环境保护中活性炭纤维的运用实践分析与研究

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200083、、。。X-1AAreviewontheapplicationandpracticeofactivatedcarbonfiberinenvironmentalprotectionLyuJingShanghaiAutomobileGroupCo.LtdShanghai200083AbstractInthecontextofthecontinuousdevelopmentofsocialeconomyourcountrypaysmoreat-tentiontoenvironmentalprotection.Watersoilandairpollutionhaveincreasinglybecometheurgentproblemstobesolved.Activatedcarbonfiberisintroducedasameansforinnovativeenvironmentalgovernance.Inthispaperbyanalyzingtheperformanceofactivatedcarbonfiberitsapplicationinenvironmentalprotectionhasbeenstudiedindepthaimedatpromotingthesteadysocialandeco-nomicdevelopment.Keywordsenvironmentalprotectionactivatedcarbonfiberapplication.、、。、、、。。。11.1①。。。②。、、、。③。、。1.22018-02-262018-05-031982-。E-mailjingle1224@126.com·25·20184Vol.24No.41。70。1985、、、、2。“SuperDixie”。。、a2FeOOH3。1962W.F.Abbott。、、、、。1970、2。Tsai4。。0.6~0.7nm5。HuangZH6。。7。。、PAN。、。。。、、、、、、。、、8。、9。、10。。2ACF90%IUPAC2nm2~50nm50nm、11。80%。0.4%~1.9%、2%~20%N、S。ACFCO。、、、、、。-COOH-OHACFACF、ACFACF、12。ACFACF、。ACFACF、。ACF。·35·20184Vol.24No.42.1ACF、、。。。、。13。2.1.1。800℃~1200℃O2CO2H2OACF14-16、KOHH3PO4、、17-19。2.1.2ACF。ACF。ACF、。2.1.3ACF20。、、、、。21CVDNiNO32·6H2OPANACFPAN-ACFACF。2.2。2.2.1。2.2.2。。ACF、ACFC4H7NOpH。1ACF。。1ACF1000W×1min500W×1min/mmol·g-10.0610.0840.106/mmol·g-10.5450.4390.1682.2.322。2.2.4ACFMg2+Ca2+。-C-OH-C-H+Moxid+H2O→-C-OH+Mred+H+1-C=O-C-H+Moxid+H20→-C=O+Mred+H+2MoxidMred。3、。ACFO2O3。23ACF85%·45·20184Vol.24No.4、ACF24ACFCd2+ACF。25ACFNaCl100mg/L60min99.3%。2.2.512。Au3+Hg2+ACFACFACF。ACF。26ACFACFXeACFXe。2.2.6、、、27。28ACF、。2.2.7TiO2ZnOACFACFACFACFACF。33.1。、。GHGIGAC。。、3。3.23.2.129。。298K、pH=40.25L/h439.4mg/g99%TOC99.4%99.5%、。30。3.2.2、、。30210mg/g、pH731。、、94.7%、67.8%、80.5%32。3.33.3.1·55·20184Vol.24No.4、。。、2。H2S。H2SSH2S。H2S。Bouzaza33-34、H2SH2S。MarafiM35H2SOH·O-2·H2S。PrimaveraA36H2S。。。SO2、。SO2。、SO2、、SO2。37SO2SO20.7nmSO2SO220.37mg/g。GaurV38-39CO2SO2。-OH-COOHC=0CO2SO2。SO2。40SO2。、、SO2。41SO2。3.3.2、。。。NOx、、。。、4243。RathoreRS44NO5mol/LNO300mg/LNO70%。、。Alcaniz-MongeJ45FeNO、NONO。NO·65·20184Vol.24No.4NO。46-48Ag、Cu、NiNO75%、85%、95%。49NO。NONO。4。50①。。②、。。③。、。1.J.201742221-26.2.J.2017343190-194.3.J.20152668.4TsaiJHChiangHMHuangGYetal.Adsorptioncharacteristicsofacetonechloroformandacetonitrileonsludge-derivedadsorbentcommercialgranularactivatedcarbonandactivatedcarbonfibersJ.JHazardMater20081541-31183-1191.5ImJSParkSJKimTJetal.Thestudyofcontrol-lingporesizeonelectrospuncarbonnanofibersforhydro-genadsorptionJ.JColloidInterfaceSci2008318142-49.6HuangZHKangFZhengYPetal.AdsorptionChar-acteristicsofTraceVolatileOrganicCompoundsonActi-vatedCarbonFibresatRoomTemperatureJ.Adsorp-tionScience&Technology2002205495-500.7.J.20153232-9.8.