氟的危害及控制

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3(,450002)(,450052)(,471002)FluorineHarmandControl.JiaoYou,YangZhanping(SoilandFertilizerInstitute,HenanAcade2myofAgriculturalSciences,Zhengzhou450002),FuQing(BasicMedicineCollege,HenanMedi2calUniversity,Zhengzhou450052),WangLiuhao(ForestryShoolofHenanProvince,Louyang471002).ChineseJournalofEcology,2000,19(5):67-70.Basedonsurveyoftheliteratreconcerned,theFharmonplants,soilmicrobesandhumanhealth,ge2ographicdistributionoftheareaswithhighFwaterandthestatasofFepidemicareasareintro2duced.AndthemethodsofcontrollingFharmandtestingFinsoilarealsopresented.Keywords:fluorineharm,controlmethod,fluoridetest,Fpoisoning,geographicdistribtion.3,:,,31,,19922,10,[1,2],,,1[3][2],[4],,[5],[6],,[7][8]Kundu[9],,,,Braen[10],,Al,FAlWilke[11],,,(APA)(ASA),Al2F;,(DHA),,[12],,2[13],[14,15]196922(WHO)[16][17],[16]20,,1937,2000,19(5)67-70ChineseJournalofEcology[13],,,[13,16],,1930HF,60[18];1952,[14]1mgkg-1,[1][17],,[19],F/Cl0.4,4mgkg-1,,,,[1,16][20,21],,[22]3,,,,,,,,(1),pH,1Tab.1FcontentsanditsharminthesoilformwesttoeastoftheEast-HebeiPlain100-50(m)50-40(m)40(m)()62.159.845.319.988.570.083.683.1102.551331156072992460128279390753464118558708800541111001183316124443670104121147112437(%)24371011131040,,,,,,,,,,,,,4,,,,,,[23],,[24],F-,(),F-,[25],,F-[13],[26],,[27],[24][2830],[31][32],86195[33]pH,F-Ca2+CaF2,Wenzel[34],pH6.06.5,,pH610pH615,[35],,F-Ca2+,pH,,,Garrec[36]45Ca,,5,,,,5.1,,[37][38],[39],[37,4043],Brewer[41],[24],,,,5.2,[44],,,,[41],[45],,[41],,,,[22,38,46,47],,,(TISAB)[46,48,49],(),A13+Fe3+Mn4+Cu2+,,pH,[1]Chauhan,C.P.S.etal.BoronandfluorinehazardsinundergroundwaterofsemiaridtractofIndia.A2grochimica,1988,32(2-3):199-204.[2]Yamauchi,M.etal.Fluorideinhibitionofphtosyn2thesisincertaincropplants.SoilSciPlantNutr.,1983,29(4):549-553.[3]Chang,C.W.Fluorides.Inresponesofplantstoairpollution.Fluorides.London:AcademicPress,1975.[4]Moeri,P.B.Effectsofflouridemeissionsonenzymeactivityinmetabolismofagriculturalplants.Fluo2ride,1988,13(3):122-129.[5],..:.1985.234-245.[6]Malik,D.N.etal.Flourideabsorptioninsoilsasin2fluencedbytexture,sodicityandcalciumcarbnate.IndiaJ.Agric.Res.,1987,21(2):110-116.[7]Singh,A.etal.Effectoffluorineandphosphorusontheyieldandchemicalcompositionofricegrowninsoilsoftwosodicities.SoilSci.,1979,127:86-93.[8]EdwardGroth.Fluoridepollution.Environ2ment,1975,17(3):29-37.[9]Kundu,S.etal.Effectofflouriedonphosphateuti2lizationbywheat.J.NuclearAgric.Biol.,1987,16:65-68.[10]Braen,S.N.andL.H.Weinstein.Uptakeoffluorideandaluminumbyplantsgrownincontanminatedsoils.WaterAirandSoilPollution,1985,24:215-218.[11]Wilke,B.M.Fluoride-inducedchangesinchemi2calpropertiedandmicrobialactivtyofmull,moderandmorsoils.BiolFertilSoils,1987,5:49-55.[12]..,1989,8(5):7-9.[13]..,1979,(2):29-31.[14]..,1981,1:77-83.[15]Singh,A.etal.AnepidemiologicalbiochemicalandclinicalstudyintheBhatinhadistrictofPunjab.In2dianJ.Med.Res.,1962,50:387-398.[16]..,1982,(10):6-7.96:[17]..,1982,(10):6-7.[18]..,1977,5:1-8.[19],..,1981,2(6):5-6.[20]Gupta,R.K.etal.Fluorioneadsorptionbehaviorinalkalisoil:relativerrolesofpHandsodicity.SoilSci.,1982,133(6):364-368.[21]..,1997,28(3):116-118.[22]Gopal,R.etal.EstimationofFluorideandnitrateingroundwatersofaridregionsofRajasthanusingionselectiveelectrodes.AnnalsofZone,1981,27(2-3):241-245.[23]..,1996,14(1):82-86.[24],..:.1990.64-83.[25]..,1990,9(3):20-24.[26]Fluhler,H.etal.Retentionandmovementoffluo2rideinsoils.J.Environ.Qual.,1982,11(3):461-468.[27]..,1992,8():163-168.[28]..,1985,4(1):30-41.[29]Polomski,J.etal.Accumulationofairbornefluorideinsoils.J.Environ.Qual.,1982,11(3):457-461.[30]Singh,A.etal.Effectoffluorineandphosphorusappliedtoasodicsoilontheiravailabilityandonyieldandchemicalcompositionofwheat.SoilSci.,1979,128(2):90-97.[31]..,1982,3(6):70-74.[32]Chhabra,R.etal.Fluorineinsodicsoils.SoilSci.Soc.Am.J.,1980,44:33-36.[33]Street,J.Fluoritesolubineinsodicsoils.J.SoilSci.Soc.Am.J.,1983,47:483-485.[34]Wenzel,W.W.andW.E.H.Blum.Fluorinespeci2ationandmobilityinF-contaminatedsoils.SoilSci.,1992,153(5):357-364.[35]..,1993,30(4):416-422.[36]Garrec,J.P.etal.Calciumaccumlationinrelationtofluoridepollutioninplants.Fluoride,1982,15(3):144-149.[37]Page,A.L.etal.Methodsofsoilanalysis(part2):Chemicalandmicrobiologicalproperties(Aecondedi2tion).Madison,WisconsinUSA.1982.[38].(,)..1987.344-348.[39]..:.1985.[40]..,1988,25(3)236-242.[41]Brewer,R.F.Methodsofsoilanalysis(part2).Fluorine.Agronomy,1965,9:1135-1148.[42]Gilpin,L.andA.H.Johnson.Fluorineinagricul2turalsoilsofsoutheasternPennsylvania.SoilSci.Soc.Am.J.,1980,44:255-258.[43]Larsen,S.andA.E.Widdowson.Soilflourine.J.SoilSci.,1971,22:210-211.[44]Willard,H.H.andO.B.Winter.Volumetricmethodfordeterminationoffluorine.Ind.Eng.Chem.Anal.,1933,5:5-10.[45]Hardin,L.J.Trportonthedeterminationofflourinecontentofsoils.J.Assoc.ofAgric.Chem.,1952,35:621-633.[46]..,1990,4(4):26-27.[47]Hopkins,D.M.Animprovedionselectiveelectroedmethodfortherapiddeterminationoffluorineinrocksandsoils.J.Res.U.S.Geol.Surrey,1977,5:589-593.[48]Moore,C.S.andG.S.P.Ritchie.Aluminumspecia2tionandpHofscidsoilinthepresenceofflouride.J.Soil

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