电化学高级氧化技术在工业废水处理中的应用陈蕾

48220192AppliedChemicalIndustryVol．48No．2Feb．20192018-06-252018-07-15413015451985－。[e-mail]210037、、、、、、。TQ150．9X703．1A1671－3206201902－0434－04ApplicationofelectrochemicaladvancedoxidationprocessesinindustrialwastewatertreatmentCHENLeiWANGZhengSchoolofCivilEngineeringNanjingForestryUniversityNanjing210037ChinaAbstractThisreviewontheapplicationofadvancedoxidationtechnologyinthetreatmentoftextilein-dustrialwastewatertannerywastewaterpetrochemicalwastewaterpaperindustrywastewaterandotherin-dustrialwastewaterinrecentyearswillprovidereferenceforselectingtheappropriateoperatingparametersduringthetreatmentofsimilarindustrialwastewaterusingelectrochemicaladvancedoxidationtechnology．Itissuggestedthatdevelopinglowcostelectrodematerialsscaleapplicationreducingtheformationoftoxicbyproductsandthecombinationofelectrochemistrywithconventionalprocesseswillbetheimportantdirectionsforfutureresearch．KeywordselectrochemicaloxidationrefractoryorganicpollutantsindustrywastewaterFenton“”。。ElectrochemicalAdvancedOxidationProcessesEAOPsH2O2、、、、、、、、1。、、、、、、2。。。1AO、FentonEFFentonPEFFentonSPEF、Fenton。·OH、H2O2、O3、。FentonH2O2DOI:10.16581/j.cnki.issn1671-3206.20181127.0272Fe2+Fenton·OH。FentonFentonFenton3。22．1。。。COD4-5。Chatzisymeon0．5%NaCl20min85%100%4。Malpass0．1mol/LNaClCOD85。。Ti/Pt、Ti/TiOx-ＲuOx、Ti/TaIrPtalloySi/BDDNb/BDDCOD6-7。5000mg/LCOD55%8-9。Tsantaki500mLBDDDSA8．0mA/cm2COD53%10。Wang500mLPt3．2mA/cm2COD74%11。COD10-11。pH2．88．1CODpH=8．1pH311-12。、。5．0kWh/m3COD413。BDDCOD16～100kWh/m3714。。70%60%6。2．2。、15。16。SzpyrkowiczTi/Pt-Ir、Ti/PbO2、Ti/PdO-Co3O4Ti/ＲhOx-TiO2、CODTi/Pt-IrTi/PdO-Co3O40．4kWh/m317。PanizzaCerisolaTi/PbO2Ti/TiＲuO2Ti/TiＲuO2Ti/PbO2Ti/PbO2Pb2+18。Sn、Ir、ＲuTiDSATi/Ｒu0．30Ti0．70O2Ti/Ir0．15Ｒu0．15Sn0．70O219。Hammami、CODI=2．4At=4hT=40℃COD92%TOC95%20。Isara-in-ChávezEC、AO、EFPEF-UVAECAOBDD/EFPEF-UVABDD/BDDPEF-UVA＞EF≈EC＞AOEC/PEFECPEF180min90%21。2．3、、。53448、、22。ＲamalhoDSAＲuO2-TiO2-SnO2DSA23。GargourietPbO2BDDBDDPbO224。ＲochaBDDTi/Pt60mA/cm2COD98%Ti/PtCOD80%25。daSilva3BDDDOCCODTi/IrO2-Ta2O526。SantosTi/ＲuO2120minCOD87%-COD96%COD27。。、ClO－3ClO－422。。2．4。COD200～300、、、、28。ChanworrawootHunsomTi/ＲuO2pH=11．872．0g/LNaCl2．53mA/cm23h、BODCOD98%98%97%70kWh/m328。El-AshtoukhyPbO2COD97%15kWh/m329。2．5、、、。ValeroTi/ＲuO2pH9．050mA/cm22000mg/LCOD75%30。DomínguezBDDDOC31。Garcia-SeguraFentonFenton32。MoreiraFentonFenton33。BorbónIrO2-Ta2O5DSAPt0．5g/LNaCl34。3。、。Fenton、。1OturanMAAaronJJ．Advancedoxidationprocessesinwater/wastewatertreatmentprinciplesandapplicationsAreviewJ．