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SeriesNo．430April2012METALMINE430201241953—430070122。。、。HazardsofFluoridePollutionandTechnicalResearchProgressofTreatingFluoride-containingWastewaterLeiShaominGuoZhenhuaSchoolofResourcesandEnvironmentalEngineeringWuhanUniversityofTechnologyAbstractConcludethefluoridepollutionsourcesintroducethehazardsoffluoridepollutiondiscussthefluoride-containingwastewatertreatmenttechnicalresearchprogressandanalyzetheexistingproblemsoffluoride-containingwastewatertreatmentmethodsfinallypointoutthatthenewfunctionalmaterialscombinationprocessandresourceutiliza-tiontechnologyarethekeyorientationoffluoride-containingwastewatertreatmentresearch．KeywordsSourcesoffluoridepollutionHazardsoffluoridepollutionFluoride-containingwastewatertreatmenttech-nologyResearchprogress。1．0mg/L。。1“”、、、、、、、、1。、。AlF3Na3AlF6、、、2、、、、、3。SiF4、HFSiF2－6CaF24。22.1。6。———、。。、·251·。、、、、、、5。Kundu7。Braen8AlF、Al。9、。2.2。。2.2.11。0.11mg/g。。2。。、、、。3。。、。2.2.2。1。。“”。2。、。、、。3。、、。4。1925Schulz10。、11。3、、、。3.13.1.1。Ca2++2F－→CaF2↓．、15～30mg/L、、。。、、F－Al3+。1238mg/L·351·201245mg/L。3.1.2F－A13+、Fe3+、Mg2+、、、。。AlOH3。pH5.5～7.5。。RajivGandhi13。14。pH6.25.425℃。、、、、、、15。3.2。15～30mg/L。、、。、、、、、、、、、、、Ti、Ce、La。16pH12、40～50℃。。YumingZhou17La3+、pH、。20mg/LpH5～7、40min、4g/L4.9mg/g98.8%。、、。。、。3.3、、、。3.3.1、。。。18、200mg/L80%～85%。3.3.2·451·43020124F－。F－2mg/L。194.52mg/L21A/m215.1g/gF－68%3。、。3.3.320-23。24001×7H、La、AlAl。AlR—SO3。、。3.3.4、。。－、、、、25。。4。。1．J．2005417-19．2WangAGXiaTChuQLetal．Effectsoffluorideonlipidperox-idationDNAdamageandapoptosisinhumanembryohepatocytesJ．BiomedEnvironSci2004172217-222．3．J．2007264119-126．4．J．200724165-66．5．M．1985234-245．6SinghAetal.EffectoffluorineandphosphorusontheyieldandchemicalcompositionofricegrowninsoilsoftwosodicitiesJ．SoilSci197912786-93．7KunduSetal．EffectofflouriedonphosphateutilizationbywheatJ．NuclearAgricBiol19871665-68．8BraenSNandWeinsteinLH．UptakeoffluorideandaluminumbyplantsgrownincontanminatedsoilsJ．WaterAirandSoilPollu-tion198524215-218．9．J．200120294-97．10．J．200118467-69．11．CJ．2000168697-699．12．CaCl2+J．199824212-24．13MeenakshiRCetal．FluorideindrinkingwateranditsremovalJ．JournalofHazardousMaterials2006137456-463．14．J．200714343-46．15PitterP．FormsofoccurrenceoffluorineindrinkingwaterJ．WaterRes1985193281-284．16．J．2002303366-372．17ZhouYumingYuChunxiangShanYun．AdsorptionoffluoridefromaqueoussolutiononLa3+-impregnatedcross-linkedgelatinJ．SeparationandPurificationTechnology200436289-94．18．J．19981431-5．159·551·20124656.62%5～73000g/t。。3.2。76。76/%/g/t/%2.04867061.6797.9611238.33100.00287100.0061118670g/t、61.37%。41。2、+、、8670g/t、61%。1．J．2006398-100．2．、J．2007382-84．3．D．2002．4．Ag+J．200626345-47．2012-02-17檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪1475.J.200524203730-3736.6.J.199965-7.7.J.19951621-14.8BrummerRichardAndrieuxPatrick.———J.200423203444-3449.9.J.200526121936-1940.10.J.20042591-9.2012-01-24檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪15519．J．198410213-17．20．———J．200421366-68．21．J．2003326553-555．22．Al－J．200016487-89．23．J．2002366-69．24．D．2007．25．J．19823552-56．2012-02-23·951·20124