高级氧化技术在水处理中的研究进展江传春

、、。。2080AOPs、、、·OH、、、、、。AOPs。Fenton、、、、。。11.1FentonFentonpH2～5Fe2+H2O2·OHFe3+Fenton。H2O2Fen-ton、、。[1]FentonA2OFenton。、Fenton、[2-5]FentonFentonFe2+Fenton。1FentonFenton。FentonFenton[6]。FentonpHFe2+。Fe2+、、、、、、Fe2+Fe2+pH。Daud[7]Fe3+5RB5150minRB599%。Youngmin[8]Fe(II)CSGLAFe(II)-CS/GLATCE5hTCE95%FentonTCE。Plata[9]-Fenton2-、。1.2610065、、。Fenton、、、、。X703.1TQ031.7A1000-3770(2011)[e-mail][e-mail]37720117TECHNOLOGYOFWATERTREATMENTVol.37No.7Jul.,201112DOI:10.16796/j.cnki.1000-3770.2011.07.0041FentonFentonTab.1ThecomparisonofFentonmethodandvarioustypesofFentonmethodFenton-Fenton-Fenton-FentonFe2+H2O2·OHUVFe2+H2O2H2O2Fe2+FentonFe2+H2O2、、、、、Fe2+、H2O2·OH、、FentonFe2+、H2O2、、、、·OH。TiO2、ZnO、WO3、CdS、ZnS、SnO2Fe3O4。TiO2、、、。[10]TiO2COD76.8%89%。TiO2、、。TiO2TiO2TiO2。[11]TiO2[12]TiO2/GeO2。。TiO2、TiO2、。Estrellan[13]-FeNbTiO2FeNb。Iliev[14]1%PtAgTiO2TiO22。[15]TiO2N。。Pan[16]BiPO4TiO2P252。Deshpande[17]Ce1-xFexVO4Ce0.99Fe0.01VO4TiO2。Pu[18]NaxH2-xTi3O7UVTiO2Au。1.3、、、COD。。[19]0.120.58。。UV/O3、H2O2/O3、UV/H2O2/O3、TiO2/UV/O3O3O3。[20]H2O2/O3、O3[21]O3、UV/O3、、O3。Correa[22]TiO2/UV/O3-TiO2/UV/O360min、、COD99.9%、97.2%89.2%TiO2/UV/O3-。。、、、。Devu-lapelli[23]γ-Al2O3Cu、Mo、Cr、MnCuO-MoO3/γ-Al2O3DMS100%96%CO2SO2。[24]-13-。。[25]COD。[26]O3/H2O2O3/MnOx-GACO3。1.416kHz-1MHz·OHH2O2。、、、、、。、TOC、。。/H2O2O3、-Fenton、/、/。[27]-FentonCOD91.8%Chen[28]Fentonα-Fe2O34A、、。Torres[29]/UV/Fe(II)、/Fe(II)、/UVATOC/UV/Fe(II)。[30]-TiO2。[31]/O3。Rokhina[32]/。1.5150～325℃、0.5～20MPa。[33]COD98%99%。、。Fe、Cu、Mn、Co、Ni、Bi、Pt。[34]Cu/Ni190℃、1.6MPaCOD95%BOD/COD0.0930.590。Liou[35]CuOCOD98%90%。Zhao[36]-CuO/ACH2O215minTOC90%。Hung[37]Cu-ACF3MPa、190℃95%。1.6374℃、22.1MPaH2O2。。、。2%。[38]COD99.8%。[39]COD99.6%。。MnO2、CuO、TiO2、CeO2、Al2O3、PtCr2O3/A12O3、CuO/Al2O3、37714Fenton、、、、、、、、、、、、、、、、、、、、、Fe2+pH、、、、、、、、、、、、、、、、、、、、、、、Fenton、、、、MnO2/CeO2。Angeles[40]MnO2/CuO。[41]MnOx/TiO2-Al2O3MnOxMnOx。2。2。、、、、。、。3。3、、、。。、、、、、3Tab.3Comparativeadvantagesanddisadvantagesofvarioustypesofadvancedoxidation2Tab.2Applicationofadvancedoxidationtechnology/m3·d-1COD/mg·L-1/min/%[42][43][44][44]SCWO[45]Fenton1200048020062000.9～1.1250-14000~15000587020000～350006801230-5--1.572704099.99999.9COD。、。。5COD20000mg·L-1。。15。、、。[1],,,.Fenton[J].,2010,26(3):93-95.[2],,,.[J].,2008,34(10):11-12.[3],,.Fenton[J].,2009,3(12):2159-2162.[4],,,.-Fenton[J].,2010(1):57-62.[5],,,.Fenton[J].,2009,25(17):97-99.[6],,,.Fenton-[J].,2010,4(6):363-1367.[7]DaudNK,HameedBH.Fenton-likeoxidationofreactiveblack5solutionusingiron-montmorilloniteK10catalyst[J].JournalofHazardousMaterials,2010,176(1-3):1118-1121.