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28520095FENXICESHIXUEBAO(JournalofInstrumentalAnalysis)Vol128No15627632:2008-12-20;:2009-01-15:(200311):(1961-),,,,,Tel:0311-86269376,E-mail:qiuqingyang@sina1com,(,050016):,,,(NMR),/,:;;;;;:O4821532;TQ423:A:1004-4957(2009)05-0627-06doi:1013969/j1issn11004-4957120091051028ProgressinNuclearMagneticResonanceSpectroscopyTechniquesforMixedSurfactantMicellarSystemYANGQiu2qing,HANYa2nan(ExperimentalCenter,HebeiNormalUniversity,Shijiazhuang050016,China)Abstract:Mixedsystemsofsurfactantsarewidelyusedinmanybiologicalandindustrialprocessesbecauseoftheirsynergisticperformance.Inrecentyears,avarietyofnuclearmagneticresonancespectroscopy(NMR)techniqueshavebeensuccessfullyusedinthestudyofdynamicprocessesofthemicellaraggregationinmixedsystemsofsurfactantsaswellastheeffectsofsurfactantinteractiononmixedmicellization.NMRtechniquescanprovideawealthofmolecularlevelinformationthatcannotbeobtainedbyotherspectroscopicmethods.Inthisreport,therecentprogressintheapplicationsofNMRtechniques,includingthechemicalshiftchanges,self2diffusioncoefficient,relaxationtimeandtwo2dimentionalnuclearoverhausereffect(NOE)formixedsurfactantmicellesarereviewed,andtheprospectsofNMRtechniquesforthestudyofmixedsurfactantmicellesystemareoutlined.Keywords:NMR;surfactant;mixedmicellarsystem;diffusioncoefficient;relaxationtime;review(NMR),,[1-2]NMR,,NOE1970[3],NMR[4],,,,,,-NMR11H111,1H,28,1H,,,,(CTAB)TritonX2100,,,TritonX2100,,TritonX2100[5](SDS)(TPPOC3Py),SDS,SDS,[6],1H(cmc)[7-8]1H(),cmc2cmc1cmc2:1/c(cmc)=1/c(cmc1)+1-1/c(cmc2)(11)cmc[9-10]1H19F,(SANS)NMR,,,1H,13C31P19F35Cl81Br133Cs,[11-16]NMR,(T2),V(v)1/2=1/(T2),T2,,,,14N35Cl23Na,[17],,(10-9s),,(DLB)[18-19],,,,-,[20]112,,(PFG),,,[21-23],[24](D)Dexp=PmicDmic+(1-Pmic)DfreeDexp=Dmic+[c(cmc)/c](Dfree-Dmic)Dexp,DmicDfree,Pmic,c(cmc)c,,[25]22n2(C8E5)(PAA)(-C8E5)(-C8E5-PAA),,,,,,[26],,,,(CORE),,8265:[27]Johnson[28](2DNMR)FT-PFG,DOSY(diffusionor2deredspectroscopy),x,y,DOSYFT-PFG,,FT-PFGSDS,,DOSY(DM)(DTAC),DDM-DTACDTAC,DMDTAC18110,,18,DTAC[29]DOSY262C[30],(EHEC)SDS,(),SDS[31],EHECNMR,,Na+,SDS-,SDSNa+[32],,,,,NMR[33],NMR,[34],NMR113,,2:-(T1),,-(T2),T2/T11,,,,T2,,,(DM)(DTAC)Gemini12-4-12Gemini12-8-123(DM/DTACDM/12-4-12DM/12-8-12)181614,,,,3,DM[29,35-36],DM2,DMGemini,22,,NMRGemini[37-41]m-s-mGemini,,,[42-43];,s,[44][45];Gemini,,[46]SDS/TX2100(TritonX2100),T1T2T2/T1,SDS92628[47],TX2100,SDSTX2100TX2100cmc,,10cmc,TX2100,T2/T1=011[48],T2/T1,TritonX2100,SDS-NP100SDS-PVPNP100-PVP3,SDSSDS-PVPSDS-NP100,SDSPVP;SDSNP100:SDS,NP100;NP100PVP,[49],1H2H14N13C35Cl[50-52]2HCTAB,,;,;,,[53]-(T2),,(2D)NOESYHOESY2NOESYHOESYNOE(nuclearoverhausereffect),NOE,,RA=RB(IB/IA)1/6(RARBAB,IAIB),015nm2DNOESY(1H-1H),2DHOESY(1H-13C)1H13C,HOESY,013014nm;1H-19FHOESY,1CH2012nm,ns[54],2DNOESY,,2DNOESY,NOE42(SDNS)-TX2100SDNS-(SDSN)2,:SDNS-TX2100,TX2100SDNS,,TX2100,SDNS;SDNS-SDSN,SDSNSDNS,SDNSSDSN0127nm,SDNS0146nm,SDSN[55];,(C162AMP)(C162UMP),2DNOE2SY2[56],,,(C162AMP/C162UMP)(AOT)[57],AOT-CCl4AOT-C6D6[58],AOT,AOT,NOEAOT2,AOT2(22),2AOT,22DNOESY-,0365:[59](PEO)SDS,SDS,PEOSDS,015nm,NOESY,PEOPEO-SDS1040NOESY,2025,PEO,,40PEOSDS(PVP)-SDS,2,SDSNO,SDS[60]2DNOESY2DHOESY,TX2100,,,[61],HOESYTX2100(PEG)-SDS,,PEG,PEGSDS/H2O,PEGSDS;NOESYPEGSDS,(cmc)(cac),PEGSDS,,,PEG[62]-(2DHOESY),2,2H13C15N,,-,NMR,[63]2DNOE,,,2DNOESY,,NMR,100,1DNMR[64-65]3,,,,NMR,,,2DNOESY,,NMR3DNMR,NMR,,,:[1]YANGJiping,DINGYan,CHENGong,etal.[J].EurPolymJ,2007,43:3337-3343.[2]WENXiaoyan,HEHongping,ZHUJianxi,etal.[J].JColloidInterfSci,2006,299:754-760.[3]ISTVANF.[J].JMolecularLiquids,2005,117:117-137.[4]DUYouru,ZHAOSui,SHENLianfang.[J].RepNMRSpectro,2002,48:145-189.[5]YUANHanzhen,ZHAOSui,CHENGGongzhen.[J].JPhysChem:B,2001,105:4611-4615.[6]QIUWenge,LIZongfeng,BAIGuangmei,etal.[J].JSpectrochimActa:A,2007,68:1164-1169.[7]LUPunchao,CAOAoneng,LILuhua,etal.[J].ColloidsSurf:A,2007,292:279-284.[8]ALEISHAAM,GERRARDMD.[J].JColloidInterfSci,2006,295:243-248.[9]AMATOME,CAPONETTIE.[J].JPhysChem:B,2003,107:10048-10056.13628[10]ESUMIK,SHOJIK,TORIGOEK.[J].ColloidSurfA,2001,183:739-748.[11]BASTARDOLA,IRUTHAVARAJJ,LUNDINM,etal.[J].JColloidInterfSci,2007,312:21-33.[12]VERMATHENM,STILESP,BACHOFERSJ.[J].Langmuir,2002,18:1030-1042.[13]IIJIMAH,KATOT,SODERMANO.[J].Langmuir,2000,16:318-323.[14]CABIOF,CHITTOFRATIA,IAZARRIP,etal.[J].ColloidsSurf:A,1999,160:47-56.[15]BOSSEVDP,MATSUMOTOM,NAKAHARAM.[J].JPhysChem:B,1999,103:8251-8258.[16]BOSSEVDP,MATSUMONOM,SATOT,etal.[J].JPhysChem:B,1999,103:8259-8266.[17]PROFIOPD,SAVELLIR,CERICELLIG.[J].Langmuir,1998,14:2662-2669.[18]WANGLP,WONGTC.[J].JPhysChem,1988,92:4753-4758.[19]WONGTC,WANGLP.[J].JPhysChem,1989,93:1295-1302.[20]CRISTIANOAD,SERGIOL,JOSEJC,etal.[J].JColloidInterfSci,2007,316:31-36.[21]XINGHang,LINShrongshi,LURunchao,etal.[J].ColloidsSurf:A,2008,318:199-205.[22]JAVADIANS,GHARIBIH,SOHRABIB,etal.[J].JMolLiq,2008,137:74-79.[23]GAIKARVG,PADALKAIKV,ASWALVK.[J].JMolLiq,2008,138:155-167.[24]BENMM,MAGDASSIS,COHENY,etal.[J].JColloidInterfSci,2004,276:221-226.[25]GHARIBIH,JAVADIANS,SOHRABIB,etal.[J].JColloidInterfSci,2005,285:351-359.[26]GERARDINODE,DONATOC,ORNWLLAO,etal.[J].JColloidInterfS