高级氧化技术在废水处理中的应用张旋caj20190322163555834

。AdvancedoxidationprocessesAOPs2080。1·OH2.80V2.87V·OH2·OH、3-4。1FentonFenton2345。11.1FentonFentonFenton1894FentonFentonFe2+H2O2·OH。[1]Fenton-、。FentonFe2+COD。、FentonFe2+FentonFentonFenton。Kang[2]FentonCOD160minTOC100%Fe2+H2O2。[3-4]FentonFenton。Verma[5]CoCuFe2+。Fenton。、。Kim[6]Fenton300071FentonFenton、、、、。。·OHTQ031.7X703.1A1000-3770(2009)[e-mail]。35320093TECHNOLOGYOFWATERTREATMENTVol.35No.3Mar.,200918BOD/COD0.10.4。[7]Fenton0.0680.86。FentonFe2+。[8-10]FeFentonFenton。1.2H2O2、O3。Andreozzi[11]UV/H2O2H2O2。[12]UV/H2O224-UV/H2O2NO3-、Cl-、HCO3-24-。。TiO2、ZnO、WO3、CdS、ZnS、SnO2Fe3O4。1976TiO2TiO2[13]。TiO2、。Yeber[14]TiO2ZnO120min85%TOC50%。TiO2TiO2TiO2。A··Ozkan[15]AgTiO2TiO2。Feng[16]-FeTiO2FeTiO2Fe0.05%TiO2。TiO2。。。1.3、、、COD。、。UV/O3、H2O2/O3、UV/H2O2/O3O3。[17]O3/H2O2O3/Mn。Hayashi[18]UV/O3O310UV/O3H2O2·OH。UV/O3、、、[19-22]UV/O3[23]。UV/H2O2/O3。UV/H2O2/O3USFilterO3/H2O2/UVUV、O3、H2O2O3[24]。、。1.4·OH。19、。。Fe2+Fenton。。Moras[25]TiO2-RuO2180minCOD73%TOC57%86%49%。Zhou[26]10%～13%。。、。DSA、、、。Polcaro[27]Ti/SnO2Ti/PbO22-Ti/SnO2。Fockedey[28]SbSnO2Ti/SnO2-Sb2O56.3kWh·kg-15kWh·kg-1COD。DSA。Pelegrini[29]Ti/Ru0.3Ti0.7O2-1960min95%34%15%。1.5US16kHz1MHz。·OHH2O2。123。CO2、H2O、、、。David[30]0.1mmol·L-13-480kHz50min60minCl-、COCO2。Petrier[31]30W500kHz0.5mmol·L-14-150minCO2、COC2H2。O3、UV、H2O2、。USO3Ragaini[32]US/O32-2-70%US/O3O37%24%。Sohmiya[33]US/UV44′-US44′-IBrClF。US·OH。1.6“”。[34]99.6%、COD96.8%。。35320374℃、22.1MPa。。Hatakeda[35]H2O23-99.999%。、。2、。、。。1·OH2·OH3。[1],.Fenton-[J].,2004,24(4):39-41.[2]KangSF,LiaoCH,ChenMC.Pre-oxidationandcoagulationoftexitilewastewaterbytheFentonprocess[J].Chemosphere,2002,46(6):923-928.[3]ModirshahlaN,BehajadyMA,GhanbaryF.DecolorizationandmineralizationofCIacidyellow23byFentonandphoto-Fentonprocesses[J].DyesandPigments,2007,7(1):305-310.[4]ChenF,XieYD,ZhaoJC,etal.Photo-FentondegradationofdyeinmethanoliesolutionunderbothUVandvisibleirradiation[J].JPhotochemPhotobiolA:Chem,2002,138(2):139-146.[5]PVerma,PBaldrian,FNerud.Decolorizationofstructurallydifferentdyesusingcobalt()/ascorbicacid/peroxidesystem[J].Chemosphere,2003,50(6):975-979.[6]YKKim,IRHuh.Enhancingbiologicaltreatabilityoflandfillleachatebychemicaloxidation[J].EnvironmentalEngineeringScience,1997,14(1):73-79.[7],.[J].,1997,19(6):33-36.[8]ChenJX,ZhuLZH.CatalyticdegradationoforangeIIbyUV-Fentonwithhydroxyl-Fe-pillaredBentoniteinwater[J].Chemosphere,2006,65(7):1249-1255.[9]FengJY,HuXJ,YuePL.Novelbentoniteclay-basedFe-nanocompositeasaheterogeneouscatalystforphoto-fentondiscolorationandmineralizationoforangeII[J].EnvironmentalScience&Technology,2004,38(1):269-275.