高级氧化技术处理制药废水研究进展陈举恩

　贵州化工GuizhouChemicalIndustry2008年2月第33卷第1期高级氧化技术处理制药废水研究进展＊陈举恩1,李沪萍1,罗康碧1,宁　平2,李　兵1(1.,,650224;2.,,650224)　　　　,,,。　　　　X52　　　　　A　　　1008-9411(2008)01-0046-05　　。,。,,,。,,。,,,,。,。1　处理制药废水的高级氧化技术,·OH,。·OH,。,·OH:1.1　FentonFenton。pH,Fe2+,·OH,。MartinezNSS[1]Fenton。COD36200mg/L,BOD5/COD=0.08,H2O23mg/L,Fe2+0.3mg/L。,COD,COD56.4%,90%10min,,,Fenton。Fenton。[2]++Fenton+,BOD5/COD0.38～0.42,,“+”,COD16800～24300mg/L1000mg/L,BOD5100mg/L,COD94%,BOD5/COD0.1,;Fenton+,COD73%,COD、BOD5267mg/L,30mg/L。Fenton,。FentonFenton。[3]“Fenton+”,FentonCOD87%,COD,BOD5132mg/L,52mg/L。3.0～3.5/t,,。Fenton?。Fenton,Fe2+,·OHFe(Ⅱ),·OH,Luc-king[4]。Fe(Ⅲ)、Mn(Ⅱ)、、,H2O2·OH,Fe(Ⅲ)Fe(Ⅱ),·OH。H2O2,Fe(Ⅲ)Fe(Ⅱ)3[5],,,。·46·＊,5206790　2008年2月第33卷第1期陈举恩等:高级氧化技术处理制药废水研究进展1.2　,TiO2,TiO2,-。,,。,·OH。[6]。:,COD86lmg/L,BOD5/COD0.17;150min,COD124mg/L,BOD5/COD0.53。,,COD85.6%,。,,。,,。[7]+A/O++、、SDM、SASP,COD14000mg/L,BOD55500mg/L。A/O,BOD5/COD(0.05),BOD5/COD。,BOD5/COD,COD,。,,,。TiO2、、、,。TiO2[8]。,,。1.3　。,·H,·OH,·OH2O2。,,·OH。EmeryRJ[9]TPPO,COD54%,1mg/LFe2+,COD60%,Fe2+,COD。,TPPO,·OH·OH。[10～12],,,,。[13]+,。:COD13%～16%,,,COD70%,COD96%,COD200～300mg/L。,COD。、,,,、、。·OH,,,。1.4　O3工艺及其联用技术O3[14～17],O3,。AndreozziR[18]O3。pH=5.5,90%4O3,20,TOC18.2%。O3,O3,O3。,O3,O3,。·OH,,O3,H2O2/O3UV/O3。UV,H2O2O3·OH,O3H2O2UV,H2O2/O3O3/UV。ArslanAlatonI[19]O3+H2O2,,COD830mg/L;O3,COD30%;O3+H2O2(20mmolH2O2),COD83%。O3(40mg/L)/min,BOD5/COD0.45。·47·　贵州化工GuizhouChemicalIndustry2008年2月第33卷第1期O3,COD81%,100mg/L。O3,·OH,HO2·,H2O2[20～22],。O3,CODpH,pH,pH10.5,COD,,O3;,OH-O3·OH,[23]。pH=7,O3+H2O2G,[24]。2　讨论,,,,。,,。:,,。,(),,。:[25][26]、、[27]、。(、[28～30]、、[31]),,、、。[32～34],,,,。,,,。+,,COD10%～20%;,,,COD1000mg/L～4000mg/L[35]。+++,,。,,。,HRT,。,,Fenton[1]、[6]、[9]、[14][15]、[36],[37][38],。,COD。,。COD[1],,,[39];,[40];A[41];EmeryRJTPPO(100mg/L,250W,50mL),150min,[11]。,,。。,,,、,,[42]。,,[43]。3　结论与展望,:Fenton、、O3。、、、、、。,,,。,、·48·　2008年2月第33卷第1期陈举恩等:高级氧化技术处理制药废水研究进展,;,;,。,,。[1]　MartinezNSS,FernandezJF,SeguraXF,etal.Pre-oxidationofanextremelypollutedindustrialwastewaterbytheFenton'sreagent[J].JournalofHazardousMaterials,B101(2003):315～322[2]　,,.[J].,2005,30(7):55～57[3]　.[J].,2005,36(3):49～51[4]　Lucking.Ironpowder,graphiteandactivatedcarbonascatalystsfortheoxidationof4-chlorphenolwithhydrogenperoxideinaqueoussolution[J].Wat.Res,1998,32(9):2607～2614[5]　Arslan-AlatonI,DogruelS.Pre-treatmentofpenicillinformulationeffluentbyadvancedoxidationprocesses[J].JournalofHazardousMaterials,B112(2004):105～113[6]　,,.[J].,2003,19(1):5～8[7]　,.