电化学方法在处理焦化废水中的研究进展

  1)100083:ProgressofStudyonTreatingCokingWastewaterwithElectrochemicalProcessJIANGGuangceChinaUniversityOfMiningAndTechnology,Beijing,100083,ChinaAbstract:Theprogressofthestudyoncokingwastewatertreatmentwithelectrochemicalprocessisdiscussedfromtheaspectsofelectrooxidation,,electroreduction,electrocoagulation/electro-adsorption,Pulsecoronadischarge.Theinfluencingfactorsofelectrochemicalprocessarealsodiscussed,basingonwhichtheresearchprospectofthecokingwastewatertreatmentwithelectrochemicalprocessisputforward.Keywords:electrochemical,cokingwastewater,researchprospectCOD511.1AOP                                                             [e-mail]   2[1]CO2H2OP.CANIZARES[2]CO2Fe3+[3]DSADSATiZrTaYa-qiongWang[4]Ti/SnO2+Sb2O3/PbO2Ti/SnO2+Sb2O3/MnOxTi/SnO2+Sb2O3/RuO2+PbO2Ti/SnO2+Sb2O3/PbO2Ti/SnO2+Sb2O3/MnOxTi/SnO2+Sb2O3/RuO2+PbO2M.A.M.Cartaxo[5]Fe–Co3O454h[6]Ti/TiO2-RuO2COD30minCOD80.2%BBDOH.[7,8]P.Canizares[9]BDDXiupingZhu[10]BDD[11][12]SnO2PbO2TOCNH3–N40%BDD121S.Chellammal[13]TiJoseL.Nava[14]BBDOH.CristinaFlox[15]Ph4.0BBDBBDO2H2O2Cl2NaClOCl-/ClO-CODLidia[16]Ti/Pt-Ir  3CODCossu[17]Ti/PbO2Ti/SnO2CODCOD[18]Ti/SnO2+Sb2O4/PbO2CIpH1.2DierreD[19]HNaokiHiro[20]Cu-ZnPt/Pr/TiNO3-NH3NH3HCIO2060kwh/kg-N(EF)H2O2Fe2+·OHH2O2H2O2Fe2+FentonFe2+[21],Sanchez-Sanchez,C.M[22]EFEFGEFSEF1.3[23]22FeFee33FeFee22222HOeHOH2222()FeHOFeOHH22324104()4FeHOOFeOHHO.Abdelwahab[24]AlAl21mg/L[25],CODEST(Electro-SorptionTechnology)CDI(CapacitiveDeionization)[26]  41.4,FeC,[27]Fe3C2022,(/)0.44FeeFeEFeFeV02222,(/)0HeHEHHVFe(OH)3[28]Fe[29]SBR1.5,HO·O·[30-32],:,,,22.1ADSBBD[33,34]three-dimensionalelecrtode[35]  5BPBE[36]2.2/200%Do[37]SnO2-PdO-RuO2-TiO2NaCl;78.1%56.1%[38]COD150%2.3Kesselman[39][40],,,——(),,(),,[41][42]-,3[1]C.Comninellis.Electrocatalysisintheelectrochemicalconversion/combustionoforganicpollutantsforwasterwatertreatment[J].  6ElectrochimiActa,1994,39:11-12.[2]P.CANIZARES,etal.Combinedelectrooxidationandassistedelectrochemicalcoagulationofaqueousphenolwastes[J].JournalofAppliedElectrochemistry,2002,32:1241-1246.[3].[D].:,2009.[4]Ya-qiongWang,etal.Electro-catalyticdegradationofphenolonseveralmetal-oxideanodes[J].JournalofHazardousMaterials,2009,162:1159-1164.[5],,.[J].,200WaterResearch39(2005)2687–27038,33(10):1-3.[6]M.A.M.Cartaxo,K.Ablad,etal.PhenolelectrooxidationonFe-Co3O4thinfilmelectrodesinalkalinemedium[J].Chemosphere,2012,86:341-347.[7]K.Rajeshwar,J.G.Ibanez,,etal.Electrochemistryandtheenvironment[J].JournalofAppliedElectrochemistry,1994,24:1077-1091.[8]D.Simonsson,Electrochemistryforacleanerenvironment[J].ChemicalSocietyReviewas,1997,26:181-189.[9]P.Canizares,J.Lobato,etal.Electrochemicaloxidationofphenolicwasteswithboron-dopeddiamondanodes[J].WaterResearch,2005,39:2687-2703.[10]XiupingZhu,etal.Advancedtreatmentofbiologicallypretreatedcokingwastewaterbyelectrochemicaloxidationusingboron-dopeddiamondelectrodes[J].WaterResearch,2009,43:4347-4355.[11]XiupingZhu,JinrenNi,etal.Scale-upofBDDanodesystemforelectrochemicaloxidationofphenolsimulatedwastewaterincontinuousmode[J].JournalofHazardousMaterials,2010,184:493-498.[12]XiupingZhu,JinrenNi,etal.Scale-upofB-dopeddiamondanodesystemforelectrochemicaloxidationofphenolsimulatedwastewaterinbatchmode[J].ElectrochimicaActa2011,56:9439-9447.[13]S.Chellammal,P.Kalaiselvi,etal.AnodicincinerationofphthalicanhydrideusingRuO2–IrO2–SnO2–TiO2coatedonTianode[J]ArabianJournalofChemistry,2012,23:1-6.[14]JoseL.Nava,FranciscoNunez,etal.Electrochemicalincinerationofp-cresolando-cresolinthefilter-press-typeFM01-LCelectrochemicalcellusingBDDelectrodesinsulfatemediaatpH0[J].ElectrochimicaActa,2007,52:3229-235.[15]CristinaFloxa,ConchitaArias,etal.Electrochemicalincinerationofcresols:AcomparativestudybetweenPbO2andboron-dopeddiamondanodes[J].Chemosphere,2009,74:1341-1347.[16]LidiaSzpyrkowicz,GeofferyHKelsall,etal.Performanceofelectrochemicalreactorfortannerywastewater[J].ChemicalEngineeringScience,2001,56:1579-1586.[17]CossuRaffacllo,PolcaroAnnaM,etal.Electrochemicaltreatmentoflandfilllechate:oxidationatTi/PbO2andTi/SnO2anodes[J].EnvironmentalScienceandTechnology,1998,32(22):3570-3573.[18].[D].:,2007.[19]DierreD,etal.Electrocatalyticdehydrochlorinationofpentachlorophenolorcyclohexanol[J].EnviromentalScienceTechnology,2000,34(7):1265-1268.[20]NaokiHiro,JunHirose,etal.Developmentofthewastewatertreatmentsystemusingdenitrificationapparatusbytheelectrolyticmethod[J].Electrochemistry,2003,71(1):24-28.[21],.[J].(),2007,35(4):126-128.[22]Sanchez-Sanchez,C.M.,etal.Goethiteasamoreeffectiveirondosagesourceformineralize-ationoforganicpollutantsbyelectro-Fentonprocess[J].ElectrochemistryCommunications,2007,9(1):19-24.[23],.[J].,2001,18(l):10-12.[24]O.Abdelwahaba,N.K.Aminb,etal.Electrochemicalremovalofphenolfromoilrefinerywastewater[J].JournalofHazardousMaterials,2009,163:711-716.[25],.[J].,2005,116(5):29-31.[26],.[J].,2012,24(1):15-19.[27],.[J].,2001,2(4):18-24.  7[28],.[J].,2010,38(1):125-128.[29].——SBR[J].,2003,3(5):471-476.[30],,,.[J].,2003,29(4):29-31.[31],,,.[J].,2004,22(2