[8]LeeYoungmin,LeeWoojin.DegradationoftrichloroethylenebyFe(II)chelatedwithcross-linkedchitosaninamodifiedFentonreac-tion[J].JournalofHazardousMaterials,2010,178(1-3):187-193.[9]delaPlataGBO,AlfanoOM,CassanoAE.Theheterogeneouspho-to-Fentonreactionusinggoethiteascatalyst[J].WaterScienceandTechnology,2010,61(12):3109-3116.[10],,.TiO2[J].,2009,29(8):25-27.[11],,.TiO2[J].,2009,29(5):471-474.[12],.TiO2／GeO2[J].,2009,29(6):518-521.[13]EstrellanCR,SalimC,HinodeH.Photocatalyticdecompositionofperfluorooctanoicacidbyironandniobiumco-dopedtitaniumdioxide[J].JournalofHazardousMaterials,2010,179(1-3):79-83.[14]IlievV,TomovaD,BilyarskaL,etal.PhotocatalyticpropertiesofTiO2modifiedwithplatinumandsilvernanoparticlesinthedegra-dationofoxalicacidinaqueoussolution[J].AppliedCatalysisB:Environmental,2006,63(3-4):266-271.[15]SenthilnathanJ,PhilipL.PhotocatalystdegradationoflindaneunderUVandvisiblelightusingN-dopedTiO2[J].ChemicalEngineeringJournal,2010,161(1-2):83-92.[16]PanCS,ZhuYF.NewTypeofBiPO4oxy-acidsaltphotocatalystwithhighphotocatalyticactivityondegradationofdye[J].Environ-mentalScience&Technology,2010,44(14):5570-5574.[17]DeshpandePA,MadrasG.Photocatalyticdegradationofdyesovercombustion-synthesizedCe1-xFexVO4[J].ChemicalEngineeringJournal,2010,158(3):571-577.[18]PuYC,ChenYC,HsuYJ.Au-decoratedNaxH2-xTi3O7nanobeltsex-hibitingremarkablephotocatalyticpropertiesundervisible-lightil-lumination[J].AppliedCatalysisB:Environmental,2010,97(3-4):389-397.[19],,,.[J].,2009,3(7):1259-1262.[20],,,.B[J].:,2009,25(2):320-324.[21],,,.O3UV/O3[J].,2007,1(7):24-28.[22]CorreaAXR,TiepoEN,SomensiCA,etal.Useofozone-photo-catalyticoxidation(O3/UV/TiO2)andbiologicalremediationfortreatmentofproducedwaterfrompetroleumrefineries[J].JournalofEnvironmentalEngineering-Asce,2010,136(1):40-45.[23]DevulapelliVG,Sahle-DemessieE.Catalyticoxidationofdimethylsulfidewithozone:Effectsofpromoterandphysico-chemicalprop-ertiesofmetaloxidecatalysts[J].AppliedCatalysisA:General,2008,348(1):86-93.[24],,,.-[J].,2010,36(4):89-92,96.[25],,,.[J].,2009,32(11):160-162,205.[26],,,.[J].:,2009,25(4):747-752.[27].-Fenton[J].,2010(4):809-812.[28]ChenF,LiY,CaiWD,etal.Preparationandsono-Fentonperfor-manceof4A-zeolitesupportedalpha-Fe2O3[J].JournalofHazardousMaterials,2010,177(1-3):743-749.[29]TorresRA,PetrierC,CombetE,etal.BisphenolAmineralizationbyintegratedultrasound-UV-iron(II)treatment[J].EnvironmentalSci-ence&Technology,2007,41(1):297-302.[30],,,.-TiO2[J].,2010,4