高分子材料的纳米技术改性与应用

:100523360(2004)0520034205(,421101):,:;;:TQ0501425:B::1986,:2003211218,,P,,[1]11.1[2],;;,,,,(1),(1),1,nm10421,%204080991,,,,,,(2),,900,100(30%50%),,,,(3),,,43PLASTICSSCI1&TECHNOLOGY5(Sum1163)October2004©1994-2008ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[2]:,(,),;,,,,(TEM),,,()XX(WAXS)X(SAXS)WAXS,,;X,SAXSP,()X(XPS)(AES)(ILS),X,P;DSC,:(STMAFM),(AFM),,,AFM,,,(PAT),;Rutherford(RBS),,XPS5nm3,,3.1,,53©1994-2008ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[3]3.1.1,,,,,,,;,,;,,,,,,,,,,,,PP,PP,,,,PP,,PP1991PPPEPR()P,PP,,,1991,,EPRPP,PP,PP15nm,,PP22PPPPPPPP,gP10min189,MPa15001000,JPm510500,10-5P6157,RH6535,PP,PP713,,,,,,,WTO,,,PPPP,,PP3.1.2,200nm400nm,280nm400nm,SiO2TiO2,PP0.3%UVTiTANP580TiO2700h,10%3.1.3,ZnO;,P,,,63©1994-2008ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(SiO2),SiO2,,,SiO2499nm70%80%,,,,3[4]3,MPa1011714,%661450,kNPm42152415,165h,700h800h10503.3,,,UVTiTANP580TiO2,,,,ZnOSiO2,,;ZnO,,,,,,,,,,3.4,,,,,:;;;;;,,,,,,,,,,,,,,,,,73©1994-2008ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[5],ZnOCaCO34,,,,,,,,:1,1[M]1:,2002,3121[J]1,43(3)163168131[J]1,2000,12(5):3841141[J]1,2002,29(2)3715,1[J]12002,(1)34371PolymerMaterialModifiedbyNano2technologyandItsApplicationJIANGMei2li(DepartmentofChemistry,HengyangBranchtoHunanUniversity,Hengyang421101,China)Abstract:Itintroducedthemodifyingmechanismsandcharacterizationofnano2particlesmodifiedpolymermaterial,aswellastheapplicationofmodificationofnano2particlestoplastics,rubber,chemicalfibreandcoating.Keywords:Nanometer;Polymermaterial;Modification20045,,,,,,,,3(1),798():55,:100053:,:0982817310001;::01028315408183©1994-2008ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.