99环境工程学报Vol.9No.920159ChineseJournalofEnvironmentalEngineeringSep.2015C/N*214122C/N。、DO0.5mg/L2.5mg/L200%、100%100%NO-2-N90%COD、73.42%98.57%。C/NCOD/TN4NO-2-NTN94%。C/NX705A1673-9108201509-4165-06Short-cutnitrificationanddenitrificationprocessfortreatinglowC/NfoodwastewaterZhangZhouZhaoMingxingRuanWenquanMiaoHengfengRenHongyanHuangZhenxingSchoolofEnvironmentalandCivilEngineeringJiangnanUniversityWuxi214122ChinaAbstractAccordingtothecharacteristicsofitswaterqualityashort-cutnitrificationanddenitrificationtreatmentoflowC/Nratiofoodwastewaterwaspresented.Through0.5mg/Land2.5mg/LofDOinmicro-oxy-genzoneandaerobiczoneand200%100%and100%refluxratioofnitrifyingliquidmicro-oxygenmixtureandthesludgetheaccumulationrateofNO-2-Ncouldbeachievedmorethan90%andaverageremovalratesofCODandNH+4-Ncouldbe73.42%and98.57%respectively.SincedenitrificationeffectwouldbeinhibitedunderthelowrationofC/NmethanolwasaddedtothereactorasasourceofcarbontoincreasetheratioofC/N.WhentheCOD/TNwasaround4theTNremovalrateofreactorcouldreach94%undertheNO-2-Nbaseddenitrificationandtheeffluentcouldmeetemissionstandards.Thereforethisstudycouldprovideanefficientandeconomicalbiologicaldenitrificationoffoodwastewater.Keywordsbiologicaldenitrificationshort-cutnitrificationanddenitrificationfoodwastewaterlowC/N2012BAC18B01-2BE20126152014-06-242014-07-161990—E-mailzhouzhang1990@126.com*E-mailwqruan@jiangnan.edu.cnNH+4-N→NO-2-N→NO-3-NNO-3-N→NO-2-N→N2。“NO-2-N→NO-3-N”“NO-3-N→NO-2-N”。1975VotesNO-2-N1-5。NH+4-N→NO-2-N→N225%40%、67。、、pH。NOBAOBNO-2-N8。9FA9、FNA10、20~35℃11、pH12、DO131415。AOBNOBNOBAOB。、COD、SS16C/N。、。350t。C/N。。11.1COD749~1965mg/LNH+4-N655~1498mg/LpH7.70~8.24NO-3-N13~93mg/LNO-2-N0~5mg/LTN666~1517mg/L。COD、C/N1。1.21。。100cm、40cm、70cm50cm200L31Fig.1Flowchartoftest、、1∶2∶2。40L。、、。30±1℃。、TNDO0.5mg/L1718。。1.31dDO0.5mg/LDO2.5mg/L0.12kg/m3·d。3~4g/L。200%100%100%。5Ⅰ0~40dⅡ41~50dⅢ51~55dⅣ56~95dⅤ96~120d。1.4COD191919N-1--19-19MLSS19。、1。=ΔCNO-2-NΔCNO-2-N+ΔCNO-3-N×100%1ΔCNO-2-NΔCNO-3-Nmg/L。22.1NO-2-N266149C/N2Fig.2ChangesofNO-2-Naccumulationrateinthemicro-oxygenzoneNH+4-N655~1498mg/L1011mg/L。1dNO-3-NNO-2-N。NO-3-NNO-2-NNO-2-NDO。15dNO-3-NNO-2-N0~40dCOD400mg/L、CODCOD90%CODNO-3-N。40~50NO-3-NpHNO-3-N15~40dNO-3-N。NO-2-NNO-2-N。51~55NO-3-N。56~95NO-3-NNO-2-NNO-2-N90%。2.22.2.1COD去除效果3CODCOD749~1645mg/LCOD1350mg/L。COD250~479mg/L《》CJ343-2010≤500mg/L。COD60%~92%COD。20COD86.4%。21CODCOD78%~85%81%。。3CODFig.3CODremovalefficiency40~50CODNO-3-N。2.2.2NH+4-N去除效果4NH+4-NNH+4-N655~1498mg/LNH+4-N1120mg/L。NH+4-NNH+4-N52%~79%69.9%DONH+4-N。