废水生物处理工艺短程硝化反硝化影响因素探讨

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321Vol.32No.120122JournalOfNortheastDianliUniversityFeb.20122011-12-02BSJXM-2007101954-.1005-2992201201-0061-0511211.1320122.150090、DO、FA、pH、。12℃~14℃30℃DO0.5mg/L1.0-5.0mg/LpH81115。X703.1A。、、、、。。。-Sharon1、-Sharon-Anammox2、3、Canon4、-Oland5。-、DO、FA、pH、。1NH+4-N。NO-2-NNO-3-N。NO-2-N。NH+4→NO-2→N2。1-4125%NH+4-N+1.5O2→NO-2-N+H2O+2H+NH+4-N+2O2→NO-3-N+H2O+2H+240%TN6NO-2-N+3CH3OH+3CO2→3N2+6HCO-3+3H2O6NO-3-N+5CH3OH+3CO2→3N2+6HCO-3+7H2O3NO-2-NNO-3-N63%424%-33%50%5。2NO-2-NNO-2-N。。、DO、FA、pH、。2.1。620℃-30℃。12℃-14℃HNO215℃-30℃30℃HNO2。5℃-40℃7umt=um20exp-Ea20-t293R273+t1μmtt℃d-1μm2020℃d-1EakJ/molR8.314J/mol·K。111。20℃0.801/d0.788/d。Ea68kJ/mol44kJ/mol。20℃20℃。。。SHARON30℃-35℃。2.2。Keisuke80.5mg/L2632。Laanbroe9DO。0.2-0.4mg/L1.2-1.5mg/L。DO0.5mg/L60%30%。10DO0.3-0.7mg/LKN=0.2-0.4mg/LKN=1.2~1.5mg/LDO。2.3FApHpH。FA2A=1714×B×10pHKb/Kw+10pH=1.214×B×10pHe6344/T+10pH.22Amg/LBmg/LKbKwTK。FAFAFA。AbelingSeyfried11FA1.0-5.0mg/L。Ford12FA24mg/L。Aathonisen1310-150mg/L。FA。NH3pH。。HNO2FAHNO2。FAHNO2HNO2。pHpHpH7.8-7.8pH7.7-8.114。15pH7.0-8.6pH7.4-8.3。NO2-NpH8.0NO3-NpH7.0。pH87。pHpH。1625℃68mg/LpH8.7388%19.5mg/LpH7.1670%11.85mg/LpH。2.4NH+4-NNO-2-N15℃。。Pollic17843613VSS0.72g/L0.10g/L0.55g/g5.0g/g3.2mg/g·h37.9mg/g·h。VanKempen18Sharon1-2.5d。19SRT-1h-4h--220NO-3-NNO-2-N。20NO-2-NNO-2-N/NO-x-N87.39%1hNO-2-N0.208mg/LNO-2-N0.46mg/L。45NO-2-N1.12mg/L471.81mg/L。49NO-2-NNO-2-N3.08mg/L60NO-2-N4.34mg/L。1149NO-2-N。11。3。112℃~14℃30℃2DO0.5mg/L3FAFA1.0-5.0mg/L4pHpH85。1HellingaCSchellenAAJJMulderJWetal.TheSHARONprocessaninnovativemethodfornitrogenremovalfromanammonium-richwastewaterJ.WaterSci.Tech.1998379135-142.2UVanDongenMSMJettenMCMVanLoosdrecht.TheSHARON-ANAMMOXprocessfortreatmentofammoniumrichwastewaterJ.Wat.Sci.Tech.2001441153-160.3HippenABaumgartenGRosenwinkelK-HSeyfriedCF.Aerobicdeammonification-AnewexperienceinthetreatmentofwastewatersJ.WaterScienceandTechnology19973510305-315.4KuaiLPVerstaeteW.AmmoniumremovalbytheOxygen-Limitedautorophicnitrification-denitrificationsystemJ.Appl.Env.Tech.199939713-21.5.-J.200016229-31.6HaoXJosephJMarkCM.Model-basedevaluationoftemperatureandinflowvariationsonapartialnitrificationANAMMOXbiofilmprocessJ.Waterresearch200236194839-4849.7KeisokeHanaki.Nitrificationatlowlevelsofdissolvedoxygenwithandwithoutorganicloadinginsuspended-growthreactorJ.Wat.Res.46321990243297-301.8LaanbroekHJBodelierPLEGerardsS.OxygenconsumptionkineticsofNitrosomoaseuropaeaandNitrobacterhamburgensisgrowninmixedcontinuousculturesatdifferentoxygenconcentrationsJ.ArchMicrobiol1994161156-162.9.A/OJ.2006265703-70.10AbelingVSeyfriedCF.Anaerobic-aerobictreatmentofhigh-strengthammoniumwastewaternitrogenremovealvianitriteJ.Wat.Sci.Tech.19922651007-1015.11KongZPVerstrateW.AutomatedrespirationinhibitionkineticsanalysisARIKAwitharespirographicbiosensorJ.Wat.Sci.Tech1994304275-284.12AnthonisenACLoehrRCPrakasamTBSetal.InhibitionofnitrificationofammoniaandnitrousacidJ.JournalofWaterPollutionControlFed1976485835-852.13.J.199523-6.14BenmoussaH.MartinG.RichardY.etal.Inhibitionofnitrificationbyheavymetalcations.Wat.Res.198620111333-1339.15.J.200619126-29.16PolliceATandoiVLestingiC.InfluenceofaerationandsludgeretentiontimeonammoniumoxidationtonitriteandnitrateJ.WaterResearch2002362541-2546.17VanKempenRMulderJWUijterlindeCAetal.OverviewfullscaleexperienceoftheSHARONprocessfortreatmentofrejectionwaterofdigestedsludgedewateringJ.WaterScienceandTechnology2001441145-152.18.J.2007233102-105.Analysisofinfluencefactorsonwastewaterbiologicaltreatmentprocessofshortcutnitrification-denitrificationYANGRi-guang1ZHANGLan-he12*LIUQiang11.SchoolofChemicalEngineeringNortheastDianliUniversityJilinJilin1320122.SchoolofMunicipalandEnvironmen-talEngineeringHarbinInstituteofTechnologyHarbin150090AbstractEffectoftemperatureDOFApHandsludgeageonshortcutnitrification-denitrificationisanalyzedafterthemechanismofshortcutnitrification-denitrificationisintroduced.Nitriteaccumulationcanbeeasilyre-alizedwhenlowtemperature12-14℃orhightemperatureabove30℃iskeptDOisabout0.5mg/Lfreeammoniaconcentrationisbetween1.0mg/Land5.0mg/LpHvalueisnear8.0andsludgeageisbe-tweenthegenerationcycleofAOBandthegenerationcycleofNOB11d-15drespectively.KeywordsBiologicaldenitrificationShortcutnitrification-denitrificationMechanismanalysis561

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