———IJ.20142104-112.9.ACFACFJ.2000328-32.10.J.2009294331-334.11MochidaIKoraiYShirahamaMetal.RemovalofSOxandNOxoveractivatedcarbonfibersJ.Carbon2000382227-239.12.J.20032115-17.13.D.2016.14SuzukiM.ActivatedcarbonfiberFundamentalsandapplicationsJ.Carbon1994324577-586.15Maciá-AgullóJAMooreBCCazorla-AmorósDetal.InfluenceofcarbonfibrescrystallinitiesontheirchemicalactivationbyKOHandNaOHJ.Micro-porousandMesoporousMaterials20071013397-405.16KoTHchiranairadulPLuCKetal.TheeffectsofactivationbycarbondioxideonthemechanicalpropertiesandstructureofPAN-basedactivatedcarbonfibersJ.Carbon1992304647-655.17LuAHZhengJT.StudyofMicrostructureofHigh-Surface-AreaPolyacrylonitrileActivatedCarbonFibersJ.JColloidInterfaceSci20012362369-374.18RyuZRongHZhengJetal.MicrostructureandchemicalanalysisofPAN-basedactivatedcarbonfiberspreparedbydifferentactivationmethodsJ.Carbon20024071144-1147.19Martín-GullónIAndrewsRJagtoyenMetal.PAN-basedactivatedcarbonfibercompositesforsulfurdi-oxideconversioninfluenceoffiberactivationmethodJ.Fuel2001807969-977.20.J.200120412-18.21.CVDPAN-ACFJ.2001229·75·20184Vol.24No.41546-1550.22.J.2017394292-295.23.J.2008246544-550.24.J.201036S137-41.25.ACFNaClJ.201081765-1770.26.J.2004206481-493.27.J.2009271100-103+106.28.ACFJ.2008371296-299.29.J.2015581-84.30.-J.20141595-96.31.J.20173682986-2993.32.-J.2012328-31.33BouzazaALaplancheAMarsteauS.Adsorption-oxi-dationofhydrogensulfideonactivatedcarbonfiberseffectofthecompositionandtherelativehumidityofthegasphaseJ.Chemosphere2004544481-488.34BandoszTJ.Ontheadsorption/oxidationofhydrogensulfideonactivatedcarbonsatambienttemperaturesJ.JColloidInterfaceSci200224611-20.35MarafiMAl-SheehaHAl-OmaniSetal.ActivityofhydroprocessingcatalystspreparedbyreprocessingspentcatalystsJ.FuelProcessingTechnology2009902264-269.36PrimaveraATrovarelliAAndreussiPetal.Theeffectofwaterinthelow-temperaturecatalyticoxida-tionofhydrogensulfidetosulfuroveractivatedcarbonJ.AppliedCatalysisAGeneral19981732185-192.37.SO2J.2014353293-298.38GaurVSharmaAVermaN.Preparationandcharac-terizationofACFfortheadsorptionofBTXandSO2J.ChemicalEngineeringandProcessingProcessIntensifi-cation20064511-13.39GaurVAsthanaRVermaN.RemovalofSO2byacti-vatedcarbonfibersinthepresenceofO2andH2OJ.Carbon200644146-60.40.SO2J.201543412-14.41DiezNAlvarezPGrandaMetal.Tailoringmicro-mesoporosityinactivatedcarbonfiberstoenhanceSO2catalyticoxidationJ.JColloidInterfaceSci201442836-40.42WangMLiuHHuangZHet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