NH+4-76149NNH+4-N0~48mg/L12mg/LNH+4-N98.57%。Zhang22、1200~1800mg/L15mg/L98%。231100~1800mg/L3DO1.5mg/L85%。。4NH+4-NFig.4NH+4-Nremovalefficiency2.2.3NO-3-N浓度变化5NO-3-N。NO-3-NH+。COD。NO-3-NNO-3-NNO-3-NNO-3-N。40~50NO-3N。NO-3-NNO-3-N51mg/L。5NO-3-NFig.5ChangeofNO-3-N2.2.4TN去除效果TN666~1517mg/L1213mg/LTN62~701mg/LTN31%~94%76%。TN62mg/L《》CJ343-2010≤70mg/L。24A2ODO0.3~0.5mg/LHRT2.34TN75.4%。TNNO-3-NTNNO-3-N。COD1350mg/LCOD/TN1.11TN。2.3。25。COD/TN>5~726。86149C/N56~95101000200030004000mg/LCOD。6TNNO-3-N。1000mg/L2000mg/LNO-3-NTNNO-3-N。3000mg/LTNNO-3-N。3000mg/LCOD/TN4NO-3-NTN94%。23C/NCOD/NOx3.86MLSS6.09g/LNO-2-NNO-2-N89.7%NO-3-NNO-3-N67.6%33.4%。6TNNO-3-NFig.6VariationofTNandNO-3-NbyadditiondifferentconcentrationsofCH3OH31C/N30±1℃DO0.5mg/LNO-2-N90%。2DONO-2-NNH+4-N69.9%NH+4-NNH+4-N98.57%。3COD/TN1.11TNNO-2-N3000mg/LCODTN94%。1..20042.A/O.2006265703-709MaYongWangShuyingZengWeietal.A/Opilot-scalenitrogenremovalprocesstreatingdomesticwastewaterⅠ.Thestudyofshort-cutnitrificationanddenitrification.ActaScientiaeCircumstantiae2006265703-709inChinese3MulderA.VandeGraafA.A.RobertsonL.A.etal.Anaerobicammoniumoxidationdiscoveredinadenitrifyingfluidizedbedreactor.FEMSMicrobiologyEcology1995163177-1844MulderJ.W.vanKempenR.N-removalbySharon.Wa-terQualityInternational19973430-315Surmacz-GórskaJ.CichonA.MikschK.Nitrogenre-movalfromwastewaterwithhighammonianitrogenconcen-trationviashorternitrificationanddenitrification.WaterScienceandTechnology1997361073-786VerstraeteW.PhilipsS.Nitrification-denitrificationprocessesandtechnologiesinnewcontexts.EnvironmentalPollution1998102S1717-7267TurkO.MavinciD.S.SelectiveinhibitionAnovelcon-ceptforremovingnitrogenfromhighlynitrogenouswastes.EnvironmentalTechnologyLetters19878419-4268.AOBNOB.20093051430-1436ZengWeiZhangYueLiLeietal.Competitionandop-timizationofAOBandNOBfordomesticwastewatertreat-mentatnormaltemperatures.EnvironmentalScience20093051430-1436inChinese9ParkS.BaeW.Modelingkineticsofammoniumoxidationandnitriteoxidationundersimultaneousinhibitionbyfreeammoniaandfreenitrousacid.ProcessBiochemistry2009446631-64010VadiveluV.M.KellerJ.YuanZ.FreeammoniaandfreenitrousacidinhibitionontheanabolicandcatabolicprocessesofNitrosomonasandNitrobacter.WaterScienceandTechnology200756789-979614911HellingaC.SchellenA.A.J.C.MulderJ.W.etal.TheSharonprocessAninnovativemethodfornitrogenremovalfromammonium-richwastewater.WaterScienceandTechnology1998379135-14212VillaverdeS.García-EncinaP.A.Fdz-PolancoF.In-fluenceofpHovernitrifyingbiofilmactivityinsubmergedbiofilters.WaterResearch19973151180-1186