高级氧化技术在废水处理中的应用

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AdvancedoxidationprocessesAOPs20801OH2.80V2.87VOH2OH3-41FentonFenton234511.1FentonFentonFenton1894FentonFentonFe2+H2O2OH[1]Fenton-FentonFe2+CODFentonFe2+FentonFentonFentonKang[2]FentonCOD160minTOC100%Fe2+H2O2[3-4]FentonFentonVerma[5]CoCuFe2+FentonKim[6]Fenton300071FentonFentonOHTQ031.7X703.1A1000-3770(2009)03-018-052008-06-121974-13011355006E-mailahongjn@126.com35320093TECHNOLOGYOFWATERTREATMENTVol.35No.3Mar.,200918BOD/COD0.10.4[7]Fenton0.0680.86FentonFe2+[8-10]FeFentonFenton1.2H2O2O3Andreozzi[11]UV/H2O2H2O2[12]UV/H2O224-UV/H2O2NO3-Cl-HCO3-24-TiO2ZnOWO3CdSZnSSnO2Fe3O41976TiO2TiO2[13]TiO2Yeber[14]TiO2ZnO120min85%TOC50%TiO2TiO2TiO2AOzkan[15]AgTiO2TiO2Feng[16]-FeTiO2FeTiO2Fe0.05%TiO2TiO21.3CODUV/O3H2O2/O3UV/H2O2/O3O3[17]O3/H2O2O3/MnHayashi[18]UV/O3O310UV/O3H2O2OHUV/O3[19-22]UV/O3[23]UV/H2O2/O3UV/H2O2/O3USFilterO3/H2O2/UVUVO3H2O2O3[24]1.4OH19Fe2+FentonMoras[25]TiO2-RuO2180minCOD73%TOC57%86%49%Zhou[26]10%13%DSAPolcaro[27]Ti/SnO2Ti/PbO22-Ti/SnO2Fockedey[28]SbSnO2Ti/SnO2-Sb2O56.3kWhkg-15kWhkg-1CODDSAPelegrini[29]Ti/Ru0.3Ti0.7O2-1960min95%34%15%1.5US16kHz1MHzOHH2O2123CO2H2ODavid[30]0.1mmolL-13-480kHz50min60minCl-COCO2Petrier[31]30W500kHz0.5mmolL-14-150minCO2COC2H2O3UVH2O2USO3Ragaini[32]US/O32-2-70%US/O3O37%24%Sohmiya[33]US/UV44-US44-IBrClFUSOH1.6[34]99.6%COD96.8%3532037422.1MPaHatakeda[35]H2O23-99.999%21OH2OH3[1],.Fenton-[J].,2004,24(4):39-41.[2]KangSF,LiaoCH,ChenMC.Pre-oxidationandcoagulationoftexitilewastewaterbytheFentonprocess[J].Chemosphere,2002,46(6):923-928.[3]ModirshahlaN,BehajadyMA,GhanbaryF.DecolorizationandmineralizationofCIacidyellow23byFentonandphoto-Fentonprocesses[J].DyesandPigments,2007,7(1):305-310.[4]ChenF,XieYD,ZhaoJC,etal.Photo-FentondegradationofdyeinmethanoliesolutionunderbothUVandvisibleirradiation[J].JPhotochemPhotobiolA:Chem,2002,138(2):139-146.[5]PVerma,PBaldrian,FNerud.Decolorizationofstructurallydifferentdyesusingcobalt()/ascorbicacid/peroxidesystem[J].Chemosphere,2003,50(6):975-979.[6]YKKim,IRHuh.Enhancingbiologicaltreatabilityoflandfillleachatebychemicaloxidation[J].EnvironmentalEngineeringScience,1997,14(1):73-79.[7],.[J].,1997,19(6):33-36.[8]ChenJX,ZhuLZH.CatalyticdegradationoforangeIIbyUV-Fentonwithhydroxyl-Fe-pillaredBentoniteinwater[J].Chemosphere,2006,65(7):1249-1255.[9]FengJY,HuXJ,YuePL.Novelbentoniteclay-basedFe-nanocompositeasaheterogeneouscatalystforphoto-fentondiscolorationandmineralizationoforangeII[J].EnvironmentalScience&Technology,2004,38(1):269-275.