-A/O--[J].,2004,30(3):47～49[8]　,.TiO2[J].,2001,17(6):26～29[9]　EmeryRJ,PapadakiM,LuisaM.FDS,etal.Extentofsonochemicaldegradationandchangeoftoxicityofapharmaceuticalprecursor(triphenylphosphineoxide)inwaterasaunctionoftreatmentconditions[J].Environ-mentinternational,31(2005):207～211[10]　,,.-[J].,2002,3(8):48～51[11]　,,.[J].,2005,19(11):3～5[12]　,,.[J].,2006,26(5):9～13[13]　,,.-[J].,2005,31(1):65～67[14]　I.AkmehmetBG,MerihO.Treatmentofpharmaceuti-calwastewatercontainingantibioticsbyO3andO3/H2O2processes[J].Chemosphere,50(2003):85～95[15]　AndreozziR,CanterinoM,MarottaR,etal.Antibioticremovalfromwastewaters:Theozonationofamoxicillin[J].JournalofHazardousMaterials,122(2005):243～250[16]　TernesTA,StuberJ,HerrmannN,etal.Ozonation:atoolforremovalofpharmaceuticals,contrastmediaandmuskfragrancesfromwastewater?[J].WaterRes,37(2003):1976～1982.[17]　ErnstM,JekelM.Advancedtreatmentcombinationforgroundwaterrechargeofmunicipalwastewaterbynanofil-trationandozonation[J].WaterSci.Technol.,40(4～5)(1999):277～284[18]　AndreozziR,CaprioV,MarottaR,etal.OzonationandH2O2/UVtreatmentofclofibricacidinwater:akineticinvestigation[J].Hazard.Mater.,103(3)(2003):233～246[19]　ArslanAlatonI,DogruelS,BaykalE,etal.Combinedchemicalandbiologicaloxidationofpenicillinformula-tioneffluent[J].JournalofEnvironmentalManagement,73(2004):155～163[20]　AkmehmetBalciogluI,ArslanI.Partialoxidationofre-activedyestuffsandasynthetictextiledye-bathbytheO3andO3/H2O2processes[J].WaterSci.Technol.,2001,43(2):221～228.[21]　BeltranFJ,Garcia-ArayaJF,AlvarezPM,etal.Aqueousdegradationofatrazineandsomeofitsmainby-productswithozonehydrogenperoxide[J].Chem.Technol.Biotechnol.,71(1998):345～355.[22]　BenitezFJ,AceroJL,Gonzalez,etal.Ozonationandbiodegradationprocessesinbatchreactorstreatingblacktableoliveswashingwastewaters[J].Ind.Eng.Chem.Res,2001,40(14):3144～3151.[23]　CokgorEU,ArslanAlatonI,KarahanO,etal.Biologi-caltreatabilityofrawandozonatedpenilillinformulationeffluent[J].JournalofHazardousMaterials,B116(2004):159～166[24]　Arslan-AlatonI,CaglayanAE.Toxicityandbiode-gradabilityassessmentofrawandozonatedprocainepen-icillinGformulationeffluent[J].EcotoxicoligyandEn-vironmentalSafety,63(2006):131～140[25]　,,.[J].(),2005,44(4):70～74[26]　ChelliapanaS,WilbybT,SallisaPJ.Performanceofanup-flowanaerobicstagereactor(UASR)inthetreat-mentofpharmaceuticalwastewatercontainingmacrolideantibiotics[J].WaterResearch,40(2006):507～516[27]　,,.[J].,2004,17(4):9～10[28]　,,.·49·　贵州化工GuizhouChemicalIndustry2008年2月第33卷第1期[J].,2004,27(3):40～42[29]　,,.[J].,2003,34(4):1～4[30]　AdachiA,HamamotoH,OkanoT.Useofleesmateri-alsasanadsorbentforremovaloforgano