沸石在多种环境介质中的应用研究进展张冬娜

　256　　　　　　　　　硅　酸　盐　通　报　　　　　　　　Vo.l25　No.6　200612　　　　　　　BULLETINOFTHECHINESECERAMICSOCIETY　　　　　　December,2006　张冬娜1,弓爱君1,宋永会2,袁　鹏2,彭剑峰2(1.,　100083;2.,　100012):。、,、,。,,。:;;;ResearchProgressontheApplicationofZeoliteinMultipleEnvironmentalMediaZHANGDong-na1,GONGAi-jun1,SONGYong-hui2,YUANPeng2,PENGJian-feng2(1.DepartmentofChemistry,CollegeofAppliedScience,UniversityofScienceandTechnology,Beijing100083,China;2.DepartmentofWaterPollutionControlEngineering,ChineseResearchAcademyofEnvironmentalScience,Beijing100012,China)Abstract:Zeoliteisakindofaqueoussilicoaluminatemineralwithexcellentadsorptionfunction.Inthispaper,thecrystalstructureofzeolite,itscharacteristicsofadsorptionandionexchangeweredescribed.Theprogressofresearchandapplicationofzeoliteinwastewatertreatment,soilimprovementandwastegastreatmentathomeandabroadinrecentyearswerecommented.Suggestionsfortheexploitationandapplicationofthezeoliteinmultipleenvironmentshadbeenputforward.Asafunctionalloadingmaterial,zeoliteshouldbepopularizedinenvironmentalpollutioncontro.lKeywords:zeolite;multipleenvironmentalmedia;loadingfunction;adsorption:;(No.2004-021);(No.2004-2005):(1978-),,..:,E-mail:[e-mail]　　Cronsted1756,,[1,2],、、,、、。,、、、、、、、、、13,,,。,140,,、。,。,、、,。1　沸石的组分和基本结构(Na,K)x(Mg,Ca,Sr,Ba)y(Alx+2ySin-(x+2y)O2n)mH2O,SiO2、Al2O3、H2ODOI:牨牥牨牰牭牭牪牤jcnkiissn牨牥牥牨牨牰牪牭牪牥牥牰牥牰牥牪牴130　　　　　　　　25()。[3,4](1),(),,2:　　,SiO1:2。,Al+3,-1。,1()。,,,。,,,,、,0.3～1.1nm。,,、。,。,,、。2　沸石在水处理中的应用2.1　、400～800m2/g。,,N2、F2、NH4+、CH3OH。,1.9～2.3g/cm3,,,、,[5]。。Chang[6],,2.2×109CFU/mL,6.5×108CFU/mL,。,,NH+4,,NH+4。[7],,COD、。2.2m/h(1.4h),COD、73.9%、88.4%96.2%,43.4mg/L、3.5mg/L3.7NTU,(III)。2.2　2.2.1　　,。,,(),,,。,。。[8]。,,,,。,。　6:131　　Ouki[9]Pb、Cd、Cu、Zn、Cr、NiCo7,,Pb2+,Pb2+100%。(Pb),Zn30×10-6mg/L,36%;Zn10×10-6mg/L,88%。,Zn(1～30)×10-6mg/L,Zn91%～99%。,Si4+Al3+,,,。,,,。Mabel[10],,。,pH8.0Pb、pH10.0Cd,95%;Cr(VI),PbCd,,。,。[11],,,pH≥4,Cr(VI)≤300mg/L,Cr(VI)1:500,Cr(VI)99%,。2.2.2　　,,,,,,。,,,,。,。[12],,NH3-N、NO2-N、Mn、、。,NH3-N、NO2-N93%、90%32%。[13],2%NaCl20～40。pH,pH=5,12.96mg/g;,246mg/L21.3mg/L,91.3%。Jorgensen[14]。,,,,NH+4pH。Ciambelli[15]Phlipsite,。,95%,。2.2.3　　,CCl4、CH4,,,,。Chang[6],7,COD88%;5,COD92%,BOD99%,78%。Razee[16]。4h,、、4-、2-、4-、2-、4-、2--4-45%～64%;(CDs),α-CD,65%～74%。[17]80,、、、132　　　　　　　　25,,pH4～5,200～250℃“”。pH≈9、CODCr3500mg/L,1:900,CODCr450～960mg/L,。3　沸石在土壤改良和修复中的应用3.1　,[18],,、。,,。,NH+4、PO3-4K+,,[19]。[20],NH+4105.7～137.1cmol/kg,9;NH+460%,NH+4,NH+4。,,,、,。,,,,。,,,,。[21],,。,5%～15%,27.9%,。;5%,7～8[22]。3.2　,、,。,,。,,,[23]。Gworek[24]Cd,、Cd。1%,,Cd86%。:13X(0.9nm)4A(0.42nm),13XCd4A,。