辐照交联超高分子量聚乙烯的生物摩擦学性能研究

ssss3162
0 ℃
2020-07-17

整理文档很辛苦，赏杯茶钱您下走！

还剩 ... 页未读，继续阅读 >>

免费阅读已结束，点击下载阅读编辑剩下 ... 页

阅读已结束，您可以下载文档离线阅读编辑

资源描述

๭ߡන೺ǖ762008-10-30גߛݴጱଉ਋ᅚဗǄUHMWPEǅਏᆶଆࡻڦิ࿿၎ඹႠĂࣅბ࿘ۨႠĂ؋ऍႠĂఱఉႠतఱޫ์Ⴀǈ๟ඇ࠲বዃ्༹࣑ኧ׫௬໯೵Փ჋ᆩڦ֌ଙǈᆌᆩᇀට߾ợ࠲বڦኲ෇࿿ᅙᆶ40ܠ౎ڦ૦๏[1]ă඗ܸǈሞ׊೺ڦ๑ᆩࡗײዐሰׯڦఉ໦ᅜतఉႈओ਋ǈᅟᆅഐࠡዊම঴ǈ݀ิ࿮ਪ຿ۯǈܸٗेዘକ࣒ኁڦས੮ǈইگକට߾࠲বڦ๑ᆩ๱ం[2-4]ăኄٝ๑ට்ლ൱ิ࿿ఊ։ბႠీ߸ᆫᅴڦට߾࠲ব༺پ֌ଙǈईܔ၄ᆶ֌ଙ৊ႜ߀Ⴀǈᅜٳڟ༵ߛ֌ଙఱఉႠڦణڦăణമǈ๘হฉܔᅅᆩUHMWPEڦఊ։ఉ໦Ⴀీڦ߀Ⴀ੗ݴྺ঍૴߀Ⴀࢅ࿿૙߀Ⴀă঍૴߀Ⴀᆼ੗ݴྺࡗᄟࣅ঍૴Ă౾૴व঍૴ࢅޖቷ঍૴Ǘ࿿૙߀Ⴀᅃӯ๟ኸགଙ߀Ⴀăഄዐǈޖቷ঍૴ీ၂ዸ༵ߛUHMWPEڦఱఉႠ[5]ăԨ࿔֑ᆩ˹-พ၍ܔᅅᆩUHMWPE৊ႜޖቷ঍૴ت૙ǈჺ৯ޖቷ঍૴ܔᅅᆩUHMWPE૰ბࢅิ࿿ఊ։ბႠీڦᆖၚă1ํᄓևݴ1.1ᇱଙUHMWPEǈݴጱଉ5000000ǈெࡔTiconaࠅິă1.2ᅏഗᇑยԢඤუฏ঳ୗǈZT-40-20YBǈฉ࡛ץࣀۉୗᆶ၌ࠅິǗཞօඤݴဆᅏǈSTA409CǈڤࡔNetzschࠅິǗྲఊ։ఉ໦๬ᄓऐǈUMT-IIǈெࡔCETRࠅິǗۉጱྤీ๬ᄓऐǈWDW-20ǈ׊ؾ๨וᄞ๬ᄓᅏഗᆶ၌ࠅິă1.3๬ᄣ዆ԢॽUHMWPEݹଙጎ෇ఇਏǈ׉࿒ူ5MPaᇨუ15minǗ඗ࢫǈॽఇਏݣ෇ेඤୗዐǈሞ200ņူԍ࿒2hǗໜࢫǈॽఇਏൽ؜ǈᅜ10MPaԍუ዁ఇਏ࿒܈ই዁40ņᅜူǈनڥׯ႙๬ᄣăॽ๬ᄣሞ๪࿒Ă੣ഘዐǈ֑ᆩ˹-พ၍৊ႜޖቷǈޖቷवଉྺ100kGyă1.4঳ৗ܈֪֑ۨᆩཞօඤݴဆᅏ֪ۨᄣ೗ڦDSC൸၍ăॽޖቷ঍૴גߛݴጱଉ਋ᅚဗڦิ࿿ఊ։ბႠీჺ৯StudyonBiotribologicalPropertyofIrradiationCrosslinkedUHMEPEएূၜణǖڍࠑᒬཨመߥ۲᧚᧗ཁᮉᄫ὇Ὀፕኁ०঻ǖϓᒬ˗ úὋႃὋ෇ᔙᄡ̠ۡὋӯܢᆐቂၶὋ˞᜵̯̂ၶྫྷ୔୺ߥழ᭦ᄉᆐቂǌWpm/48!Op/2!)Tvn/312*Kbovbsz!!311:ృጲݿNiZifeng-ዐࡔઁᄽٷბऐۉ߾ײბᇾఊ։ბᇑ੗੍Ⴀ߾ײჺ৯໯ఊ։ბࡔॆዘۅํᄓ๪ิ࿿ఊ։ბዐ႐ǈॿ໋Ⴘዝ221116-BiotribologyCenter,StateKeyLaboratoryofTribology,InstituteofTribologyandReliabilityEngineering,CollegeofMechanicalandElectricalEngineering,ChinaUniversityofMiningandTechnology,Xuzhou221116,China୑Ǌ᜵:֑ᆩ˹-พ၍ܔᅅᆩגߛݴጱଉ਋ᅚဗǄUHMWPEǅ৊ႜޖቷ঍૴ت૙ǈჺ৯କޖቷ঍૴ܔᅅᆩUHMWPE૰ბႠీࢅิ࿿ఊ։ბႠీڦᆖၚă঳ࡕ՗௽ǖޖቷ঍૴๑UHMWPEڦ঳ৗ܈Ăᆘ܈ĂڑႠႠీĂੇࣄ࢓ీ૰ࢅఊ։ఉ໦Ⴀీ༵ߛǈڍইگକUHMWPEڦ໒ႠႠీăAbstract:Themedicalultra-highmolecularweightpolyethylene(UHMWPE)wasirradiationcrosslinkedby˹-rays,theeffectofirridiationcrosslinkingonthemechanicalpropertyandbiotribologicalpropertyofUHMWPEwasstudied.Theresultsshowthatirradiationcrosslinkingimprovesthecrystallinity,hardness,elasticproperty,anti-scratchpropertyandwearresistancofUHMWPE,butdecreasestheplasticpropertyofUHMWPE.С᪃ជ:גߛݴጱଉ਋ᅚဗǗޖቷ঍૴Ǘิ࿿ఊ։ბKeywords:UHMWPE;Irradiationcrosslinking;Biotribology૙ࣅ֪๬࿔ቤՊࡽǖ1005-3360Ǆ2009ǅ01-0076-03஠࿸ಕខᆉ:A˖ڎѫዜՁ:TQ325.1277311:౎!2ሆ!