沸石曝气生物滤池预处理微污染水源水中氨氮的研究杨林

:　,,1985,,。#。＊(No.107046);(No.NECT-07-0175);(No.08JC1400500)。沸石曝气生物滤池预处理微污染水源水中氨氮的研究＊杨　林　薛　罡#　李小琴　汪永辉(,201620)　　　,。:(1),。5.00mg/L,30min,0.66mg/L,86.8%,。(2),,。0.4m3/(m2·h)1.3m3/(m2·h),13.2%。(3),,。0.5(,)、1.0、1.5,81.8%、85.3%、86.7%。(4)200～600mm,600mm89.7%,96.9%,600mm,。　　　　　　Pretreatmentofammonianitrogeninmicro-pollutedsourcewaterbyzeolitebiologicalaerationfilter　YangLin,XueGang,LiXiaoqin,WangYonghui.(SchoolofEnvironmentalScienceandEngineering,DonghuaUniversity,Shang-hai201620)Abstract:　Zeolitebiologicalaerationfilterwasemployedforthepretreatmentofammonianitrogenmicro-pollu-tedsourcewater.Theadsorptioncharacteristicandeffectofoperationparametersonadsorptionefficiencywereinves-tigated.Thestaticabsorptionprocesspresentedthecharacterofquickadsorptionandslowbalance,after30minofab-sorption,86.8%ofammonianitrogenwasremovedfrommicro-pollutedsourcewater(ammonianitrogenconcentrationof5.00mg/L),thenthechangetendedtostability.Whenhydraulicloadingrangedfrom0.4m3/(m2·h)to1.3m3/(m2·h),theremovalrateofammonianitrogenhadalittlechange.Ammonianitrogenremovalratewasincreasedwithincreasingofgas-waterratio,whenthegas-waterratiowere0.5,1.0and1.5,theremovalrateofammonianitro-genwere81.8%,85.3%,86.7%respectively.Theoptimumlayerwasfrom200mmto600mm,89.7%ofammonianitrogenwasremovedattheheightsof600mm.Keywords:　zeolitebiologicalaerationfilter;micro-pollutedwater;pretreatment;ammonianitrogen　　,。,,。,、、,,,,“”。　　,。,,、,。,,。　　,,,、、,。1　1.1　实验进水,1。·9·　　DOI:10.15985/j.cnki.1001-3865.2009.11.0041　Table1　Qualityofmicro-pollutedrawwaterpH/(mg·L-1)/(mg·L-1)254nm(UV254)/cm-17.5～8.06.32～8.681.32～2.850.1170～0.26987.87.551.860.18951.2　沸石性质65%(),1.0～3.0mm,2,Cu、Pb、As、Be、Zr、Ni、P、Mo、Sn、Ca、V、Yb、Y、Nb、La。:2.16g/cm3,3～4,230～320m2/g,0.0187mL/g,3.5～4.0,4.25～5.25,750℃。1.3　实验装置　　80mm,1200mm,800mm,4L,100mm,1。、,,[1]。,,1　Fig.1　Theschematicdiagramoftestdevice。,。1.4　沸石的静态吸附实验　　0.50～3.30mg/L,5.00～7.00mg/L[2]。1g250mL,5.00mg/L100mL,,,。　　,pH,。1g250mL,10.00、20.00、40.00、80.00、100.00mg/L100mL,pH,,,1h,15min,pH,。1.5　运行条件对氨氮去除效果的影响实验1.5.1　pH7.5～8.0、19.8～21.6℃、1.0(,),0.4、0.7、1.0、1.3m3/(m2·h)。1.5.2　　　pH7.3～7.8、21.3～22.9℃、1.0m3/(m2·h),0.5、1.0、1.5。1.5.3　　　pH7.2～8.1、22.1～23.8℃、1.0m3/(m2·h)、1.0,。2　2.1　静态吸附实验结果2,0～10min,2　1)Table2　Compositionsofnaturalclinoptilolite%　SiO2TiO2Al2O3Fe2O3FeOMnOMgOCaONa2OK2OH2O66.210.1310.990.960.110.040.532.982.220.926.45　　:1)。·10·　　31　11　200911,;10～30min,,,、;30min,。10min,1.32mg/L,73.6%;20min,0.97mg/L,80.6%;30min,0.66mg/L,86.8%。2　Fig.2　Varietyofammonianitrogenduringabsorption　　,Na+NH+4,pH,3。