,。4　沸石在治理废气和除臭抗菌方面的应用4.1　,H2O、NH3、H2SCO2,、、,,、。Siriwardane[25],CO2。,,,3(2)CO2、N2、O2,CO2,,CO2N2、O2。Ichiura[26],。,,,,。　6:133　　4.2　,NH3、H2S,,。,,、,,,[27]。2060,[28]。,、,[29]。,[30],NH3,,,。5　沸石的其它应用,、,[31],[32],,,。,,,,。,、、,。6　展　　望、,。,,:(1),,。(2)、,、。(3),。(4)、。,,,,。[1]　　,　.[J].,1998,24(7):60-63.[2]　.　[M].:,1980:1-15.[3]　,,,.[M].:,1986:1-12.[4]　DavisME.Zeoliteandmolecularsievesynthesis[J].ChemMater,1992,4(4):756-758.[5]　RaykalBB.Performanceofclinoptilolitealoneandincombinationwithsandfiltersforremovalofammoniapeaksfromdomesticwastewater[J].WaterSciTechnol,1996,35(7):47-54.[6]　ChangWS,HongSW,ParkJ.Effectofzeolitemediaforthetreatmentoftextilewastewaterinabiologicalaeratedfilter[J].ProcessBiochem,2002,37(7):693-698.[7]　,,　.COD[J].,2002,18(12):13-15.[8]　　,,,.[J].,2002,25(2):49-50.[9]　OukiSK,KavamiaghM.Treatmentofmetals-contaminatedwastewatersbyuseofnaturalzeolites[J].WaterSciTechnol,1999,39(10-11):115-122.[10]　MabelVM,CallejasRL,GehrR,eta.lHeavymetalremovalwithMexicanclinoptilolitemulti-componentionicexchange[J].WaterRes,2001,35(2):373-378.[11]　,,　.[J].,1997,15(3):13-15.[12]　,,.[J].,2000,21(5):71-73.134　　　　　　　　25[13]　,,,.[J].,2002,3(12):60-63.[14]　JorgensenTC,WeatherleyLR.Ammoniaremovalfromwastewaterbyionexchangeinthepresenceoforganiccontaminants[J].WaterRes,2003,37:1723-172.[15]　CiambelliP,DrzaiB,HocevarS,eta.lZeolitesynthesisstructuretechnologyandapplication[J].Amsterdam:Elsevier,1985:185-187.[16]　RazeeS,MasujimaT.Uptakemonitoringofanilinesandphenolsusingmodifiedzeolites[J].AnalChimActa,2002,64:1-5.[17]　,,,.[J].,1999,18(4):335-338.[18]　.[J].,1991,23(2):320-325.[19]　AndoH,MiharaC.Thefateofammoniumnitrogenappliedtofloodedriceasaffectedbyzeoliteaddition[J].SoilSci,1996,42:531-538.[20]　,,,.[J].,1990(2):71-75.[21]　　,,,.[J].,1993,16(4):48-52.[22]　MaoRLV,SjiarielB,DunniganJ.Asbestos-derivedzeolitesaswater-retainingmaterialsinsoils[J].Zeolites,1991,11(8):804-809.[23]　PhillipsIR.Theuseofsoilamendmentstoreducenitrogenphosphorusandheavymetalavailability[J].JSoilContam,1998,7(2):191-212.[24]　GworekB.Inactivationofcadmiumincontaminatedsoilsusingsyntheticzeolites[J].EnvironPollut,1992,75:269-271.[25]　SiriwardaneRV,ShenM-S,FisherEP,eta.lAdsorptionofCO2,N2andO2onnaturalzeolites[J].EnergFuel,2003,17(3):571-576.[26]　IchiuraH,NozakiM,KitaokaT,eta.lInfluenceofuniformityofzeolitesheetspreparedusingapapermakingtechniqueonVOCadsorptivity[J].AdvEnvironRes,2003,7(4):975-979.[27]　,,　,.[J].,2002,(3):7-10.[28]　,.[J].,1995,15(6):42-43.[29]　MinerJR.Useofnaturalzeoliteinthetreatmentofanimalwas