海水淡化技术集成的研究进展伍联营

伍联营,夏　艳,高从(中国海洋大学化学化工学院,山东青岛266100):,、、、。、,。:;;;;:P747;TQ085.42　:A　:0253-4320(2006)12-0013-04AdvancesinintegrationofseawaterdesalinationtechnologiesWULian-ying,XIAYan,GAOCong-jie(CollegeofChemistryandChemicalEngineering,OceanUniversityofChina,Qingdao266100,China)Abstract:Thecouplingcharacteristicsofseawaterdesalinationtechnologiesareanalyzed,andtheintegrationofdesalinationprocessesisintroduced,includingdesalinationmethods,theintegrationbetweendesalinationandenergyresource,pretreatmentanddesalinationandthedesalinationamongindustrialchains.Inaddition,someproblemsindesalinationintegrationsuchaslowdegreeofintegrationandlackoftheoreticalguidancearepointedout.Itisthereforesuggestedthatthetheoreticstudyofdesalinationintegrationandoptimumtechnologiesshouldbestrengthened.Keywords:desalination;reverseosmosis(RO);multi-stageflash(MSF);multi-effectdistillation(MED);integration　:2006-09-12　:(1971-),,,,,[e-mail]。　　,,,[1]。2:,、;,,。,[2-3]。1　2[4-5],(MSF)(MED),(RO)。、、、,。RO,,RO。,:①、;②、、。2　,。3:①;②;③--。2.1　,。TorayBCS(brineconversionsystem)60%,Mas-Palomas4500t/d。BCS12[6-9]。ROMSF(MED)。MSFRO。MisraROMSF。Car-dona[10]MSFRO·13·2612现代化工Dec.2006200612ModernChemicalIndustryDOI:10.16606/j.cnki.issn0253-4320.2006.12.003,ROMSF,,。MisraMSFRO,(TDS),、。MayROMSF。Helal[11-13]7:RO,ROMSF。,ROMSF[3],JeddahMSF/(SWRO);Yanbu,44500m3/dMSF12800m3/dSWRO;Al-Jubail9000m3/dSWRO。FujairahMSF/SWRO/。,,。MSFRO:2RO,ROMSF。,,;,,。2.2　[14-18],(MF)、(UF)(NF),、SWRO,,。,。(SalineWaterCon-versionCorporation,SWCC)NF-SWRO,70%,。SWCCNF-MSF:、,,MSF120～160℃,　　(上接第12页)4　,:,、、、、、、、、、。、、。2,,,,。,,,。,,,。,,,。,,。[1]MittelbachM.Dieselfuelderivedfromvegetableoils:Ⅵ.Specificationandqualitycontrolofbiodiesel[J].BioresourceTechnology,1996,56(1):7-11.[2]BiofuelSystemsGroupLtd.Biodieselstandards[S/OL].[2006-08-01].[3],.:[J].,2001(6):37.[4].[J].,2004,23(5):75-75.[5].GB/T19147—2003《》EN590《》[J].,2003,30:35-36.[6],.[J].,2005,3:33-34.[7],,,.-[M].:,2005.[8],,,.[J].,2004,3:14-17.□·14·现代化工2612230kJ/kg168.7kJ/kg。,NFSWROMSF,,(),。2.3　(),。2.3.1　海水淡化与火电厂的集成,;。,。Yanbu-MedianⅡ,JeddahⅠ、Ⅱ,AlKhobarⅢShoaibaⅡ、;JebelAli(G)450MW,28.8m3/d;(AbuDhabi)732MW65.8m3/d[3]。,、3000m3/dMED,。2.3.2　核能与海水淡化的集成(IAEA):。1973,MEDMSF,、。10,MED、MSFRO,,。Madras(PHWR),,4500t/dMSF1800t/dRO[19]。、、,。10MW,MED,8000t。、。2.3.3　太阳能与海水淡化的集成2[20],。Wilson、Salinas,4700m2,23t。20,、。,,,35%～45%。,。(SGSP)[21]2,。1987SGSPMSF(MEMS)。,SGSP(BCRS)。。RO,,2080,,[21]。2.3.4　其他能源与海水淡化的集成、,、、。,RO。,GranCanari200t/dRO,5kWh/m3,[19]。2.4　--,、,、。,Ahmed[22]Arakel、、:,、;;,,。3　,、·15·200612:。,:(1),,。