高效抗污染中空纤维膜光催化反应器的构建及性能研究

B060306(2009)[e-mail]2[e-mail]0571-88320863/[e-mail]0571-88320515:20101—20121235.0000(400)TiO2-Dean(5)200931.001.570:[e-mail][e-mail][e-mail][e-mail][e-mail][e-mail][e-mail]10898323:200941.001.570.24.50001.7.80001//3.00002/1.50003/1.80004//1.500052.12.70001//8.500024.20003.4.000011.800022.20004.5..3.50001.3.50002..5.2500.1.750035.00000.0000200951.001.5704000-80001.60%50%60-80%15%[1]2080[2][2001]118TiO23.0eV[3]TiO2TiO2Bahnemann[4]200961.001.570a,[45]CO2,HCl,TeflonTiO2aTiO2photocatalyticmembranereactor,PMRTiO2SPMRbc[5,6](CongoRed)(PatentBlue)18(AcidBlue18)5(ReactiveBlack5)TOCCODNH4+-N(4NP)(TCE)E-1E-2UVPE-1UVbc200971.001.570(E.coliform)[7-9]MBRMolinariDrioli[10]TiO2TiO2Mozia[11]TiO2(CA)(PSf)(PES)(PVDF)(PSf)PPTiO2-1PMR/PMRDegussaP25TiO2PMRTiO2TiO2200981.001.5702[12]3MolinariDrioli[1314]ChinFane[1516]MBRMC-[1]CorreiaVM,StephensonT,JuddSJ.Characterizationoftextilewastewater-areview.Environ.Technol.,1994,15(10):917-929[2]SerponeN,Pelizzetti(eds.).PhotocatalysisFundamentalsandApplications,Wily,NewYork,1989[3]GogatePR,PanditAB.AreviewofimperativetechnologiesforwastewatertreatmentI:oxidationtechnologiesatambientconditions,Adv.Environ.Res.,2004,8:501-512[4]BahnemannD.TheHandbookofEnvironmentalChemistry.Vol2.EnvironmentalPhotochemistry.Springer-Verlag,Heidelberg,1999[5]CaetanoA,PinhoMD,DrioliE,MuntauH(eds.).MembraneTechnology:ApplicationstoIndustrialWastewaterTreatment,KluwerAcademicPublishers,Dordrecht,TheNetherlands,1995200991.001.570[6]LeeSA,ChooKH,LeeCH,LeeHI,HyeonT,ChoiW,KwonHH.UseofultrafiltrationmembranesfortheseparationofTiO2photocatalystsindrinkingwatertreatment,Ind.Eng.Chem.Res.,2001,40:1712-1719[7]MolinariR,CarusoA,ArgurioP,PoerioT.DegradationofthedrugsGemfibrozilandTamoxifeninpressurizedandde-pressurizedmembranephotoreactorsusingsuspendedpolycrystallineTiO2ascatalyst.J.Memb.Sci.,2008,319:54–63[8]SunDD,TayJH,TanKM.PhotocatalyticdegradationofE.coliforminwater,WaterResearch,2003,37:3452–3462[9]AzragueK,AimarP,Benoit-Marquie´F,MauretteM.Anewcombinationofamembraneandaphotocatalyticreactorforthedepollutionofturbidwater,Appl.CatalysisB:Environmental,2007,72:197-204[10]MolinariR,PirilloF,LoddoV,PalmisanoL.HeterogeneousphotocatalyticdegradationofpharmaceuticalsinwaterbyusingpolycrystallineTiO2andananofiltrationmembranereactor,CatalysisToday,2006,118:205–213[11]MoziaS,TomaszewskaM,MorawskiAW.Anewphotocatalyticmembranereactor(PMR)forremovalofazo-dyeAcidRed18fromwater,Appl.CatalysisB:Environmental,2005,59:131-137[12]TangC,ChenV.Thephotocatalyticdegradationofreactiveblack5usingTiO2/UVinanannularphotoreactor,WaterResearch,2004,38:2775–2781[13]MolinariR,MungariM,DrioliE,PaolaAD,LoddoV.Studyonaphotocatalyticmembranereactorforwaterpurification,CatalysisToday,2000,55:71–78[14]MolinariR,GrandeC,DrioliE,PalmisanoL,Schiavello.Photocatalyticmembranereactorsfordegradationoforganicpollutantsinwater,CatalysisToday,2001,67:273–279[15]ChinSS,LimTM,ChiangK,FaneAG.Hybridlow-pressuresubmergedmembranephotoreactorfortheremovalofbisphenolA,Desalination,2007,202:253-261[16]ChinSS,ChiangK,FaneAG.ThestabilityofpolymericmembranesinaTiO2photocatalysisprocess,J.Memb.Sci.,2006,275(2):202-2112.,TiO2--1TiO2a.TiO2Fe3O4TiO2b.TiO2Fe3+Cu2+c.2009101.001.5702TiO2a.b.c.3a.b.c.pH4bubblelessaerationa.b.c.5a.b.c.6a.b.1a.b.pHc.d.2a.2009111.001.570b.c.3a.b.c.Dean3.TiO2(PSf)(PES)(PAN)(PVDF)PEPPDeanTiO22009121.001.5701TiO2No.2006C23067TiO2Fe3O4TiO2SPMRFe3+Cu2+2(PSf)(PES)(PAN)(PVDF)PEPP24-30UV200mMH2O2UV-H2O2TOC(SEM)(AFM)2009131.001.5703PSPESPVDFSO3-SO3(AlCl3SnCl4ZnCl2)(CH2)3SO3--CH(CH3)CH2OHYoung-LaplaceSEMAFMdeDean4deDean52009141.001.570H2O222eOO−−+→•22OHHO−+•+→•22222HOHOHOO•+•→+222HOhvOH+→•22eHOOHOH−−+→•+MBR(bubblelessoxygenation/bubblelessaeration)100%()(90)fPDMSPPPE2009151.001.570f6SPMRB145pHTiO2NaCl,CaCl27MPRTiO2gTiO2XRD2009161.001.570TiO2TiO2gAppl.CatalysisB:EnvironmentalEdwardL.CusslerMichaelJ.SemmensSemmensCussler[1718][17]ReedBW,SemmensMJ,CusslerEL.“MembraneContactors”,inMembraneSeparationTechnology.NobleRDed.Amsterdam,Elsevier,1995[18]FangY,NovakPJ,HozalskiRM,CusslerEL,SemmensMJ.Condensationstudiesingaspermeablemembranes.J.Memb.Sci.,2004,231:47-551Degussa-P25TiO2SPMR.TiO22009171.001.57023Dean/4.20101~201012TiO220111~201112SPMRB14520121~2012122009181.001.570123Dean1-28SCI5EI31-223-51Appl.CatalysisB:EnvironmentalJournalofMembraneScience,12IndustrialEngineeringChemistryResearchCatalysisToday,13WaterResearchEnviron.Sci.&Techn.,11-2ACSAIChEEDSmeetingCusslerSemmensFane1511ACS-TiO22009191.001.570MBR863-2XXPSPLIRBET(SEM)(AFM)ICPTOC2009201.001.570319912/200751991()19991120037()15113155Asia-PacificDesalination&WaterReuseAIChEJJMembSciIndE&CResearchBiochem