高级氧化法污水处理技术综述宋怡明

242019－09－23“”TP20190008201911276041Y1999—。211167、。、、、Fenton。。X703A1008－021X201924－0211－03SummaryofadvancedoxidationwastewatertreatmenttechnologySongYimingXuShaoweiSongHaoQianFannaZhuYiwenSchoolofenvironmentalengineeringNanjingInstituteofEngineeringNanjing211167ChinaAbstractAdvancedoxidationprocesshasbeenwidelyusedinwastewatertreatmentduetoitsadvantagesofrapidreactionandgoodtreatmenteffect．ThisarticleintroducesseveralcommonmethodssuchasphotocatalyticoxidationcatalyticwetoxidationozoneoxidationelectrochemicaloxidationandFentonoxidationandsummarizestheiradvantagesanddisadvantages．OnthisbasisthisarticledescribestheapplicationandProspectofadvancedoxidationmethod．KeywordsAdvancedoxidationprocessPhotocatalyticoxidationOzoneoxidationSewagetreatmenttechnology1。。。。。2AdvancedOxidationProcessAOPs·OH。、106～1010L/mol·s。、、、Fenton。2．1、。TiO2。1N80%。2/TiO2pH=3．5±0．5180min40mg/L92．0%。3X－3B5GNCOD90%。4FentonX－ＲBUVBFenton60min。5Fenton。H2O21.5mmol/L30minTiO25g/LCOD46．7%、69．2%。。2．2CWAO、CO2、N2H2O6。、37。、。8K2S2O8/FA150℃0．5MPa240minFA77．8%COD。。·112·DOI:10.19319/j.cnki.issn.1008-021x.2019.24.101、、9。Fe、Cu、Mn。Pt、Pd。J．Atwater105%Ｒu15%Pt。60℃。11Mn/Ce、、pH120minCOD93．1%。2．3·OH。、12。。13。A．Ozlem14－194Fe2+8min98．3%47．32%。、。15、、、MnO2＆MgO/15min30COD20min50mg/L。。16SBA－15Fe2O3/SBA－1560min99．4%COD79．5%。2．4。17。。13h1m3/h15m3/h420A。COD3100mg/L1311．3mg/L57．7%。。、pH。。19、B、TOC。Tsantaki20BDD25g/LpH=18mA/cm2180minTOC85%。2．5FentonFentonFe2+H2O2。FentonFenton21。Fenton、。22。pH4ρH2O2∶COD4∶1、nH2O2∶nFe2+1∶120minCOD83．75%．FentonFenton、Fenton。23ACFFenton360minTOCCOD78．9%62．8%。Trabelsi－Souissi24UV/Fe3+/H2O2H2O2/Fe3+=40∶1Fe3+0.1mmol/L120minTOC98．7%。3、1、。2、。3。。1．J．201541328－32．2．/TiO2－D．2016．3．J．2003291052－54．4．UV/FentonX－BＲJ．201544122766－2768．5．CODCrJ．2017451262－64．6García－MolinaVKallasJEsplugasS．Wetoxidationof4－chlorophenolKineticstudyJ．ChemicalEngineeringJournal2007126159－65．7LiLChenPGlkoynaEF．Generalizedkineticmodelforwetoxidationoforganiccompounds．AlcheJournal199137111676－1681．8．D．2012．9．J．2016431288－89．10AtwaterJEAkseJＲMckinnisJAeta1．LowtemperatureaqueousphasecatalyticoxidationofphenolJ．Chemosphere1997341203－212．11．MnOx－CeO2J．20095965－970．12．J．2018461714－16．13．J．201746122455－2458．14YildirimAGülSerminErenOrkideetal．AComparative·212·SHANDONGCHEMICALINDUSTＲY20194824StudyofOzonationHomogeneousCatalyticOzonationandPhotocatalyticOzonationforC．I．ＲeactiveＲed194AzoDyeDegradationJ．Clean－SoilAirWater20118795－805．15．D．．2016．16．Fe2O3/SBA－15J．2019．17．J．20112841－5．18．J．2015931308－1312．19．GACD．2019．20TsantakiEVelegrakiTKatsaounisAetal．Anodicoxidationoftextiledyehouseeffluentsonboron－dopeddiamondelectrodeJ．JournalofHazardousMaterials2012207/2081291－96．21．J．2016341136－37．22．J．201645132－134．23．．J．20093111－16．24Trabelsi－SouissiSOturanNBellakhalNetal．Applicationofthephoto－FentonprocesstothemineralizationofphthalicanhydrideinaqueousmediumJ．DesalinationandWaterTreatment2011251－3210－215．．J．20194824211－213．檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴檴2062．2“”。、、、、、。、、、。。。、、、、。。、、、。、。。、“”、“”、“”、。、。2．3“”“”。、、、、80%、、2。2．4。《》、、、、。、、、。。。3。。“”“”3。1．“”J．20198145－146．2．－J．2017195135－137．3．J．201917163－165．．“”－J．20194824206213．·312·