MaterialSafetyDataSheetProduct:Haveg4801PhenolicResin1.ChemicalProductandCompanyIdentificationTradeNameHaveg4801PhenolicResinSynonymsNoneManufacturerAMETEK,INC.,CHEMICALPRODUCTSDIVISIONHAVEGSITEMSDS#17DatePrinted08/28/01900GreenbankRoadWilmington,DELAWARE19808Description24HOUREMERGENCYASSISTANCE:CHEMTREC(800)424-9300PhoneProductInformation(302)995-0400RevisionDateOctober19,2000NoHazardRatingisavailableforthisProduct2.CompositionandInformationonIngredientsIngredient(s)Phenol-FormaldehydeResinPhenol(Free)Formaldehyde(Free)EthylAlcohol3.HazardIdentificationEmergencyOverview:CASNumber9003354108-95-250-00-064-17-5Percent(W/W)ProprietaryInformation9.00.8ProprietaryInformationReddish-brown,lowviscosityliquidwithcharacteristicphenolicresinodor.Keepcontainertightlyclosedwhennotinuseanddonotbreathevaporsunnecessarily.Donotallowthisproducttocomeincontactwithstrongmineralacids,suchassulfuricorhydrochloricacids,inordertopreventdangerofviolentexothermoccurring.EffectsofOverexposure:EyeContact:Vaporsmaybeirritatingtotheeyes.MaterialSafetyDataSheetProduct:Haveg4801PhenolicResinMSDS#17Page2of6SkinContact:Maybeirritatingtotheskin,andrepeatedcontactwiththeskinmaycausedermatitisinsensitiveindividuals.Inhalation:Vaporsmaybeirritatingtotherespiratorytract.Ingestion:Phenol(free)ishighlytoxicbyingestion.CarcinogenicityInformation:FormaldehydePOTENTIALCANCERHAZARD(A2)Basedonanimaldataandlimitedepidemiologicalevidence,NTPandIARChavelistedformaldehydeasaprobablehumancarcinogen.OSHAregulatesformaldehydeasapotentialhumancarcinogen.Maycauseallergicskinreaction.Somereportssuggestthatformaldehydemaycauserespiratorysensitization,suchasasthma.PhenolCancauseliver,kidney,bladder,andcardiacdamage.Pre-existingheartorcirculatorydisordersmaybeaggravatedbyexposure.ThismaterialhasnotbeenlistedbyNTP,classifiedbyIARC,norregulatedbyOSHAasacarcinogen(A4)Primaryroutesofentry:Skinandeyecontact,inhalationandingestion.4.FirstAidInformationEyeContact:Flusheyeswithlargeamountsofwaterforatleast15minutes,thenseekmedicalattention.SkinContact:Removecontaminatedclothing.Washskinwithmildsoapandcoolwater.Inhalation:Removepersonfromsourceofexposuretofreshair,thenseekmedicalattentionimmediately.Ingestion:Seekmedicalattentionimmediately.5.FireFightingMeasuresFlashPoint:210F,ASTMMethod,D93(PMCC)LowerExplosiveLimit(%):N.D..UpperExplosiveLimit(%):N.D.AutoignitionTemperature:N.D.ExtinguishingMedia:Usewater,drychemical,orcarbondioxide.2MaterialSafetyDataSheetProduct:Haveg4801PhenolicResinMSDS#17Page3of6UnusualFire&ExplosionHazards:Duringafire,freephenolandfreeformaldehydemaybereleasedaswellastheircombustionproducts,andcarbonmonoxideand/orcarbondioxide.FireFightingInstructions:Wearfullfirefightingprotectiveequipmentincludingself-containedbreathingapparatus.6.AccidentalReleaseMeasuresStepstobetakenincasematerialisreleasedorspilled:1.Coversmallspillswithsandorothernon-combustibleabsorbent.Donotallowspilledmaterialtoenterwaterwayasphenolicresinmaybeleachedout.2.Disposeofallwastematerialsinaccordancewithallapplicablefederal,state,andlocalenvironmentalregulations.7.HandlingandStorageHandling:1.Avoidskincontact.Handlewithcare.2.Handleinwell-ventilatedarea.3.Usesafetyglasseswithsideshieldsandimperviousgloveswheneverhandlingthismaterial.StorageStorematerialinclosedcontainers,preferablyat35F,tomaintainmaximumshelflife.8.ExposureControlsandPersonalProtectionENGINEERINGCONTROLS:Ventilation:Generalventilationand/orlocalexhaustventilationaswellasprocessisolationmaybeusedtominimizeemployeeexposureandmaintainexposuresbelowtheTLV.RespiratoryProtection:UseNIOSHapprovedfullface-piecerespiratoryprotectionequipmentwhereaircontaminantsexceedacceptablecriteria.EyeProtection:Wearsafetyglasseswithsideshields,orchemicalsplashgoggles.ProtectiveClothing:Wearprotective(impervious)glovesasrequiredtopreventskincontact.Fullbodyprotectiveclothingshouldbewornintheeventofaspillorotheremergency.OtherProtectiveEquipment:Eyewashfountain,safetyshower3HygienicPractices:UsegoodhygienicpracticesMaterialSafetyDataSheetProduct:Haveg4801PhenolicResinEXPOSURELIMITS:OSHA(PEL)ACGIHPhenolicResinN.E.N.E.MSDS#17Page4of6NOTATIONSPhenol(Free)Formaldehyde(Free)EthylAlcohol9.PhysicalandChemicalPropertiesPHYSICALDATA:BoilingPoint:205°FMeltingPoint:N.A.SolubilityinWater:SlightlysolubleVaporPressure:N.D.VaporDensity:N.D.SpecificGravity:1.18pH:6.9-7.1Color:Reddish-brownOdor:CharacteristicphenolicresinodorPhysicalState:Lowviscosityliquid10.StabilityandReactivity5ppm(skin)0.75ppmSTEL2ppm1,000ppm5ppm(skin)(C)0.3ppmA21,000ppmChemicalStability–Productisstableatnormaltemperaturesandstorageconditions,butwillpolymerizeathightemperatureswithsomeevolutionofheat.Incompatibilities–Strongmineralacidssuchassulfuricorhydrochloricacid,oxidizers.HazardousPolymerization:Hazardouspolymerizationwillnotoccurundernormalconditions.HazardousDecompositionProducts:Duringdecomposition,freephenolandfreeformaldehydemaybereleasedaswellastheirdecompositionproducts,andcarbonmonoxideand/orcarbondioxideandotherunidentifiedorganiccompounds.11.ToxicologicalInform