ڼ48ਝ!ڼ2೺Ǆጺڼ312೺ǅޖቷ঍૴גߛݴጱଉ਋ᅚဗڦิ࿿ఊ։ბႠీჺ৯UHMWPE๬ᄣǄሀ5~10mgǅٗ๪࿒ेඤ዁180ņǈื࿒໏୲10ņ/minăٗDSC൸၍ฉऺ໙30~170ņݔྷాڦဌඤރ௬ओǈᇑᅙኪ100%঳ৗڦUHMWPE๬ᄣڦභබඤܔԲǈन੗ڥڟԥ֪๬ᄣڦ঳ৗ܈xǈनǄ1ǅ๕ዐǈŗHĊĊ໯֪๬ᄣڦ঳ৗභබඤǗŗHcĊĊ100%঳ৗ๬ᄣڦභබඤǈྺ291J/gă1.5ᆘ܈֪ۨუ࢓ᆘ܈֪๬ӀENISO2039Ċ1Քጚሞྲఊ։Քጚ๬ᄓऐฉ৊ႜǈ჋ᆩ኱০ྺǄ5.0Ġ0.05ǅmmڦZrO2༩ٍ൰ă֪๬ࡗײዐǈ๯ံॽᄣ೗Ǆ40mmġ50mmġ4mmǅݣሞ֪๬ೝ໼ฉǗ඗ࢫӝ༩ٍ൰ᅜ9.8Nፕᆩ૰უ෇UHMWPE๬ᄣ՗௬ժԍ׼3sǗໜࢫॽፕᆩ૰ሺ዁132Nժԍ׼30sࢫႂሜǗሞ๬ᄓࡗײዐǈऻ୤უ࢓ศ܈ǈሶუ࢓ᆘ܈࣑໙ྺǖǄ2ǅ๕ዐǈHĊĊუ࢓ᆘ܈ǈMPaǗDĊĊ൰኱০ǈmmǗhmaxĊĊፌٷუ࢓ศ܈ǈmmǗPmaxĊĊፌٷፕᆩ૰ǈNă1.6؋უ२ൎഽ܈֪๬؋უ२ൎႠీ֪๬ᅈ਍ASTMF2183Ċ02Քጚሞۉጱྤీ๬ᄓऐฉ৊ႜă๯ံǈॽೌጒUHMWPE๬ᄣǄ኱০6.4mmǈࢩ܈1mmǅҾጎሞጆᆩॄਏዐǈස཮1໯๖Ǘ඗ࢫӝॄਏݣሞ๬ᄓऐฉ৊ႜუ໫ेሜǈუ໫࿋ᅎ໏܈ྺ0.5mm/minǈཞ้ऻ୤๬ᄣڦሜࢁ-࿋ᅎ൸၍ăⴤᖴ˖2.5mmUHMWPE䈅ṧ৊ᓖ˖1.0mmⴤᖴ˖6.4mm䙏⦷˖0.5mm/minⴤᖴ˖3.8mmᒣⴤߢཤ཮1؋უ२ൎ๬ᄓॄਏ๖ᅪ཮'JH4DIFNBUJDESBXJOHPGUIFIPMEFSPGUIFQVODITIFBSJOHUFTUJOHEFWJDF1.7ࣄ࢓ഽ܈๬ᄓࣄ࢓๬ᄓৎຼںఇెକఉ૭ఉ໦ऐ૙ڦڇ߲ᆘዊྲཫ༹ईఉ૭ሞްࢇ֌ଙ՗௬ڦఉ໦ࡗײă໲ፕྺްሗఉ໦ࡗײڦ०ࣅǈᅙׯྺ՗ኙ֌ଙఊ։ፆ૰ईఱఉႠڦዘᄲ๮܎ኮᅃăԨࣄ࢓๬ᄓሞఊ։ఉ໦๬ᄓऐฉ৊ႜǈࣄ࢓ኍॖ኱০ྺ400̂mǈ݆ၠፕᆩ૰1Nǈࣂۯ໏܈0.2mm/săࣄ࢓ဣຕ̂ᆯူ๕ऺ໙ǖǄ3ǅ๕ዐǈFfĊĊࣄ࢓ፆ૰ǈNǗFNĊĊ݆ၠፕᆩ૰ǈNă1.8ఊ։ఉ໦Ⴀీ֪๬๬ᄣڦఊ։ఉ໦Ⴀీ֪๬ሞఊ։ఉ໦๬ᄓऐฉ৊ႜă჋ൽ኱০ྺ4mmڦSi3N4༩ٍ൰ፕྺܔఊ֌ଙǈ֑ᆩྫްࣂۯఊ։๬ᄓఇ๕ă๬ᄓཉॲྺǖ๪