电渗析法处理含盐废水的进展章晨林

367July201620167ModernChemicalIndustry*(，100013)。、、。X703．1P747+．3A0253－4320201607－0013－04DOI10．16606/j．cnki．issn0253－4320．2016．07．004Ｒesearchprogressoftheelectro-dialysisintreatmentofsalinewastewaterZHANGChen-linZHANGXin-miaoGUOZhiLUANJin-yi*EnvironmentProtectionＲesearchInstituteBＲICISINOPECBeijing100013ChinaAbstractTheadvantagesoftreatingsalinewastewaterbyelectrodialysisareanalyzed．Theprinciplesofthistechniqueandtheresearchprocessintreatmentofsalinewastewaterbyelectrodialysisarereviewed．Therecentdevelopmentofelectrodialysisishighlighted．Inthispaperitissuggestedthattheadjustmentoftheoperationparametersprocessesoptimizationandimprovementofmembraneperformance/characteristicscanbeappliedtoimprovetheconcentratingratioofelectrodialysis．Intheendtheprospectsofelectrodialysisintreatmentofsalinewastewaterarealsoproposed．Keywordselectrodialysissalinewastewaterzeroliquiddischargeminimizationofwastewater2015－12－0815－14ZS04091992－1963－“”[e-mail]。。、。。“”“”。。“”zeroliquiddischarge1。“”、、。。、。。。、、。1。。、3。。12。、。·31·367。。12“”。。、、。2.1“”。。3185～200g/L185～220kWh。TokuyamaTSX－200200g/LNaCl155kWh2。。Mohammadi4、。Monhtada5Taguchi、、。670g/L250L/h、2∶3、19V、30℃177.63g/L171.71kWh。Emmanuel70.2%～2%20%1.5～7.1kWh/m325kWh/m3。2.22.2.1、。CaSO4175%。Marian8CaSO4300%17min。CaSO49CaSO4330%17～30min10CaSO4368%80%60%。2.2.2、。。、。Konstantinos11NiSO4210.4mg/L、NiCl283mg/L10～20A/mNi2+100mg/L35min800mg/L。Tatiane12Ni2+90mg/L·A·cm21kgNiSO4·6H2O0.7kWh。Peng13－60V50mg/L450mg/L0.46mg/L。14。80%、4285、5672mg/L。Ahmed15Pb2+600mg/L2600～3000mg/L15mg/L·41·20167。pH16pH3～5、10V0.25kWh/L17－18。19、。55V19.84mg/L·s25V355V24.6kWh/m325V230g/L132.8g/L78%。Chen20。pH2.20HCrO－410mA/cm2180min400mg/LCr6+555mg/L30mA/cm2752mg/L。pH8.5CrO2－4Na+、Cl－NH2SO－345%。2.2.3。21。。26V1∶540～50L/h1000mg/L120min97.3%。22。1∶532V60L/h337mg/L29944mg/L0.71kWh/m3。2.2.4。23。55V24L/h534.59mg/L2700mg/L13mg/L。Luciano24。151000.36mg/LCd2+2106mg/LCN－CdCN2－4。20mA/cm2240min86%CdCN2－495%CN－。pHCN－CdOH2。25NaBr16g/LNaBr150g/L120mg/L。3“”。“”。、。“”。、。、、、。、。。·51·3671DaniJenniferBarringtonGoenHo．TowardszeroliquiddischargeTheuseofwaterauditingtoidentifywaterconservationmeasuresJ．JournalofCleanerProduction2014661571－576．2HeinerStrathmann．Electrodialysisamaturetechnologywithmulti-tudeofnewapplicationsJ．Desalination2010264268－288．3．J．20073321－3．4TorajMohammadiAnitaKaviani．Watershortageandseawaterde-salinationbyelectrodialysisJ．Desalination20031581267－270．5MonhtadaSadrzadehTorajMohammadi．Seawaterdesalinationu-singelectrodialysisJ．Desalination20082211440－447．6．J．2014285951－956．7EmmanuelKorngoldLudaAronovNaphtaliDaltrophe．Electrodial-ysisofbrinesolutiondischargedfromanＲOplantJ．Desalina-tion2009242215－227．8MarianTurekPiotrDydo．Electrodialysisreversalofcalciumsul-phateandcalciumcarbonatesupersaturatedsolutionJ．Desalina-tion20031581/2/391－94．9MarianTurekPiotrDydoJoannaWas．ElectrodialysisreversalinhighCaSO4supersaturationmodeJ．Desalination20061981/2/3288－294．10MarianTurekPiotrDydoJoannaWas．Highefficiencyelectrodialy-sisreversalofconcentratedcalciumsulfateandcalciumcarbonatesolutionsJ．Desalination20072051/2/362－66．11KonstantinosDermentzis．Ｒemovalofnickelfromelectroplatingrinsewatersusingelectrostaticshieldingelectrodialysis/electro-deionizationJ．JournalofHazardousMaterials20101731/2/3647－652．12TatianeBenvenutiＲenanSilvanoKrapfMarcoAntonioSiqueiraＲodriguesetal．Ｒecoveryofnickelandwaterfromnickelelectro-platingwastewaterbyelectrodialysisJ．SeparationandPurifica-tionTechnology2014129106－112．13PengChangshengLiuYanyanBiJingjingetal．Ｒecoveryofcop-perandwaterfromcopper-electroplatingwastewaterbythecombi-nationprocessofelectrolysisandelectrodialysisJ．JournalofHaz-ardousMaterials20111893814－820．14．J．201339135－37．15AhmedAbou-ShadyChangshengPengJingjingBietal．ＲecoveryofPbⅡandremovalofNO－3fromaqueoussolutionsusinginte-gratedelectrodialysiselectrolysisandadsorptionprocessJ．De-salination2012286304－315．16AhmedAbou-ShadyChangshengPengJuanAlmeriaOetal．EffectofpHonseparationofPbⅡandNO－3fromaqueoussolu-tionsusingelectrodialysisJ．Desalination201228546－53．17NalanKabayHafizeKahveciOzgurIpeketal．Separationofmon-ovalentanddivalentionsfromternarymixturesbyelectrodialysisJ．Desalination200619874－83．18NalanKabayOzgurIpekHafizeKahvecietal．Effectofsaltcom-binationonseparationofmonovalentanddivalentsaltsbyelectrodi-alysisJ．Desalination200619884－91．19．J．20102071440－1445．20ChenShiao-ShingLiChi-WangHsuaHong-Deretal．Concentra-tionandpurificationofchromatefromelectroplatingwastewaterbytwo-stageelectrodialysisprocessesJ．JournalofHazardousMate-rials20091612/31075－1080．21．J．201037515－30．22．D．2011．23．J．200826327－29．24LucianoMarderSulzbachGuilhermeOAndreaMouraBernardesetal．ＲemovalofcadmiumandcyanidefromaqueoussolutionsthroughelectrodialysisJ．BrazChemSoc2003144610－615．25．J．200430119－21．■·61·