国内外厌氧消化模型研究进展

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2012,30(25)0、,。、、、。,,,———。,,,,[1]。,,。,;,[2]。,,,,113001,、。、、。,1(ADM1)、-(ASM1-ADM1)、-(SPMT-ADM1)、-(SPHT-ADM1)、-(TP-ADM1)、-(ADM1-ASMs)、-(SR-ADM1)、-(NR-ADM1)、-(GPAE-ADM1)、-(ST-ADM1)-(IK-ADM1)。,。;;;;ADM1X703Adoi10.3981/j.issn.1000-7857.2012.25.010ProgressinAnaerobicDigestionModelsYANGShuangchun,DENGDan,LIANGDandan,PANYiDepartmentofEnvironmentalandBiologicalEngineering,LiaoningShihuaUniversity,Fushun113001,LiaoningProvince,ChinaAbstractTheanaerobicbiologicalmethodisaprocessoflowenergyconsumptionandhighefficiencytodealwithhighconcentrationorganicwastewater.Ananaerobicdigestionmodeldescribeshowthebacteriaandthefacultativeanaerobicbacteriadecomposethebiodegradableorganicinthesludgeintocarbondioxide,methaneandwaterunderanaerobicconditions.Asastructuremodel,itcontainsallprocedures,includingtheproductionprocessesofdecompositionandhydrolysis,acid,aceticacidandmethane.Inthispaper,somesludgeanaerobicdigestionmodelsarereviewed,suchasthesingle-phaseanaerobicdigestionmodel(SP-ADM1),theTwo-PhaseAnaerobicDigestionModel(TP-ADM1),thecombinationoftheAnaerobicDigestionandtheActivatedSludge(ADM1-ASMs),theSulfateReductionofAnaerobicDigestionModel(SR-ADM1),theNitrateReductionofAnaerobicDigestionExpansionModel(NR-ADEM1),theGasProductionanditsExpansionoftheAnaerobicDigestionModel(GPAE-ADM1),theSedimentationTankofAnaerobicDigestionModel(ST-ADM1),andtheInhibitionKineticsofAnaerobicDigestionModel(IK-ADM1).Inaddition,theanaerobicdigestionmodelsareevaluatedincomparisonwiththeanaerobicdigestionmodel1,andsomesuggestionsaremadeforfutureresearches.Keywordsanaerobicdigestion;biologicalmathematicalmodel;expansionmodel;wastewatertreatment;ADM1:2012-06-14;:2012-07-29:(80040118):,,,:yangchun_bj@126.com(Reviews)742012,30(25)11.1-,-[3]。(1)-。,()。,,。(2)-。/,-(,1(ADM1))。,。,,,,、,。,。-(pH),-。1.2[4],:,(、)(),;:,。,,。1.3,2070,Bryant,[5](1)。,,,;,,H2、CO2;,。、、、。22.11987,1(ASM1)[6],,ASM1BSM1[7]、ASM-AS()[8]、ASM2[9]、ASM3[10],[11-13],。,、、,,。20023,ADM1[14]。10,10,(Single-PhaseAnaerobicDigestionModel,SP-ADM1)、(ADM1-ASMs)、(Two-PhaseAnaerobicDigestionModel,TP-ADM1)、-(SulfateReductionofAnaerobicDigestionModel,SR-ADM1)、-(NitrateReductionofAnaerobicDigestionModel,NR-ADM1)(SedimentationTankofAnaerobicDigestionModel,ST-ADM1)。2.2ADM1ADM1,,、、。26,1412,(LCFAs)、(VFAs)。(DAE),7,26、19、38[15],。ADM1,。COD,COD,COD,ASMs;(CO2HCO3-)(NH4+NH3),-:SIC=SCO2+SHCO3-Sac=SAC-+SHAC,SIC,SCO2,SHCO3-,Sac,SAC-,SHAC。ASMs,ASMs。Fezzani[16]ADM1。55℃,3COD43、67、130g/L。,324d36d,、pH。ADM1,1Fig.1Anaerobicfermentationenergyflowdiagram(Reviews)752012,30(25),,;,。,,,、。、,,。2.3ASM1-ADM1,,,。、,ADM1ASMs,:(1)kgCOD/m3gCOD/m3;H2CO3-,kmol/m3mol/m3,kmol/m3g/m3mg/L;(2)ADM。ADM1ASM,。ADM1ASMs,UZaher[17],ASM1-ADM1ADM1-ASM1,,。,,,ADM1ASM。Kauder[18]ASM2d-ADM1,ASM2d,ADM1,(SBR)Fortranode,、,。Brdjanovic[19]ADM13(ASM3),,,。2.4SPMT-ADM1,,(33—35℃)。Parker[20]ADM1,SPMT-ADM1,、。。,。Veeken[21]6,,20℃0.03—0.15d-1,40℃0.24—0.47d-1。Ahring[22]45℃,,,。、,、,、、。[23]、、4,,,,-ds/dt=ks,sk,0.183、0.147、0.190、0.020d-1。[24-26],SPMT-ADM1。2.5SPHT-ADM,,,[27]。Hansruedi[28](ContinuousStirred-TankReactor,CSTR),,、pH,、。,Aquasim,。BatstoneKelle[29]UASB(UpflowAnaerobicSludgeBlanket),,ADM1pH,;,,。SPHT-ADM1,[30],,、、,。,[31](SMP),、;,。,,,,(55℃),,,、,。2.6TP-ADM11971,,。Blumensaat[32](Reviews)762012,30(25),SimulinkMatlabADM1,,,,。,。[33-34],,,,,。[35],,,、,。,,,,。,,,。、、,,。2.7SR-ADM1,ADM1。2003,Fedorovich[36]。SR-ADM1、、、4,、。,SR-ADM1、。,。Batstone[37],,,,1:10,1;1:10,,。ADM1,,。2.8NR-ADM1,ADM1。ADM1,、。:、,,、。,Tugtas[38]。,,、,,、,,。2.9GPAE-ADM1———,。Parker[39]ADM1,GPAE-ADM。、,、。,。Bouallagui[40],,,,,pH6.8—7.6,。20d,((VS))2.89gVS/(L·d),,。44%144%。Bouallagui[40],(ASBR)0.32L/gCOD,COD96%。[41]、,,6.59VS/L30.865t/gVS,0.950L/gVS1.012L/gVS。2.10ST-ADM1,。Batstone[29]ST-ADM1,CaCO3,CaCO3,、,。Yasui[42]ADM1,,,3。RistowHRT60d5d,COD40、25、132g/L。(Reviews)772012,30(25)2.11IK-ADM、,,。ADM1,pH、、。pH,,;pH,,,pH。,,Lehninger,[43],I=1/(1+SI/KI),I,SI,KI。pH,pH。,,Zaher[44]3,,,ADM1,,,———。,,ρj=kmSKS+SXnk=1仪Ik,ρj;kmSKS+SMonod;km;KS;S;X;,Ik=f(Sk)(k=1,2,…,n)pH、、。3,,。ADM1、pH,。。ADM1,,,,,。,,,,,,。,ADM1(SPMT-ADM1、TP-ADM1、ADM1-ASMs、SR-ADM1、NR-ADM1、GPAE-ADM1),。,;,,。,。(References)[1],,,.[J].,2012,38(4):13-15.ChenGong,SongLingling,DaiXiaohu,etal.TechnologyofWaterTreatment,2012,38(4):13-15.[2].[J].,2008,26(4):45-47.ChenLirong.EnvironmentalEngineering,2008,26(4):45-47.[3]MadsenM,Holm-NielsenJB,EsbensenKH.Monitoringofanaerobicdigestionprocesses:Areviewperspective[J].RenewableandSustainableEnergyReviews,2011,15(6):3141-3155.[4]BlumensaatF,KellerJ.Modellingoftwo-stageanaerobicdigestionusingtheIWAAnaerobicDigestionModelNo.1(ADM1)[J].WaterResearch,2005,39(1):171-183.[5].()[M].:,1997.ZhangZijie.Drainageengineering(volumetwo)[M].Beijing:ChinaArchitecturalIndustryPress,1997.[6]HenzeM,GradyCPL,GujerW,etal.ActivatedsludgemodelNo.1-IAWPRCscientificandtechnicalreportNo.1[R].IAW-PRCScientificandTechnologicalReportNo.1,London:IAW-PRC,1987.[7]AbdelhayB,MohamedH,MoussaC.LinearizationofthefullactivatedsludgemodelNo1forinteractionanalysis[J].BioprocessandBiosystemsEngineering,2010,33(4):759-771.[8],.ASM1[J].,2012,29(1):67-70.ShuHaitao,LuoJianxu.ComputersandAppliedChemistry,2012,29(1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