反渗透膜的研究进展

:(20060516),(06YFGZSH01700),(50673077);:(1970-),,,Email:[e-mail];*:Email:[e-mail]李国东1,王薇1,2*,李凤娟1,任强3,宿辉3(1天津工业大学中空纤维膜材料与膜过程教育部重点实验室,天津300160;2天津膜天膜工程技术有限公司,天津300160;3中海油能源发展股份有限公司采油技术服务分公司,天津300452):,,,;,:;;;;1国内外反渗透膜研究进展11[1]:2050Reid6m;1960LoebSourirajan,Reid()10;2060RileyCadoffe,;LS,;,1975,DuPontB101997,,4104m32005,,5104m32006,,,[2]2009,;SWC5Max,10%,:NS100NS200NS300PA100PA300FT30PEC1000121958,80200860,10%30,,377Zhou,[3],[4],[5]20098;,13,,,21,,40,5105m3/d[6],6,(CTA):,100S/cm~200S/cm,,995%2中空纤维膜,:[7,8],1965[9]1968,,70,;,,90,,,11Table1Materialsandresearchinstitutesforhollowfibermembrane/(PVC/PIRT)[10]PVC,,,;PIR,(PVDF)[11,12],(PAN)[13,14],,,(PS)[15,16],,-100~150,,,(PES)[17,18],180,,,3界面聚合法制备复合膜31,,,3820107()(),;();,,,1[19]1Figure1Schematicrepresentationofthepreparationofcompositemembranebyinterfacialpolymerization32,,(2)(2),,(MPD)(OPD)(PPD)(TMC)Zhou,(MPD)/5(SMPD)TMC[20](ATRIR)X(XPS),,(COOH),,NaCl2(BTRCBTEC)Figure2Chemicalstructuresoftwoacylchloridemonomers(BTRCandBTEC)Liu,(MPD),5(ICIC),,,ICICMPDTMCMPD[21]Li:3,4,5(BTRC)3,3,5,5(BTEC),BTRCBTEC,2BTRCBTEC[22],397(CONH),,Li,32g/LNaCl,:omBTECopBTEC50L/(m2h)mmBTEC99%[23]3(mmBTEComBTECopBTEC)Figure3Chemicalstructuresofthreeacylchloridemonomers(mmBTEC,omBTECandopBTEC)33,,Roh;(SC,IPC,TPCTMC),(MPD,OPD,PPD)(TMC)[24]:,;,Tang(ATRIR)X(XPS)(TEM)[25]XPS:/TEM(COOH)4反渗透膜的改性;,01mg/L,[26],:41,Kang,(PEG);(MPEGNH2),ATRFTIRXPSAFMPEG,[27]Freger,TEM;AFM,[28]Kim,4,35g/LNaCl996%4020107[29]4Figure4Generalmechanismofsolgelmethodsforsurfacemodificationwithtriethyloxyalkylsilanecompounds42,,Kim,,,[30]5建议,,,,:,,,;,参考文献:[1]CadotteJE,LloydDR.AmChemSoc,1984:273~294.[2].,2006,3(6):73.[3]ZhouY,YuSC,LiuMH,ChenHL,GaoCJ.Desalination,2006,192(13):182~189.[4]ChenG,LiSH,ZhangXS,ZhangSB.JMembrSci,2008,(310):102~109.[5],,,.,2004,20(6):138~141.[6],,,,.,2009,25(10):90~94.[7].,2002,21(4):72~76.[8]VerssimoS,PeinemannKV,BordadoJ.Desalination,2005,184(13):1~11.[9],.,2004,,15~17.[10],,,.2009,37(2):55~59.[11],,.,2009,29(1):83~89.[12]玥,赵军,刘学军,张东.工程物理研究院科技年报,2008,(1):86~87.[13],,,,.,2009,29(2):34~39.[14],,,,.,2009,32(1):4~7.[15],,.,2009,28(1):1~5.[16],,,,.,2009,43(1):17~19.[17],,.,2009,29(1):36~40.[18],,.:,2009,27(1):6~13.417[19],,.,2007,19(9):1428~1435.[20]ZhouY,YuSC,LiuMH,GaoCJ.JMembrSci,2006,270(12):162~168.[21]LiuLF,YuSC,ZhouY,GaoCJ.JMembrSci,2006,281(12):88~94.[22]LiL,ZhangSB,ZhangSX,ZhengGD.JMembrSci,2007,289(12):258~267.[23]LiL,ZhangSB,ZhangSX,ZhengGD.JMembrSci,2008,315(12):20~27.[24]Roh.JJ.MembrSci,2002,198(1):63~74.[25]TangCYY,KwonYN,LeckieJO.JMembrSci,2007,287(1):146~156.[26]TanakaS,NumataK,KuzumotoH,SekinoM.Desalination,1994,96:191.[27]KangGD,LiuM,LinB,CaoYM,YuanQ.Polymer,2007,48(5):1165~1170.[28]FregerV,GilronJ,BelferS.JMembrSci,2002,209:283~292.[29]KimN,ShinDH,LeeYT.JMembrSci,2007,300(12):224~231.[30]KimHII,KimSS.JMembrSci,2006,286(12):193~201.DevelopmentofHollowFiberReverseOsmosisMembraneLIGuodong1,WANGWei1,2,LIFengjuan1,RENQiang3,SUHui3(1.KeyLaboratoryofHollowFibermembraneMaterialandMembraneprocessofMinistryofEducation,TianJinPolytechnicUniversity,TianJin300160China;2.TianJinMotianMembraneEng.&Tech.Co.,LTD.,TianIin300160,China;3.CNOOCEnergyTechnology&ServicesOilfieldTechnologyServicesCo.,Tianjin300452,China)Abstract:Reverseosmosisisaliquidseparationtechnology,withpropertiesofhighefficiency,lowenergyconsumptionandeasyoperation.Comparedtotraditionalmethodsofwastewatertreatment,reverseosmosismembranetechnologyhasmanyadvantages,suchasseawaterandbrackishwaterdesalination,thecirculatoryuseofwastewaterandrecoveryofusefulsubstances.Thedevelopmentofreverseosmosismembranehasbeenreviewed.Thetypeofmembranemodule,materialofpreparinghollowfibermembraneandtheresearchinstitutionareintroduced.Themethodofpreparingcompositemembrane,technicsofinterfacialpolymerization,functionalmonomerofpreparingcompositemembraneandtheeffectoffunctionalmonomeronreverseosmosismembraneareexplained.Themodifymethodsofreverseosmosismembraneisintroduced,too.Finally,giveseveralsuggestionsaccordingtotheresearchsituationofreverseosmosismembrane.Keywords:Reverseosmosismembrane;Compositemembrane;Interfacialpolymerization;Functionalmonomer;Modify4220107