[10]FengJY,HuXJ,YuePL.DiscolorationandmineralizationoforangeIIbyusingabentoniteclay-basedFenanocompositefilmasaheterogeneousphoto-Fentoncatalyst[J].WaterResearch,2005,39(1):89-96.[11]RAndreozzi,VCaprio,AInsola,etal.Advancedoxidationprocessesforthetreatmentofmineraloil-contaminatedwastewaters[J].WaterResearch,2000,34(2):620-628.[12],,,.UV/H2O22,4-[J].,2007,29(7):487-490.[13],,,.[J].,2004,13(1):99-104.[14]MCYeber,JaimeRodrguez,JuanitaFreer,etal.PhotocatalyticdegradationofcellulosebleachingeffluentbysupportedTiO2andZnO[J].Chemosphere,2000,41(8):1193-1197.[15]AOzkan,MH,RGrkan,etal.Photocatalyticdegradationofatextileazodye,SiriusGelbGConTiO2orAg-TiO2particlesintheabsenceandpresenceofUVirradiation:theeffectsofsomeinorganicanionsonthephotocatalysis[J].JournalofPhotochemistryandPhotobiologyA:Chemistry,2004,163(1-2):29-35.[16]FengJ,WongRSK,HuX,etal.DiscolorationandmineralizationoforangebyusingFe3+-dopedTiO2andbentoniteclay-basedFenanocatalysts[J].CatalyToday,2004,98(3):441-446.[17],.O3/H2O2O3/Mn[J].,2004,25(1):72-77.[18]Jun-ichiroHayashi,JojiIkeda,KatsukiKusakabe,etal.Decompo-sitionofvolatileorganochlorinesbyozoneandultilizationeffi-ciencyofozonewithultravioletinabubble-column[J]WaterResearch,1993,27(6):1091-1097.[19]ShuHY,HuangChR.DegradationofcommercialazodyesinwaterusingozonationandUVenhancedozonationprocess[J].Chemosphere,1995,31(8):3813-3825.[20]GOhlenbusch,SHesse,FHFrimmel.Effectsofozonetreatmentonthesoilorganicmatteroncontaminatedsites[J].Chemosphere,1998,37(8):1557-1569.[21]NigelGraham,WeiChu,CatherineLau.Observationsof2,4,6-triehlorophenoldegradationbyozone[J].Chemosphere,2003,51(4):237-243.[22]BOhmeA.OzoneTechnologyofgermanindustrialenterprises[J].OzoneScienceandEngineering,1999(21):3208-3222.21[16],,,.TiO2[J].,2008,26(1):129-133.[17],,.TiO2/[J].,2006,15(6):54-57.[18]LeiShaomin,GongWenqi,BaiChunhua.PreparationofTiO2/kaolinitenanocompositeanditsphotocatalyticalactivity[J].JournalofWuhanUniversityofTechnology-MaterSciEd.,2006,21(4):12-15.[19],,.TiO2[J].,2006,363(9):42-45.[20],.TiO2[J].,2006,4:615.[21],,.TiO2[J].,2006,34(10):1208-1212.[22],,.TiO2[J].,2007,25(6):91-93.[23],,,.TiO2[J].,2006,34(8):932-935.[24],,./[J].,2006,29(5):18-20.PROGRESSOFORGANICWASTEWATERPHOTO-DEGRADATIONWITHPOROUSMINERAL/NANOMETERTITANIUMDIOXIDECOMPOSITEMATERIALLIYan,WANGCheng,YUKai-ning,LIJing-jing,ZHANGPu,LIUZhi-feng(ShijiazhuangUniversityofEconomics,Shijiazhuang050031,China)Abstract:Theimmobilizationofnanometertitaniumdioxideandtheenrichmentoftheorganiccontaminationontothesurfaceoftheporousmineralcometruebytheresearchofporousmineralloadingnanometerti

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