环丙沙星在水中的高级氧化去除方法研究进展

4510201610AppliedChemicalIndustryVol．45No．10Oct．20162016-04-042016-04-052012ZX07403-0011980－。[e-mail]。[e-mail]1121111．0140102．200092、、、、、。TQ031．7A1671－3206201610－1959－06ＲesearchprogressoftheoxidationremovalmethodsofciprofloxacininwaterYANGWen-huan1WANGChao-hui1GAONai-yun2LIWei-ping1YINZhen-yu1GAOJing-tian11．SchoolofEnergyandEnvironmentInnerMongoliaUniversityofScienceandTechnologyBaotou014010China2．StateKeyLaboratoryofPollutionControl＆ＲesourcesＲeuseTongjiUniversityShanghai200092ChinaAbstractSummarizestheFentonheterogeneousphotocatalysisozoneoxidationbasedonpersulfateandperoxymonosulfatetreatmenttechnologyandotheradvancedoxidationprocessesofciprofloxacindegrada-tioninwateranalysestheremovalmechanismsremovaleffectsmeritsanddrawbacksandtheeffectivemethodswasoutlooked．KeywordsciprofloxacindegradationadvancedoxidationprocessesCIP80%ng/L～μg/L。CIP、、CIP1-5。CIP。F2·OH·SO4－6-8CIP。1CIP1．1CIP1CIP。CIP、。1Table1Theconcentrationofciprofloxacindetectedinaquaticenvironment/ng·L－1Nd～23．29＜1091393093×103～8．9×10410151．8×102～9．8×103111．9×103～5．3×10312、67～509131．2CIPCIP21%14。MBＲCIPDOI:10.16581/j.cnki.issn1671-3206.20160705.0074551%MBＲ15。CIP、CIP。LanhuaCIPCIP1216。17。。22080、、。、F2·OH·SO4－2。CIP、、、·SO4－。2Table2ComparisonofredoxpotentialsofcommonoxidantsF2·OH·SO4－O3H2O2KMnO4ClO2HClOCl2Br2/V2．872．802．602．071．771．671．501．491．361．092．1Fe2+H2O2·OH1～318。、、。、、、、、、、19、、。Fe2++H2O2→Fe3++OH－+·OH1FeOH2++hv→Fe2++·OH2Fe3++H2O2→Fe2++·HO2+H+3Fe2+H2O2Fe2+H2O2。UV、。3CIP。3CIPCIP20-21。3CIPTable3PerformanceofdifferentadvancedoxidationprogressforciprofloxacinremovalCIP65μmol/L2．6μmol/L15W、365nm410nm、pH2．5～6．5、CIPH2O26mmol/L3160μmol/LH2O2500．130．320．80mmol/LpH4．510min65μmol/LCIP10min20%CIPpHH2O2CIP200．15mmol/L0．1mmol/LFe2+、0．05mmol/LNa2SO4、pH3、60～400mACIP400mA8minCIP6hCIP94．62%21100μmol/LUV-A、Vis、0．5g/LTiO2、pH6UV-A/TiO2CIP2245．3μmol/LUV-A、UV/C、0．5g/LTiO2-P25、pH3～10UV-CCIPUV-ACIPpH7CIP2345．3μmol/L2500mg/LO3、0～1000μmol/LH2O2、pH3～10、pH10CIP19minH2O2CIP24200μg/L450mg/hO3、pH930minCIP25PS0．013mmol/L35～60℃、PS0．260．521．04mmol/L、pH4～11CIP、PSpH2610mg/L8W、254nm、pH6．8～7．1、PS1．92g/L30minCIP95%27PMS50μmol/L15W、254nm、UV/PS12．60×10－2min－1UV/PMS5．64×10－2min－128pH3069110Fe2+。。CIP29Fe2+。2．2TiO2、、30。TiO2388nm/。、OH－·OH31。1。、32。1TiO2Fig．1SchematicdiagramforcatalyticmechanismbyTiO2photocatalysispH。CIPUVA-TiO2＞Vis-TiO2＞UVAUVA-TiO222。pHCIPpHCIP233。2。。TiO2、、、、。32。2Fig．2Thepercentageofdifferenetadvancedoxidationprocesses2．3。·OH·OH4～9。O3+OH－→O2+HO2－4O3+HO2－→·HO2+·O3－5·HO2→H++·O2－6·O2－+O3→O2+·O3－7·O3－+H+→·HO38·HO3→·OH+O29CIPpH37pH10CIP244、5pHpH。