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钟晓1，王启山1，何凤华2，李思思1，岳尚超1（1.，300071；2.，300457）［］，—V+。，，a31.37%57.29%；a78.91%99.34%。，，UV254、DOC。，。［］；；［］TU991.25［］A［］1005-829X（2013）04-0069-03Researchontheanalysisofhighalgae-ladenwatertreatedbyprechlorinationinwatersupplyplantsZhongXiao1，WangQishan1，HeFenghua2，LiSisi1，YueShangchao1（1.CollegeofEnvironmentalScienceandEngineering，NankaiUniversity，Tianjin300071，China；2.TianjinTedaWaterWorksCo.，Tianjin300457，China）Abstract：WaterintheLuanRiverhasbeentreated.Theeffluentfromthetreatingunits，suchasprechlorination－V-typefilter+disinfectionbychlorineinwaterworks，aredetected.Theresultsshowthataftertherawwaterhasbeentreatedbyprechlorination，theaverageremovingratesofthealgaeandchlorophyll-aare31.37%and57.29%，re-spectively.Theaverageremovingratesofthealgaeandchlorophyll-acanreach78.91%and99.34%，respectivelybythewholesetoftechnology.Besides，prechlorinationcanreducetheturbidityefficiently，buttheremovingeffectbyUV254andDOCarenotremarkable.Haloformandhaloaceticacidwillgenerateafterprechlorination，butithascer-tainremovingeffectbythesubsequentprocess.Keywords：prechlorination；highalgae；drinkingwater。，。，，，〔1-4〕。，。，，〔5〕。，〔6〕。，—V+，。11.15×104m3/d，：+++V+，，1.2mg/L，3min；，，15、20、3mg/L。1，5。11.2，；a，752N；pH，MettlerToledo320pH；，HACH2100N；254nm（UV254），752N；（DOC），TOCVCSH；（THMFP），（Agilent6890NGC）；（HAAFP），（Agilent6890NGC）。33420134IndustrialWaterTreatmentVol．33No．4Apr.，201369、（1）、（2）。=1-21×100%（1）=1-51×100%（2）22.1a〔5〕，a，，，〔1〕。a，。a。a，a，1。1a/（104·L-1）/%/%a/（μg·L-1）a/%a/%123451234509-17176.487.679.861.849.250.3472.115.203.000.5000.3350.095642.3198.1610-0930502262367.543244525.8485.4110.4582.7180.5690.0990.028274.0199.7310-144450364819681406120018.0273.035.7184.0510.2110.106029.1510010-21132068243549030648.3376.824.4461.9580.9310.3320.051955.9698.8310-28112098023020815012.5086.614.8780.7320.00330084.991001，，，，ClO-，，，〔7〕。，72.11%~86.61%，。，a，，。2.22。2，，，29.94%~49.85%，38.60%。，0.290~0.500NTU，98.37%，97.51%。22.3UV254DOCUV254〔7〕，DOC，〔8〕。UV254、DOC3。/NTU/%/%1234509-1715.1338.0561.0770.4410.38746.7797.4410-0913.4006.7200.6480.3090.41949.8596.8710-1417.80012.4000.4590.2650.29030.3498.3710-2119.40012.4000.8420.4300.50036.0897.4210-2817.70012.4001.1140.3870.45429.9497.443UV254、DOCUV254/cm-1UV254/%UV254/%DOC/（μg·L-1）DOC/%DOC/%123451234509-175.484.403.653.303.1719.7142.153.7393.5843.2822.9682.9194.1521.9310-094.934.383.013.293.6811.1625.355.0214.7483.9774.1944.0155.4420.0410-145.554.904.834.484.2111.7124.144.0254.0724.1733.7503.773－1.176.2610-217.347.345.575.504.91033.113.5492.8792.8192.8732.99918.8815.5010-286.676.825.304.644.832.2527.595.5904.7534.1594.2693.93014.9729.703，，UV254（1028），，8.07%。。，UV25424.14%~42.15%，30.47%。，DOC（1014），，8.45%，UV254。，。SUVADOC254nm，，〔9〕。SUVA＞4mg/（m·L），，。，SUVA2013-04，33（4）70。，SUVA1.416mg/（m·L），。，SUVA，，。2.4THMFPHAAFP（THMFP），，。，〔10〕。THMFP4。4THMFP4，1014，，THMFP，9.18%。1014THMFP，，。THMFP5.6%~35.45%，26.84%。，，THMFP。（HAAFP）（3~5mg/L），，〔11〕。HAAFP5。5HAAFP5，9171021，，HAAFP，。28.41%。，。3（1），+++V+，a78.91%99.34%，a31.37%57.29%。（2），97.51%，UV254DOC，UV254DOC8.07%8.45%；，。（3）—V+，。［1］，，，.［J］.，2010，30（2）：24-27.［2］，.［J］.，2008（）：115-117.［3］，，.［J］.，2008，29（4）：88-90.［4］ChenJJ，YehHH，TsengIC.Effectofozoneandpermanganateonalgaecoagulationremoval：Pilotandbenchscaletests［J］.Chemo-sphere，2009，74（6）：840-846.［5］SiddiquiMS，AmyGL，MurphyBD.Ozoneenhancedremovalofnaturalorganicmatterfromdrinkingwatersources［J］.Wat.Res.，1997，31（12）：3098-3106.［6］，，，.［J］.，2007，35（2）：145-148.［7］，，，.a［J］.，2011，32（4）：976.［8］，.UV254［J］.，2002，24（2）：61-63.［9］.［D］.：，2007.［10］，.［J］.，2007，33（4）：7-10.［11］.［D］.：，2005.———————————［］（1986—），。：15522658610。E-mail：zhongxiao_2008@yeah.net。［］2013-01-10（）THMFP/（μg·L-1）THMFP/%THMFP/%1234509-17176.706153.617110.82196.150118.04913.0733.1910-09121.546106.873108.95995.170114.73612.075.6010-14225.268284.080174.129165.885140.878-26.1137.4610-21334.541234.906268.050204.678215.83829.7835.4810-28193.689160.626192.455144.308150.10317.0722.50HAAFP/（μg·L-1）HAAFP/%HAAFP/%1234509-17303.946255.870205.386192.204174.25815.8242.6710-09154.496307.418147.306292.134131.862-98.9814.6510-14201.520261.680145.109128.251150.702-29.8525.2210-21446.862249.879210.177169.406171.01944.0861.7310-28255.036324.427231.549189.816260.669-27.21-2.212013－04，33（4），：71