[10]FengJY,HuXJ,YuePL.DiscolorationandmineralizationoforangeIIbyusingabentoniteclay-basedFenanocompositefilmasaheterogeneousphoto-Fentoncatalyst[J].WaterResearch,2005,39(1):89-96.[11]RAndreozzi,VCaprio,AInsola,etal.Advancedoxidationprocessesforthetreatmentofmineraloil-contaminatedwastewaters[J].WaterResearch,2000,34(2):620-628.[12],,,.UV/H2O22,4-[J].,2007,29(7):487-490.[13],,,.[J].,2004,13(1):99-104.[14]MCYeber,JaimeRodríguez,JuanitaFreer,etal.PhotocatalyticdegradationofcellulosebleachingeffluentbysupportedTiO2andZnO[J].Chemosphere,2000,41(8):1193-1197.[15]A··Ozkan,MH,RGürkan,etal.Photocatalyticdegradationofatextileazodye,SiriusGelbGConTiO2orAg-TiO2particlesintheabsenceandpresenceofUVirradiation:theeffectsofsomeinorganicanionsonthephotocatalysis[J].JournalofPhotochemistryandPhotobiologyA:Chemistry,2004,163(1-2):29-35.[16]FengJ,WongRSK,HuX,etal.DiscolorationandmineralizationoforangebyusingFe3+-dopedTiO2andbentoniteclay-basedFenanocatalysts[J].CatalyToday,2004,98(3):441-446.[17],.O3/H2O2O3/Mn[J].,2004,25(1):72-77.[18]Jun-ichiroHayashi,JojiIkeda,KatsukiKusakabe,etal.Decompo-sitionofvolatileorganochlorinesbyozoneandultilizationeffi-ciencyofozonewithultravioletinabubble-column[J]．WaterResearch,1993,27(6):1091-1097.[19]ShuHY,HuangChR.DegradationofcommercialazodyesinwaterusingozonationandUVenhancedozonationprocess[J].Chemosphere,1995,31(8):3813-3825.[20]GOhlenbusch,SHesse,FHFrimmel.Effectsofozonetreatmentonthesoilorganicmatteroncontaminatedsites[J].Chemosphere,1998,37(8):1557-1569.[21]NigelGraham,WeiChu,CatherineLau.Observationsof2,4,6-triehlorophenoldegradationbyozone[J].Chemosphere,2003,51(4):237-243.[22]B··OhmeA.OzoneTechnologyofgermanindustrialenterprises[J].OzoneScienceandEngineering,1999(21):3208-3222.21[16],,,.TiO2[J].,2008,26(1):129-133.[17],,.TiO2/[J].,2006,15(6):54-57.[18]LeiShaomin,GongWenqi,BaiChunhua.PreparationofTiO2/kaolinitenanocompositeanditsphotocatalyticalactivity[J].JournalofWuhanUniversityofTechnology-MaterSciEd.,2006,21(4):12-15.[19],,.TiO2[J].,2006,363(9):42-45.[20],.TiO2[J].,2006,4:615.[21],,.TiO2[J].,2006,34(10):1208-1212.[22],,.TiO2[J].,2007,25(6):91-93.[23],,,.TiO2[J].,2006,34(8):932-935.[24],,./[J].,2006,29(5):18-20.PROGRESSOFORGANICWASTEWATERPHOTO-DEGRADATIONWITHPOROUSMINERAL/NANOMETERTITANIUMDIOXIDECOMPOSITEMATERIALLIYan,WANGCheng,YUKai-ning,LIJing-jing,ZHANGPu,LIUZhi-feng(ShijiazhuangUniversityofEconomics,Shijiazhuang050031,China)Abstract:Theimmobilizat