(2),。(3),;;。(4),,。[1],.[J].,2000,26(1):7-12.[2],,.[J].,2000,2(7):43-46.[3]HamedOA.Overviewofhybriddesalinationsystems:Currentstatusandfutureprospects[J].Desalination,2005,186(1/2/3):207-214.[4]El-DessoukyH,EttouneyH.MSFdevelopmentsmayreducedesalinationcost[J].WaterandWastewaterInternational,2000,15(6):20-21.[5].[J].,2003,21(11):24-26.[6]GrǜndischA,SchneiderBP.OptimisingenergyconsumptioninSWROsystemswithbrineconcentrators[J].Desalination,2001,138(1/2/3):223-229.[7]TaniguchiM,KuriharaM,KimuraS.Behaviorofareverseosmosisplantadoptingabrineconversiontwo-stageprocessanditscomputersimula-tion[J].JMembrSci,2001,183(2):249-257.[8]KuriharaM,YamamuraH,NakanishiT.Highrecovery/highpressuremembranesforbrineconversionSWROprocessdevelopmentanditsper-formancedata[J].Desalination,1999,125(1/2/3):9-15.[9]KuriharaM,YamamuraH,NakanishiT,etal.Operationandreliabilityofveryhigh-recoveryseawaterdesalinationtechnologiesbybrinecon-versiontwo-stageROdesalinationsystem[J].Desalination,2001,138(1/2/3):191-199.[10]CardonaE,CulottaS,PiacentinoA.EnergysavingwithMSF-ROseriesdesalinationplants[J].Desalination,2003,153(1/2/3):167-171.[11]HelalAM,El-NalsharAM,Al-KatheeriE,etal,Optimaldesignofhy-bridRO/MSFdesalinationplants:PartⅠ.Modelingandalgorithms[J].Desalination,2003,154(1):43-66.[12]HelalAM,El-NalsharAM,Al-KatheeriE,etal.Optimaldesignofhy-bridRO/MSFdesalinationplants:PartⅡ.Resultsanddiscussion[J].Desalination,2004,160(1):13-27.[13]HelalAM,El-NalsharAM,Al-KatheeriE,etal,Optimaldesignofhy-bridRO/MSFdesalinationplants:PartⅢ.Sensitivityanalysis[J].De-salination,2004,169(1):43-60.[14],,.[J].,2003,23(6):54-58.[15]HassanAM,FarooqueAM,JamaluddinATM,etal.AdemonstrationplantbasedonthenewNF-SWROprocess[J].Desalination,2000,131(1/2/3):157-171.[16]HassanAM,Al-SofiMA-K,Al-AmoudiAS,etal.Anewapproachtomembraneandthermalseawaterdesalinationprocessesusingnanofiltra-tionmembranes[J].Desalination,1998,118(1/2/3):35-51.[17]Al-SofiMAK.Seawaterdesalination-SWCCexperienceandvision[J].Desalination,2001,135(1/2/3):121-139.[18]Al-SofiMAK,HassanAM,HamedOA,etal.Optimizationofhy-bridizedseawaterdesalinationprocess[J].Desalination,2000,131(1/2/3):147-156.[19]NisanS,CarusoG,HumphriesJR,etal.Seawaterdesalinationwithnu-clearandotherenergysources:TheEURODESALproject[J].NuclearEngineeringandDesign,2003,221(1/2/3):251-275.[20]TriebF,NitschJ,KronshageS,etal.Combinedsolarpoweranddesali-nationplantsfortheMediterraneanregion-sustainableenergysupplyus-inglarge-scalesolarthermalpowerplants[J].Desalination,2