高级氧化工艺预处理制药废水的研究进展

ANHUICHEMICALINDUSTRY36420108Vol．36No．4Aug.2010、“”CODCrBOD5BOD5/CODCrNH3-NSS。、。、。。、、、。、。Fenton、Fenton、O3/H2O2、UV/O3、、、。1UV/O3UV/O3。UV/O3UV/O3·OH。[1]COD54800mg/LBOD5156mg/LpH8.9BOD5/CODCr0.0028UV/O3BOD5/CODCr0.32。[2]、pHCOD。5LpH9.033.6mg/min180minCOD385mg/L104mg/L73%。Claus[3]UV/O3254nm。COD。UV/O3。。723001HO-。。X703.1A1008-553X201004-0013-042010-05-12SLGQD07051988-、[e-mail]。1316620104362Fenton1894H.J.H.FentonH2O2Fe2+。Fenton。FentonCO2H2O。H2O2Fenton-Fenton、UV/TiO2+Fenton。M.Ravina[4]400WPhoto-FentonTOC100%。、[5]-Fenton48min-FentonCOD44.1%BOD5/CODCr0.99。。WallingKato[6]S.H.LinLo[7]FentonFe2+、Fe3+。-FentonH2O2Fe2+Fenton。Fe2+H2O2Fenton·OH。AliOzcan[8]Pt-FentonFe2+、、UV。FentonCO2H2O。Fenton。3O3/H2O2O3/H2O2OH·、。ArslanAlatonI[9]O3/H2O2COD830mg/LO3COD30%O3/H2O220mmolH2O2COD83%。O340mg/L/minBOD5/CODCr0.45。[10]O3/H2O2、、pH10.720minH2O23.9mmol/LO34.2mmol/LOUR00.578mg/g·min。O3/H2O2。4SCWOSCWOModell2080。[11]。SCWO。LixongLi[12]SCWODNT450℃1minDNT99%。SCWOSCWO。SCWO。SCWO。SCWO。5。·H、·OH、·OH2O2。·OH[13]。。、、、、。、、、、、、、、TNT14。NH3-N47%CODNH3-N60%[14]。EmeryRJ[15]TPPOCOD54%1mLFe2+COD60%。[16]+、COD13%~16%COD70%COD96%COD200~300mg/L。COD。。。、。/H2O2TOC。。6。TiO2TiO2-。TiO2CO2、H2O、PO43-、SO42-、NO3-、[17]。TOC、、、。[18]COD861mg/LBOD5/CODCr0.17150minCOD124mg/LBOD5/CODCr0.53。COD85.6%。Tusnelda[19]carbama-zepine、clofibricacid、iomeproliopromide。COD。。TiO2。。7CODBOD5/CODCr。。、、。。[1].[J].200810:143-147.[2].[J].2007244:291-294.[3]HClausSGerhardSOliveretal.OxidativedegradationofAOXandCODbydifferentadvancedoxidationprocess[J].WaterScienceTechnology1997354:257-264.[4]M.RavinaL.CampanellaJ.Kiwi.AcceleratedMineralizationoftheDrugDiclofenacViaFentonReactionsinaConcentricPhoto-reactor.WaterRes.20023614:3553-3560.[5]/Fenton[J].2007156:19-23.[6]C.WallingS.Kato.TheOxidationofalcoholsbyFenton’sReagent:theEffectofCopperion.J.Am.ChemSoc197193:4276-4280.[7]S.H.LinC.C.Lo.FentonProcessforTreatmentofDesizingWastewater.Wat.Res.19973182050-2056.[8]AliOezcanYuecelSahin.Degradationofpiclorambytheelec-tro-Fentonprocess[J].JournalofHazardousMaterials20081531/2:718-727.[9]ArslanAlatonIDogruelSBaykalEetal.Combinedchemicalandbiologicaloxidationofpenicillinformulationeffluent[J].JournalofEnvironmentalManagement200473:155-163.151662010436CurrentSituationandProspectofPretreatingPharmaceuticsWastewaterwithAdvancedOxidationProcessesYANGNa-naDUMin-juanSHUWen-boLIChenCollegeofChemistryandEnvironmentalScienceShanxiUniversityofTechnologyHanzhong723001ChinaAbstract：Advancedoxidationprocessesisaeffectiveandrapidpretreatmentmethodofpharmaceuticswastewater.Itacceleratethedecompositionreactionoforganicpollutantswithhigh-concentrationHO-thatproducedintheprocess.Thepapersystematicallyintroducethetechnologicalprincipleandthepretreatingusinginpharmaceuticswastewater.Characteristicsandadvantagesoftheseprocesswasanalyzed.Andprospectonthepretreatingpharmaceuticswastewaterwithoxidationcombinationprocess.Keywords：advancedoxidationprocessespharmaceuticalwastewaterpretreatment[10].O3/H2O2[J].20082510:21-24.[11].[J].2001226:32-34.[12]LixiongLiEarnestGloynaJohnESawick.TreatabilityofDNTprocesswastewaterbysuperciriticalwateroxidation[J].WaterEnvironRes19933:250-257.[13].[J].2003224:13-16.[14].[J].2007272:36-39.[15]EmeryRJPapadakiMLuisaM.FDSetal.Extentofsonochemicaldegradationandchangeoftoxicityofapharmaceuticalprecursortriphenylphosphineoxideinwaterasaunctionoftreatmentconditions[J].Environmentinternationa2005131:207-211.[16].-[J].2005311:65-67.[17].[J].200833146-50.[18].[J].2003191:5-8.[19]EDTusneldaHFFritz.Kinetic.StudyofphotocatalyticdegradationofcarbamazepineclofibricacidiomeprolandiopromideassistedbydifferentTiO2materials-determinationofintermediatesandreactionpathways[J].WaterRes2004385:955-964.□、、、、《》、《》、《》、《》、《》、《》、《》、《》、《》、《》2010820－21“2010”。、。1、“”“”“”。。2、“2010”。3、。《》2010720!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!16