812Vol.8No.12201412ChineseJournalofEnvironmentalEngineeringDec.20141222*1.1008712.130017SBR。40%、60%15SBR27COD89%TN、NH3-NTP56%、86%90%。1.3mmSEM。SBR。SBRTQ116.2A1673-9108201412-5335-04TreatingpetrochemicalwastewaterusingaerobicgranularsludgeJinYuhui1WuDi2SongGuojing2HuoMingxin21.GuanghuaSchoolofManagementPekingUniversityBeijing100871China2.SchoolofEnvironmentNortheastNormalUniversityChangchun130017ChinaAbstractWastewaterfromtheprimarysedimentationtankofJilinPetrochemicalWastewaterTreatmentPlantwasusedasrawwatertocultureaerobicgranularsludgeinalab-scalesequencingbatchreactorSBR.TheSBRwasoperatedwith40%to60%dilutedpetrochemicalwastewatergranularstructureswereobservedafter15daysthen100%ofthepetrochemicalwastewaterwasusedandthesettlingtimewasgraduallyreduced.Theefflu-entwassteadyatthe27thdayandtheCODTNNH3-NTPremovalefficiencieswere89%56%86%and90%respectively.Accordingtothescanningelectronmicroscopeimagethesludgewasmainlycomposedofba-cillusandfilamentarybacteriaandthereexistedanumberofholeswithinthesludge.Resultsindicatethataerobicgranulesludgeformedmorerapidbygraduallyincreasingtheproportionofpetrochemicalwastewaterandshorteningthesettlingtime.Theaerobicgranularsludgeshowsgoodpotentialforpetrochemicalwastewatertreatment.KeywordsaerobicgranularsludgesequencingbatchreactorSBRpetrochemicalwastewater200860352013-11-042014-02-181966—。E-mailjinyh369@163.com*E-mailhuomx097@nenu.edu.cn、--TNNH3-N1。、、。2-5、。、、、6-9。SBRCOD、、、。11.1SBR7cm52cm2L1.5L。、、、。0.15m3/h820±1℃1。1SBRFig.1SBRexperimentaldevice1.2SBRMLVSS/MLSS0.60SVI170mL/g0.1mm0.078mm。46h10min30、20、15、105min1010min。20cm。40%、60%=V/V+V×100%15dCOD、BOD5、NH3-N、TN、TP390~450、170~204、51~57、83~909~11mg/LpH7.5~8.0。COD、TN、NH3-N、TP4。1.31SV、SVI、MLSS、MLVSS、COD、NH3-N、TN、TP11。212、、、、、、HITACHIS-4700。22.1COD200mg/L。。2。1.3mm。2。2a2Fig.2SEMimagesofaerobicgranularsludgeofdifferentmagnification6335122b2c、2d。2.2CODCOD150~250mg/L。COD70%15d。COD400mg/L。3CODmLSSCOD85%。3CODFig.3RemovalefficiencyofCODwithaerobicgranularsludge2.31545。NH3-N、TN54mg/L88mg/LNH3-N85%TN56%。NH3-NNO-2-NNO-3-N。4NH3-NFig.4RemovalefficiencyofNH3-Nwithaerobicgranularsludge5TNFig.5RemovalefficiencyofTNwithaerobicgranularsludgeNN2。TNNH3-NC/NNO-3-N13。2.46TPFig.6RemovalefficiencyofTPwithaerobicgranularsludge6TPNH3-NTNTP90%TP733582125。12Ca2+133--14。225。WangFen15。31SBR。2SEM、。3COD、NH3-N、TPTN、TP。1..2006ShiLijun.Biologicalnitrogenremovalfrompetrochemicalwastewaterusingswimbedbiofilmreactorandanaerobicammoniumoxidation.DalianDoctoralDissertationofDalianUniversityofTechnology2006inChinese2BeunJ.J.HendriksA.VanLoosdrechtM.C.M.etal.Aerobicgranulationinasequencingbatchreactor.Wa-terResearch199933102283-22903TayJ.H.LiuQ.S.LiuY.Microscopicobservationofaerobicgranulationinsequentialaerobicsludgeblanketre-actor.JournalofAppliedMicrobiology2001911168-1754TayJ.H.LiuQ.S.LiuY.Theeffectsofshearforceontheformationstructureandmetabolismofaerobicgran-ules.AppliedMicrobiologyandBiotechnology2001571-2227-2335LiuY.YangS.F.LiuQ.S.Theroleofcellhydropho-bicityintheformationofaerobicgranules.CurrentMicrobi-ology2003464270-2746..200423553-55LanHuixiaChenZhonghaoChenYuancai.Treatmentofeffluentfromannnonimsulfitepulpingwithaerobicgranularsludgetechnology.ChinaPulp&Paper200423553-55inChinese7..200632873-75ChiHanYangFenglinLiuYihuietal.Treatmentofmu-nicipaldomesticsewagewithaerobicgranularslude.Technol-ogyofWaterTreatment200632873-75inChinese8ArrojoB.Mosquera-CorralA.GarridoJ.M.etal.Aerobicgranulationwithindustrialwastewaterinsequen-cingbatchreactor.WaterResearch20043814-153389-33999SuKuizuYuHanqing.Formationandcharacterizationofaerobicgranulesinasequencingbatchreactortreatingsoy-bean-processingwastewater.Eniron.Sci.&Technol.20053982818-282710..200826115-17GaoJingfengGuoJianqiuBiHuanyu.Rapidstartofaerobicgranularsludgereactorwithtreatmentphosphorusremoval.EnvironmentalEngineering200826115-17inChinese11.1.198912..2009BaoRuiling.Studyontheperformanceandprocessesofsim-ultaneouslynitrogenandphosphorusremovalbyaerobicgran-ularsludgeatlowtemperature.HarbinDoctoralDissertationofHarbinInstituteofTechnology2009inChinese13JuangY.C.SunilS.A.LeeD.J.etal.Stableaer-obicgranulesforcontinuous-flowreactorsPrecipitatingcalciumandironsaltsingranularinteriors.BioresourceTechnology2010101218051-805714WachtmeisterA.KubaT.VanLoosdrentM.C.M.etal.Asludgecharacterizationforaerobicanddenitrif-yingphosphorusremovingsludge.WaterResearch1997313471-47815WangFenLuShanWeiYanjieetal.CharacteristicsofaerobicgranuleandnitrogenandphosphorusremovalinaSBR.JournalofHazardousMaterials20091642-31223-12278335