CriticalＲeviewsinEnvironmentalScience＆Technology201444232577-2641．2MoreiraFCSolerJFonsecaAetal．Incorporationofelectrochemicaladvancedoxidationprocessesinamulti-stagetreatmentsystemforsanitarylandfillleachateJ．WaterＲesearch2015816375-387．3MoreiraFCＲuiAＲBBrillasEetal．ElectrochemicaladvancedoxidationprocessesAreviewontheirapplica-tiontosyntheticandrealwastewatersJ．AppliedCataly-sisBEnvironmental2017202217-261．4ChatzisymeonEXekoukoulotakisNPCozAetal．Elec-trochemicaltreatmentoftextiledyesanddyehouseefflu-entsJ．JournalofHazardousMaterials20061372998-1007．63425MalpassGＲPMiwaDWMortariDAetal．Decolori-sationofrealtextilewasteusingelectrochemicaltechno-queseffectofthechlorideconcentrationJ．WaterＲe-search2007412969-2977．6SalaMGutiérrez-BouzánMC．Electrochemicaltreatmentofindustrialwastewaterandeffluentreuseatlaboratoryandsemi-industrialscaleJ．JournalofCleanerProduc-tion201465458-464．7LingYHuJQianZetal．Continuoustreatmentofbio-logicallytreatedtextileeffluentusingamulti-cellelectro-chemicalreactorJ．ChemicalEngineeringJournal2016286571-577．8ＲajuGBKaruppiahMTLathaSSetal．Electrochemi-calpretreatmentoftextileeffluentsandeffectofelectrodematerialsontheremovaloforganicsJ．Desalination20092491167-174．9AquinoJMＲocha-FilhoＲCＲuotoloLAMetal．Elec-trochemicaldegradationofarealtextilewastewaterusingβ-PbO2andDSAanodesJ．ChemicalEngineeringJournal2014251251138-145．10TsantakiEVelegrakiTKatsaounisAetal．Anodicoxi-dationoftextiledyehouseeffluentsonboron-dopeddia-mondelectrodeJ．JournalofHazardousMaterials2012207/2081291-96．11WangCYLaiIWChiuehTDetal．BEＲanalysisforMIMOBICM-IDassumingfiniteprecisionofextrinsicLLＲC．TaiwanInternationalSymposiumonInformationTheoryandItsApplicationsIEEE2010129-134．12VaghelaSSJethvaADMehtaBBetal．LaboratorystudiesofelectrochemicaltreatmentofindustrialazodyeeffluentJ．EnvironmentalScience＆Technology20053982848-2855．13BashaCASendhilJSelvakumarKVetal．Electro-chemicaldegradationoftextiledyeingindustryeffluentinbatchandflowreactorsystemsJ．Desalination20122853188-197．14Martínez-HuitleCASantosEVDAraújoDMDetal．Applicabilityofdiamondelectrode/anodetotheelectro-chemicaltreatmentofarealtextileeffluentJ．JournalofElectroanalyticalChemistry2012674674103-107．15VijayalakshmiPＲajuGBGnanamaniA．Advancedoxi-dationandelectrooxidationastertiarytreatmenttech-niquestoimprovethepurityoftannerywastewaterJ．In-dustrial＆EngineeringChemistryＲesearch2011501710194-10200．16ＲadjenovicJSedlakDL．Challengesandopportunitiesforelectrochemicalprocessesasnext-generationtechnolo-giesforthetreatmentofcontaminatedwaterJ．ChineseJournalofClin