TibiriáG、、CIP30min25。、、、。33、。。2．4PS、34。Fe2+H2O235。16914536。。、、。43。43Table4MechanismforthreemethodsofactivationpersulfateS2O82－+heat→2·SO4－S2O82－+Men+→2·SO4－+Men+1++SO42－S2O82－→uv2·SO4－2．4．1ISCOISTＲ。37。。、、pH、、。26CIPCIP、pHCl－、NO3－、PO43－CIP。50℃40℃。2．4．2Co2+、Ag+、Ce2+、Mn2+、Cu2+、Fe2+FeIII、MnIV38-39。、。Yuefei40FeII-CIPCIPFeII-1∶1∶11∶5∶51∶20∶20CIP36．9%73．3%95．6%FeII-·SO4－·OH。Fe2+PS41。Fe2+Ag+pH3Fe2+Ag+。。2．4．3UV。、。Chia-Chang27CIP1．92g/L30minCIP95%。CIP/。UV。UV5%·SO4－42。2．5PMS、。、·SO4－·OH43-44。5。5、Table5MechanismforUVionactivatedperoxymonosulfateHSO5－+hv→·SO4－+·OHMn++HSO5－→Mn+1++OH－+·SO4－AniPsitakisCo2+。Co2+45-47。Co2+CIP。MoussaMahdi-Ahmed28UV/PMS、UV/PS、UV/H2O2CIPUV/PS＞UV/PMS＞UV/H2O2。UV/PMS＞UV/PS＞UV/H2O2HCO3－PMS。Co2+/PMSpHpH=2pH=9。Co2+269110。3CIP1CIP。2、。3·SO4－。1ParasTrivediDharniVasudevan．Spectroscopicinvestiga-tionofciprofloxacinspeciationatthegoethite-waterinter-faceJ．EnvironmentalScience＆Technology2007413153-3158．2ChengGuKarthikeyanKG．SorptionoftheantimicrobialciprofloxacintoaluminumandironhydrousoxidesJ．EnvironmentalScience＆Technology200539239166-9173．3HuLanhuaAmandaMStemigKristineHWammer．Oxi-dationofantibioticsduringwatertreatmentwithpotassiumpermanganatereactionpathwaysanddeactivationJ．En-vironmentalScience＆Technology20114583635-3642．4SunShipengAlanHattonTChungTai-Shung．Hyper-branchedpolyethyleneimineinducedcross-linkingofpoly-amide-imidenanofiltrationhollowfibermembranesforre-movalofciprofloxacinJ．EnvironmentalScience＆Technology20114594003-4009．5AndreaSpeltiniMichelaSturiniFedericaMaraschi．Ana-lyticalmethodsforthedeterminationoffluoroquinolonesinsolidenvironmentalmatricesJ．TrACTrendsinAna-lyticalChemistry20113081337-1350．6AnTaichengYangHaiLiGuiying．Kineticsandmecha-nismofadvancedoxidationprocessesAOPsindegra-dationofciprofloxacininwaterJ．AppliedCatalysisBEnvironmental201094288-294．7VanessadeJesusGaffneyCristinaMMAlmeidaAlexan-dreＲodriguesetal．Occurrenceofpharmaceuticalsinawatersupplysystemandrelatedhumanhealthriskassess-mentJ．WaterＲesearch201572199-208．8．J．201137311-17．9TangJShiTWuXetal．Theoccurrenceanddistribu-tionofantibioticsinLakeChaohuChinaSeasonalvaria-tionpotentialsourceandriskassessmentJ．Chemo-sphere2015122154-161．10LindbergＲHWennbergPJohanssonMIetal．Screen-ingofhumanantibioticsubstancesanddeterminationofweeklymassflowsinfivesewagetreatmentplantsinswe-denJ．EnvironmentalScience＆Technology200539103421-3429．11PereiraAMPTSilvaLJGMeiselLMetal．Environ-mentalimpactofpharmaceuticalsfromPortuguesewastewat