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第33卷第5期辽 宁 化 工Vol.33,No.52004年5月LiaoningChemicalIndustryMay,2004 王春敏,李亚峰,陈 健 (,110168) : 。、、、、、。。 : ;;;: TQ085+.412 : A : 10040935(2004)05027604 ,。,,,。、,,。,。,;。,。1 1.1 ,,。,,,。2080King,。,,。:MacGlashan25%(TOPO)(DIBK);QH-1;YH;YH-1。1.2 ,,、。,、。,,。1.3 ,、。,,。1.3.1 ,。,(PACT);(SBR)PAC-SBR; 收稿日期: 2004-02-10 作者简介: 王春敏(1973-),女,讲师,在读硕士研究生。。1.3.2 ,,。。Edgehill、Lewandon-ski、,,,。1.3.3 ,2080,。,100%;330mgL,97%～99%。,。、,。1.3.4 、。,。2000,,,,。2000,KaiChleeLonPseudomonasputida49451,2000～3500mgL。,,。1.4 1.4.1 (125～320℃)(0.5～20MPa),。,。1987,Cu(NO3)2,(7866mgL,COD22928mgL),、、100%,COD65%～90%。1996,S.H.Lin,,150℃,0.5MPa。,。1.4.2 20,、、,。。,,。TiO2、、,。1999,TiO2,pH=42h,100%。,、、,。,O3、H2O2、Fenton,,,,。:UVO3、UVH2O2、UVFenton,UVFenton。Fenton1894Fenton,H2O2Fe2+。Fenton,,Fenton。,Fenton,UVFenton。UVFentonFe2+H2O2UVH2O2。UVTiO2,UVFenton,,UVFentonUVTiO23～5,UVH2O2、UVTiO2。Photo-Fenton277335 ,: ,KiWi、Faust、Holgne,Bolt-on、Cater、Amiri,Sedlak、Ollis、Rupert、Pigna-tello。、、、、、、、、、Photo-Fenton。、Fenton,。1.4.3 ,、、、。,,。β-PbO2,。,,。1.4.4 2080。NeisSuri,(5000K)(·OH),、。,、,,。1.4.5 Modell。,,,。、,,、,、。1.5 1.5.1 ,-。2080,。。TBP()--,,80%,TBP,。,。1.5.2 2060。2080,,,。,,,,50μgmL,2%NaOH,CO2NaOH,。1.6 ,,H2O、CO2。,、,,,。,,。,,。2 (1)、、,、、。(2),,。(3)、、,。,。278 20045、。(4),CO2、H2O,,,,,。(5),,、。。1 ...2003,(4)2 ,...2002,(2)3 ...2001,(2)4 ,...2001,(14)5 ...1998,18(2)6 .UVFenton..2001,(3)7 .UVFenton..2002,(2)8 ,,.UVFenton..2002,3(2)9 ,,.Fenton..2003,25(4)10 ,,.Fenton..2003,31(5)11 .Fenton..2000,(5)12 ...2002,(6)13 ,...2001,(6)14 FentonH.J.,Oxidationoftartaricacidinthepresenceofiron.j.Chem.soc.,1894,65:899-91015 ZeppR.G.,FaustB.C.,HolgneJ.,Hydroxylradicalformationinaqueousreactions(pH3-8)ofiron(Ⅱ)withhydrogenper-oxide:thephoto-Fentonreaction,Environ.Sci.Technol.,1992,26:313-31916 HarberF.,WeissJ.J.,Proc.R.Soc.London,Ser.A1934,147,332-34517 BarbW.G.,BaxendaleJ.H.,GeorgeP.,HargraveK.R.,TransFaradaySoc.,1951,47,462-50018 WallingC.,Acc.Chem.Res.,1975,125-13119 BossmanS.H.,OliverosE.,etal.,OxidativedegradationofpolyvinylalcoholbythephotochemicallyenhancedFentonreac-tion.Evidencefortheformationofsuper-macromolecules,Prog.React.Kinet.Mech.,2001,2620 LewandonskiG.A.,etal.Reactordesignforhazardouswastetreatmentusingawhiterotfungus.Wat.Res.,1990,24(1):75-7921 RuppertG.,BauerR.,ThePhoto-FentonReaction--aneffectivephoto-chemicalwastewatertreatmentprocess,J.Photochem.Photobiol.A:Chem.,1993,73:75-7822 BrasquetC,SubrenatE,etal.RemovalofPhenolicCom-poundsfromAqueousSolutionbyActivatedCarbonCloths[J].WaterScienceTechnology,1999,39(10-11):201-20523 RengarajS,Seung-HyeonNoon,etal.Removalofphenolfromaqueoussolutionandresinmanufacturingindustrywastewaterusinganagriculturalwaste:rubberseedcoat[J].JournalofHazardousMaterials,2002,89(2-3):185-19624 RodriguezIMPLiompart,CelaR.Solid-phaseextractionofphenols[J].JournalofChromatographyA,2000,885(1-2):291-30425 AlvaroAMGMonteiro,etal.PhenolbiodegradationbyPseudo-monasputidaDSM548inabatchreactor[J].BiochemicalEn-gineeringJournal,2000,6(1):45-49.StudyStatusandProcessofTreatmentofPhenolicWastewaterWANGChun-min,LIYa-feng,CHENJian(DepartmentofMunicipalEngineeringofShenyangArchitecturalandCivilEngineeringInstitute,Shenyang110168,China)Abstract:Thestatusoftheresearchontreatmentofphenolicwastewaterweresummarizedinthepaper.Thecharacteristicsandmainproblemsofsolventextractiontechnique、adsorptiontechnique、advancedoxidationprocess、biochemicaltreatmentprocess、membranesep-arationprocessandincinerationprocesswereanalyzed.Theapplicationprospectofeachtechnologywasalsoanalyzed.Inaddition,thedevelopingtrendoftreatmenttechnologyofphenolicwastewaterwasdiscussed.Keywords:Phenolicwastewater;Treatmenttechnology;Researchstatus;Developingtrend279335 ,: