硅太阳能电池用铝浆的现状和发展趋势

17420108MetallicFunctionalMaterialsVol.17,No.4August,2010张红斌1,赵玲1,熊庆丰1,乔威2(1,650106;2,650033):,,,:;;;:TM91441:A:1005-8192(2010)04-0072-04RecentSituationandDevelopmentTrendsofAluminumPasteforSiliconSolarCellsZHANGHongbin1,ZHAOLing1,XIONGQingfeng1,QIAOWei2(1KunmingInstituteofPreciousMetals,Kunming650106,Yunnan,China;2YunnanTiandaPhotovoltaicCoLtd.,Kunming650033,Yunnan,China)Abstract:Siliconsolarcellisapollutionfreeandhighsupplyproducts.Itisthroughthephotoelectricconversiontoobtainelectricpowerfromsolarenergy,andiswidelyusedinavarietyoflightingandpowergenerationsystemsInthispaper,thealuminumpasteforsiliconsolarcellswerereviewedintermsofcomposition,roleandpreparationmethodswhichhaveanimportantimpactonthesiliconsolarcellTherecentsituationandthedevelopmenttendencyofaluminumpasteforsiliconsolarcellsarealsostudiedKeywords:solarcell;aluminumpaste;recentsituation;developmenttendency:(1980-),,,,Tel:[phone];Email:zhhb610527@163com,,,,,;;,,[1~3],P(n)()PNPN,,PN,NP,PN,,PN,,,P+/P,,,,,(VOC)(ff),[4]1,,FerroCN1877864A,,,,;170%[5]US2006/1289055A1[6],,,,,Ni,Al,Zn,Sb,,(BSF),,,,,,,l0%,,,,,,,MohamedMHilali[7],,,,,,,,,,,[8],[9],,,,[10],,,PN,,,,,3,,p+,,2,,,734:,10~20cm,,(30cm30cm),,,,,,:;;;;,,:;;;;;,,,244%3PbO:,,,,PbO,,,!,,,,ROHSREACH,,,,,,,,,3∀#,!20,/kWh25/kWh,(PV),4/kWh,,(,),,,,,,,,∃∃∃;:[1],,,.[J].,2006(2):52~56.[2],,,.[J].,2006,34(9):37~39.[3],.[J].,2008,15(1):48~52.[4]VichaiMeemongkolkiat,KentaNakayashiki,etc.FactorsLimitingtheFormationofUniformandThickAluminumBackSurfaceFieldandItsPotential[J].JElectrochemicalSociety,2006,153(1):G53~G58.[5],.[P].:1877864A,2006-06-30.[6]SrinivasanSridharan,Strongsville,etc.LEADFREESOLARCELLCONTACTS[P].USPatent,2006/1289055A1,2006-12~28.(44)742010,140%,Fe3O4;200%,Fe3O4336%3Fe3O4,(PEI),,Fe3O4:Fe3O4,Fe3O4,Fe3O4,:[1].[M].:,2003,280~343.[2].[M].:,2008,20.[3]ZhangChun,etal.Polyethyleniminestrategiesforplasmiddeliverytobrainderivedcells[J].Methods,2004,33:144~150.[4]CarolaBrus,etal.Efficiencyofpolyethyleniminesandpolyethyleniminegraftpoly(ethyleneglycol)blockcopolymerstoprotectoligonucleotidesagainstenzymaticdegradation[J].EuropeanJournalofPharmaceuticsandBiopharmaceutics,2004,57:427~430.[5]OgrisM,etal.Tumortargetedgenetherapy:strategiesforthepreparationofligandpolyethyleneglycolpolyethylenimine/DNAcomplexes[J].JControlRelease,2003,91(122):173~181.[6]LungwitzU,etal.Polyethyleniminebasednonviralgenedeliverysystems[J].EuropeanJournalofPharmaceuticsandBiopharmaceutics,2005,60(2):247~266.[7]LeeWenJiung,FangTsangTse.Theeffectofthemolarratioofcationsandcitricacidonthesynthesisofbariumferriteusingacitrateprocess[J].JourmalofMaterialsScience,1995,30(17):4349~4354.[8]KaitoC,etal.Novelmethodforproducingultrafineoxidegrainsfrommetallicparticles[J].JournalofAppliedPhysics,1996,35,9(A):4736~4737.[9]FanR,ChenXH.AnewsimplehydrothermalpreparationofnanocrystallinemagnetiteFe3O4[J].MaterialsResearchBulletin,2001,36(3-4):497~502.[10]ZhouZX,etal.Compositeofpolyanilinecontainingironoxideswithnanometersize[J].SyntheticMetals,1996,78(1):27~31.[11]PENGJian,etal.PreparationandcharacterizationofPEGPEI/Fe3O4nanomagneticfluidbycoprecipitationmethod[J].TransactionsofNonferrousMetalsSocietyofChina,2008,18:393~398.[12]YamauraM,etal.Preparationandcharacterizationof(3aminopropyl)triethoxysilanecoatedmagnetitenanoparticles[J].JournalofMagnetismandMagneticMaterials,2004,279:210~217.[13]AmynS.Synthesis,propertiesandapplicationsofmagneticironoxidenanoparticles[J].ProgressinCrystalGrowthandCharacterizationofMaterials,2009,55:22~45.:2009-08-14(74)[7]MohamedM.Hilali,JamesM.Gee,PeterHacke.Bowinscreenprintedbackcontactindustrialsiliconsolarcells.[J].SolarEnergyMaterials&SolarCells,2007,91:1228~1233.[8].[J].,1997,16(2):47~49.[9],,,.[J].,2003,22(11):40~43.[10],.[A].∃∃∃2007()[C].2007.:2009-07-20442010