࿒ǈ25%ၭ౥ეൣාࣂǈ݆ၠेሜ૰ྺ19.8Nǈࣂۯ໏܈10mm/sǈࣂۯਐ૗10mmǈ๬ᄓ้क़2hǈཞ้ऻ୤ఊ։ဣຕǈժᆩMicroXAM՗௬ෙྼႚஸᅏ֪ଉఉ໦༹ओǈᆩ෢௮ۉጱ၂ྲ৥࠵ִఉ໦՗௬ႚஸă2঳ࡕᇑ༪ஃ2.1ޖቷ঍૴ܔUHMWPE঳ৗ܈ࢅᆘ܈ڦᆖၚ՗1ଚ؜କޖቷ঍૴മࢫUHMWPEڦ঳ৗ܈ࢅᆘ܈ڦՎࣅăٗ՗1ዐ੗ᅜੂ؜ǈޖቷ঍૴ࢫUHMWPEڦ঳ৗ܈ࢅᆘ܈ۼᆶ໯ሺेǈݴ՚༵ߛକ13.03%ࢅ3.92%ăኄ๟ᅺྺǖޖቷ঍૴ڞዂUHMWPEݴጱ૾܏ଛǈܸٗ๑ڥኄၵႎႚׯڦݴጱ૾ీࠕ߸ࡀሶںዘႎಇଚǈႚׯৗ༹Ǘ঳ৗ܈ڦሺे՗௽ݴጱ૾ڦಇଚ߸ᆶႾ৆ٙǈᆘ܈ᄺࣷໜኮ༵ߛă՗1ޖቷ঍૴മࢫUHMWPEڦ঳ৗ܈ࢅᆘ܈5BC$SZTUBMMJOJUZBOEIBSEOFTTPGJSSBEJBUFEBOEVOJSSBEJBUFE6).81&6).81&ፆంऎᆵऎ /噝NNᣢཱ̓ᐎґddᣢཱ̓ᐎՐdd78ޖቷ঍૴גߛݴጱଉ਋ᅚဗڦิ࿿ఊ։ბႠీჺ৯2.2ޖቷ঍૴ܔUHMWPE२ൎႠీڦᆖၚ՗2ߴ؜କޖቷ঍૴മࢫUHMWPEڦ؋უ२ൎႠీຕ਍ăٗ՗2ዐ੗ᅜੂ؜ǈޖቷ঍૴ࢫǈUHMWPEڦ؛๔ߑ܈Ăᆘࣅߑ܈ࢅट၌ሜࢁݴ՚༵ߛକ13.7%Ă12.1%ࢅ11.8%ǈڍट၌࿋ᅎইگକ22.7%ăኄ๟ᅺྺǖUHMWPEڦڑႠ༬Ⴀ๴ৗ၎ႚༀڦᆖၚǈܸ໒Ⴀ༬Ⴀ๴ݥৗ၎ႚༀڦᆖၚăޖቷ঍૴ᆅഐ঳ৗ܈ڦ༵ߛǈܸٗ؛๔ߑ܈ࢅᆘࣅߑ܈ᄺໜኮ༵ߛǗ඗ܸǈޖቷ঍૴ࣷইگUHMWPEڦჽቛႠǈᅺܸഄट၌࿋ᅎᄺ၎ᆌইگă՗2ޖቷ঍૴മࢫUHMWPEڦ؋უ२ൎႠీ5BC1VODITIFBSJOHQSPQFSUJFTPGJSSBEJBUFEBOEVOJSSBEJBUFE6).81&6).81&ѹݼѷऎ /噝NNᆵӐѷऎ /噝NN౜ᬌᣑᕲ/౜ᬌͮሧNNᣢཱ̓ᐎґddddᣢཱ̓ᐎՐdddd2.3ޖቷ঍૴ܔUHMWPEఊ։ბႠీڦᆖၚ՗3ߴ؜କޖቷ঍૴മࢫUHMWPEڦࣄ࢓ဣຕࢅఉ໦༹ओăٗ՗3੗ᅜੂ؜ǈޖቷ঍૴ࢫǈUHMWPEڦੇࣄ࢓ፆ૰௽၂༵ߛăኄ๟ᅺྺǖޖቷ঍૴༵ߛକUHMWPEڦ঳ৗ܈ࢅᆘ܈ǈሺٷକUHMWPEڦئ٪ఇଉǈᅺܸഄੇࣄ࢓ీ૰ᄺڥᅜ༵ߛă՗3ޖቷ঍૴മࢫUHMWPEڦࣄ࢓ဣຕࢅఉ໦༹ओ5BC4DSBUDIDPFGGJDJFOUTBOEXFBSWPMVNFPGJSSBEJBUFEBOEVOJSSBEJBUFE6).81&6).81&Ѳ჈ጆஜᇛ૮ͳሤNNᣢཱ̓ᐎґddᣢཱ̓ᐎՐdd཮2၂๖କUHMWPEᄣ೗ఉ໦՗௬ڦෙྼႚஸǈᅈ਍ُ཮૧ᆩMicroXAM෉ॲऺ໙؜ఉ໦༹ओăޖቷ঍૴༵ߛକUHMWPEڦఱఉႠీăሞ25%ၭ౥ეൣාࣂཉॲူǈޖቷ঍૴ࢫUHMWPEڦఉ໦༹ओইگକ34%ă཮3ߴ؜କޖቷ঍૴മࢫUHMWPEᄣ೗ఉ໦՗௬ڦSEMႚஸ཮ă࿄ޖቷڦUHMWPEᄣ೗՗௬၂ڥ࢔փೝኝǈᆶႹܠࠏ֣ࢅྲଛ࿖ǈ੗९ೃહ࢓गǗሞఊ։ࡗײዐ๴ڟთ࣍ᆌ૰ፕᆩǈํाথة൶݀ิᅃۨײ܈ڦ໒ႠՎႚǈໜጣ৊ᅃօڦఉ໦ǈUHMWPE՗֫ႚׯ၂ྲଛ࿖ǈժሞথة՗௬ူકቛǈፌዕԊ૗ྃ஌ႚׯఉႈăޖቷ๑UHMWPEݴጱ૾क़ׂิ঍૴ǈፆҹକ္ྼଛ࿖ڦׂิࢅકቛǗཞ้ᆯᇀᆘ܈ڦሺेǈఉ໦՗௬߸ೝኝă཮2UHMWPEᄣ೗ఉ໦՗௬ڦෙྼႚஸ'JH%NPSQIPMPHZPGUIFXPSOTVSGBDFPG6).81&TBNQMF὇BὈలᣢཱ̓ᐎ὇CὈᣢཱ̓ᐎՐ཮3ޖቷ঍૴മࢫUHMWPEᄣ೗ఉ໦՗௬ڦSEMቷೌ'JH4&.QIPUPTPGUIFXPSOTVSGBDFTPGJSSBEJBUFEBOEVOJSSBEJBUFE6).81&TBNQMFT3঳ஃǄ1ǅDSC֪๬঳ࡕ՗௽ǈޖቷ঍૴༵ߛକUHMWPEڦ঳ৗ܈ăǄ2ǅᆘ܈ࢅ؋უ२ൎ֪๬঳ࡕ၂๖ǈޖቷ঍૴ሺेକUHMWPEڦᆘ܈ࢅڑႠႠీǈڍইگକUHMWPEڦ໒ႠႠీăǄ3ǅఊ։ఉ໦঳ࡕ՗௽ǈޖቷ঍૴༵ߛକUHMWPEڦੇࣄ࢓ీ૰ࢅఊ։ఉ໦༬ႠăԟᏥ஠࿸Ὑ-J4#VSTUFJO)6MUSBIJHINPMFDVMBSXFJHIUQPMZFUIZMFOFUIFNBUFSJBMBOEJUTVTFJOUPUBMKPJOUJNQMBOUT++#POF+PJOU4VSHN .D,FMMPQ)$BNQCFMM11BSL4)FUBM5IFPSJHJOPGTVCNJDSPOQPMZFUIZMFOFXFBSEFCSJTJOIJQUPUBMIJQBSUISPQMBTUZ+$MJO0SUIPQ+BTUZ.#SBHEPO$#VSLF%FUBM*OWJWPTLFMFUBMSFTQPOTFTUPQPSPV