。,,,。2.1.1,、、、、,。,,,,。,[1~3]。,、,、、[4]。,[5]。。,,,,。2.1.2-()-,,,、、、[6~10],。,,-、、、、。,,。,140mg/L,,Cr3+0.7~1.0mg/L[11]。,[12]。,。:100mg/L,Ni2+50mg/L,pH=4~6,[13]。、,,[14]。。。。,[15]。-,,,,,。2.1.3,。,。,,·37·20035 253(150) 。、、,,、、[11,18,19]。,[16~18]。,。,、、,、。,,,。,,。,,,,80%。。2.2 、,。2070,[20~23]。,,,,[24,25]。,30~40mg/L[18]。,,NH4+,[24]。,,,。,。2.3 ,,,,、、。,,。,,,,。1990,37%[26],2080,[12,27,28]。,,,,,,,,,。,。:[1] ,,,.[J].,1992,12(1):26-27.[2] .[J].,1995,15(5):6-7.[3] .[J].,1991,11(6):27-30.[4] ,,.[J].,1997,15(3):11-12,60.[5] ,.[J].,1992,12(2):36-37.[6] .[J].,1991,11(4):37-38.[7] ,.[J].,2001,21(4):30-31.[8] .[J].,1998,18(3):28-31.[9] ,.[J].,1991,11(1):42.[10] ,.[J].1995,17(1):22-23.[11] ,,.[M].:,2000.50-72,123-141.[12] ,.[M].:,2000.80-83.[13] ,.[J].,1993,13(5):17-20.[14] .[J].,2001,21(3):32-35.[15] ,.()[J].,1989,9(6):6,7-10.[16] .[J].,1989,11(2):12-14.[17] .[J].,1998,18(1):33-36. (下转第42页)·38· May2003 PlatingandFinishing Vol.25No.3(μm) (s)(mΨ)13C2600Ni-17%P1.0Sn◎1.7414C2600Ni-3%P0.6Sn○1.6915C2600Ni-3%P2.8Sn◎1.6316C2600Ni-0.03%P1.0Sn×1.61217C2600Ni-28%P1.0Sn◎2.57 1:◎—。○—。×— 2 CuX、NiX(ΔG°)ΔG°(kJ/mol) Cu3P-1452、4、9Ni3P-2121、3、4、5、7、8、9、10、11、12、14、15NiB-987、8 12,P、B、SNi、CuCu-NiSnSnP、B(1-15),,,16~17。5 (、),,。P、B、S,0.01%~20.0%。。:[1] ,.[P].2001-89893,2001-04-03.(上接第38页)[18] .[J].,1987,7(3):7-11.[19] .[J].,1989,9(5):3-6.[20] ,,.[J].,1991,17(2):77-86.[21] ,.[J].。1999,7(6):94-103.[22] ,.[M].:,1992.32-37.[23] ,,.[J].,1991,17(6):355-360.[24] .[J].,1985,5(5):280-283.[25] ,.、[J].,1999,19(3):28-32.[26] .[J].,1998,20(4):31-33.[27] .[J].,1990,10(1):16-18.[28] .[J].,1988,8(5):36-37.(待续) (),、、、。, :13041462323·42· May2003 PlatingandFinishing Vol.25No.3