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(333332):,:CLO2,67.45,-59,11,,253.01G/L,5,9,2.61811HumphreyDavey,,,,2090,,11.11.1.11.1.1.1(1)R5(KESTING):HCINaClO3CA(CLO3)2,ClO2NaCI,NaClO332%,,,,C1O2,ClO2,Cl2NaClO3:NaClO3+2HCIClO2+0.5Cl2+NaCl+H2ONaClO3+6HCI3Cl2+NaCl+3H2ONaClNaClO3,NaClCl2,,ClO287%,,,,,NaClO3Ca(ClO3)2NaClO3,,CaCl2NaClCa(ClO3)2+4HCl2ClO2+Cl2+CaCl2+2H2O(2)R6(Chemetics)Inte-grated,ClO2,HCl,,Cl2ClO29,,ClO2Cl2,:,,Cl2,,NaClO3,,,,:HClNaClO3,,,,,,1-2h,(3)R72080,R6,Cl2,,,:2NaClO3+2HCl+H2S4O2ClO2+Cl2+2H2O+Na2SO4Cl2+SO2+2H2O2HCl+H2SO4:2NaClO3+SO22ClO2+Na2SO4(4)(Mathienson)(R1)1320073©1994-2008ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.:Cl2=1020SO2,8mol/l,,Cl2,,ClO2,Na2SO4,NaHSO4H2O,,Cl2,Na2SO48.5g/l,NaClO3260g/l,1ONaClO3ClO2,Cl2SO2,SO2,Cl2,ClO2,90%SO2NaCl,NaClO3520%NaCl,ClO29597%ClO2,,,,,H2SO4,0NaHSO4H2O(5)R2NaCINaClO3NaClO3NaCl1:1.05,98%H2SO43555,ClO2Cl2,ClO2,,ClO2,Cl2(1213%)Cl2,NaClO,Na2SO4H2SO4,NaClNaClO3,:NaClO3+NaCl+H2SO4ClO2+0.5Cl2+H2O+Na2SO4,,1KgClO298%H2SO41.5KgR2,,,H2SO4,,Cl21/3,Na2SO4,Cl2ClO22NaClO2+Cl22ClO2+2NaCICl2+2H2O+CH3OH6Cl-+CO2+6H+Cl2+2H2O+SO2H2SO4+2HCl,,,,,R2R3R3HR5SVPNa2SO4(6)CH3OHNaClO3CH3OHCl2,,,,,A:(Solvay)(101.325KPa),,NaClO3,ClO2,,:6NaClO3+CH3OH+6H2SO4CO2+6ClO2+5H2O+6NaHSO4ClO2HCHOH2SO4ClO2,Cl2,7mol/1NaClO35mol/lNaCl,,ClO21tClO20.15CH3OHCH3OH,,,Cl-H2SO4R81985,SolvayR3SVPL-LITE,NaClO3CH3OHNaCl()ClO2,70,13.32KPa45mol/l,NaClO3CH3OH4:1,,ClO2,ClO2,ClO28-10g/l,99100%,:30NAClO3+12CH3OH+2OH2SO4CO2+30ClO2+23H2O+10Na3H(SO4)2:12NaClO3+6CH3OH+8H2SO46CO2+6ClO2+18H2O+4Na3H(SO4)2+3Cl2R8ClO-3ClO2,96100%,,,Cl22320071©1994-2008ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(7)A:HJL,,ClO2,48NaClO3+Cl2H22O11+20H2SO448ClO2+12CO2+24Na2SO4+35H2ONaClO3H2SO4(:NaClO3=48:1.1),90,5mol/l,30ClO2ClO2,0ClO2,95%,94%,CO2ClO2,,,,ClO2B:2NaClO3+H2C2O4+20H2SO42ClO2+2CO2+2NaHSO4+2H2O90NaClO3:H2SO4=2:1.1,4.2mol/l,92.5%,ClO298%1.1.1.2(1)Hicks2NaClO2+Cl22ClO2+2NaClCl2200300%,,HClO,HClONaClO2ClO2,Cl2,(2)CCV5NaClO2+4HCl4ClO2+5NaCl+2H2O5ClO2-4ClO2,ClO2-Cl-,(3)Rapson10NaClO2+5H2SO48ClO2+4H2O+5Na2SO4+2HCl(4)CO25NaClO2+2H2O+4CO24ClO2+4NaHCO3+NaCl,NaClO285%,(5)ECFNaClO2+H2OClO2+0.5H2+NaOHECFClO2ClO2,98.4%,NaClO2,(6)2NaClO2+Na2S2O82ClO2+2Na2SO4,(KyroChem)NaClO2Na2S2O8,C1O2ClO2,,,,ClO2,1.1.2,ClO2,,,ClO2TetravalentClO2,,,,,ClO21.2ClO2,ClO2ClO2ClO2,,ClO2ClO2,ClO2,,ClO2,ClO22.0%ClO2,ClO2,ClO23320073©1994-2008ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[1],.,,1994(5),52-53[2].,,1994.14(3),7-9[3].,,1995(3),22-23[4].,,1994(8),42-43[5],2002,43(1)[6].CN:1196881A,1998.[7],,.CN:1075298A,1993.[8],.CN:1266017A,2000.[9].CN:1175350A,1998.[10].,,1991(1),33-36[11],,.CN:1215552A,1999.[12],.CN:1310941A,2001.[13],,.CN:1261051A,2000.[14].,2001,(1)[15].[J],,1998,(2):85-87.[16].[J],1997(10):6.[17],,,.[J].,1996.[18].[J].,1997.[19].[J].,2002,43(1):4649.[20],[J].,1996,(1):9-11.[21],,.[M].:,1999.[22],,,[M].:,1996.59.[23].[J],1997,(3):45-47.[24],,.[J].[25],,.[J].,2001,2l(3):256-258.[26].[J].,1989,6(1):1-3.4320071©1994-2008ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.