3　pHFig.3　VarietyofpHduringabsorption2.2　运行条件对氨氮去除效果的影响结果2.2.1　,。4,,。5,0.4m3/(m2·h)1.3m3/(m2·h),13.2%;0.4～1.0m3/(m2·h),;1.0m3/(m2·h)1.3m3/(m2·h),79.1%71.6%。,,,,[3],,,[4]。,,,。,[5],。2.2.2　。6,0.51.0,;1.0,,,。,,·11·　　,,,,,,。7,0.5,81.8%;1.0,85.3%;1.5,86.7%,1.01.4%。2.2.3　8:(1)0～200mm,,,,,,,,2,,,。(2)200～600mm,600mm89.7%,96.9%,600mm,。,,,,,,,[6]。,,,200mm,,,200mm,。(3)600～800mm,,,,200～600mm,600mm。8　Fig.8　Concentrationofammonianitrogenatdifferentheightsoffillerlayer3　　(1),。5.00mg/L,30min,0.66mg/L,86.8%,。　　(2),。0.4m3/(m2·h)1.3m3/(m2·h),13.2%。(下转第16页)·12·　　31　11　200911　　2(c),DTP/TPDIP/TP。,DTP/TP。,,DTP/TP23.75%()43.85%()。(62.91%),DTP/TP39.16()19.06()。,DTP/TP24.90()23.37()。,,DTPTP,PP。3　　(1),,,,。,TP,,,PP。　　(2),。,DIP/DTP、DIP/TP、DTP/TP,PP。:[1]　PALOMOL,CLAVEROV,IZQUIERDOJJ,etal.Influenceofmacrophytesonsedimentphosphorusaccumulationinaeu-trophicestuary(PamonesRiver,SouthernSpain)[J].AquaticBotany,2004,80(2):103-113.[2]　EDLUNDG,CARMANR.Distributionanddiagenesisofor-ganicandinorganicphosphorusinsedimentsoftheBalticprop-er[J].Chemosphere,2001,45(6/7):1053-1061.[3]　LIW,fRIEDRICHR.Insituremovalofdissolvedphosphorusinirrigationdrainagewaterbyplantedfloats:preliminaryre-sultsfromgrowthchamberexperiment[J].AaricultureEcosys-tems&Environment,2002,90(1):9-15.[4]　PERKINSRG,UNDERWOODGJC.Thepotentialforphos-phorusreleaseacrossthesediment-waterinterfaceinaneu-trophicreservoirdosedwithferricsulphate[J].WaterRe-search,2001,35(6):1399-1406.[5]　,,,.[J].,2007,20(2):78-83.[6]　SφNDERGAARDM,WINDOLFJ,JEPPESENE.Phosphorusfractionsandprofilesinthesedimentsofshallowdanishlakesasrelatedtophosphorusload,sedimentcompositionandlakechemistry[J].WaterResearch,1996,30(4):992-1002.[7]　,.[J].,1996,15(1):15-19.[8]　RYDINE,WELCHEB.Aluminumdoserequiredtoinactivatephosphateinlakesediments[J].WaterResearch,1998,32(10):2969-2976.[9]　,,,.[J].,2003,24(1):40-45.[10]　KIMLH,CHOIE,GILKI,etal.PhosphorusreleaseratefromsedimentsandpollutantcharacteristicsinHanRiver,Se-oul,Korea[J].ScienceoftheTotalEnvironment,2004,321(1/2/3):115-125.[11]　,,,.[J].,2005,24(3):521-525.[12]　,,,.———[J].,2006,18(2):179-183.[13]　,,,.———[J].(D),2005,35(Ⅱ):33-44.[14]　,,,.[J].(D),2003,33(8):760-768.[15]　,,,.-:2.-[J].,2006,18(3):207-217.[16]　,,,.[J].,2007,28(1):70-74.[17]　,,.[J].,2002,24(4).[18]　FROELICHPN.Kineticcontrolofdissolvedphosphateinnaturalriversandesturies:aprimeronthephosphorusbuffermechanism[J].Limnology&Oceanography,1988,33(4):649-668.编辑:陈泽军　(:2009-05-16)(上接第12页)　　(3),,。0.5、1.0、1.5,81.8%、85.3%、86.7%。　　(4)200～600mm,600mm89.7%,96.9%,600mm,。:[1]　.[D].:,2006.[2]