1Unit1ChemicalIndustry化学工业1.OriginsoftheChemicalIndustryAlthoughtheuseofchemicalsdatesbacktotheancientcivilizations,theevolutionofwhatweknowasthemodernchemicalindustrystartedmuchmorerecently.ItmaybeconsideredtohavebegunduringtheIndustrialRevolution,about1800,anddevelopedtoprovidechemicalsroeusebyotherindustries.Examplesarealkaliforsoapmaking,bleachingpowderforcotton,andsilicaandsodiumcarbonateforglassmaking.Itwillbenotedthattheseareallinorganicchemicals.Theorganicchemicalsindustrystartedinthe1860swiththeexploitationofWilliamHenryPerkin’sdiscoveryifthefirstsyntheticdyestuff—mauve.AtthestartofthetwentiethcenturytheemphasisonresearchontheappliedaspectsofchemistryinGermanyhadpaidoffhandsomely,andby1914hadresultedintheGermanchemicalindustryhaving75%oftheworldmarketinchemicals.ThiswasbasedonthediscoveryofnewdyestuffsplusthedevelopmentofboththecontactprocessforsulphuricacidandtheHaberprocessforammonia.Thelaterrequiredamajortechnologicalbreakthroughthatofbeingabletocarryoutchemicalreactionsunderconditionsofveryhighpressureforthefirsttime.TheexperiencegainedwiththiswastostandGermanyingoodstead,particularlywiththerapidlyincreaseddemandfornitrogen-basedcompounds(ammoniumsaltsforfertilizersandnitricacidforexplosivesmanufacture)withtheoutbreakofworldwarⅠin1914.Thisinitiatedprofoundchangeswhichcontinuedduringtheinter-waryears(1918-1939).1.化学工业的起源尽管化学品的使用可以追溯到古代文明时代,我们所谓的现代化学工业的发展却是非常近代(才开始的)。可以认为它起源于工业革命其间,大约在1800年,并发展成为为其它工业部门提供化学原料的产业。比如制肥皂所用的碱,棉布生产所用的漂白粉,玻璃制造业所用的硅及Na2CO3.我们会注意到所有这些都是无机物。有机化学工业的开始是在十九世纪六十年代以WilliamHenryPerkin发现第一种合成染料—苯胺紫并加以开发利用为标志的。20世纪初,德国花费大量资金用于实用化学方面的重点研究,到1914年,德国的化学工业在世界化学产品市场上占有75%的份额。这要归因于新染料的发现以及硫酸的接触法生产和氨的哈伯生产工艺的发展。而后者需要较大的技术突破使得化学反应第一次可以在非常高的压力条件下进行。这方面所取得的成绩对德国很有帮助。特别是由于1914年第一次世界大仗的爆发,对以氮为基础的化合物的需求飞速增长。这种深刻的改变一直持续到战后(1918-1939)。datebaketo/from:回溯到dated:过时的,陈旧的standsb.ingoodstead:对。。。很有帮助Since1940thechemicalindustryhasgrownataremarkablerate,althoughthishasslowedBeforereadingthetextbelow,trytoanswerfollowingquestion:1.Whendidthemodernchemicalindustrystart?2.Canyougiveadefinitionforthechemicalindustry?3.Whatarethecontributionwhichthechemicalindustryhasmadetomeetandsatisfyourneeds?4.Isthechemicalindustrycapital-orlabor-intensive?Why?2significantlyinrecentyears.Thelion’sshareofthisgrowthhasbeenintheorganicchemicalssectorduetothedevelopmentandgrowthofthepetrochemicalsareasince1950s.Theexplosivesgrowthinpetrochemicalsinthe1960sand1970swaslargelyduetotheenormousincreaseindemandforsyntheticpolymerssuchaspolyethylene,polypropylene,nylon,polyestersandepoxyresins.1940年以来,化学工业一直以引人注目的速度飞速发展。尽管这种发展的速度近年来已大大减慢。化学工业的发展由于1950年以来石油化学领域的研究和开发大部分在有机化学方面取得。石油化工在60年代和70年代的迅猛发展主要是由于人们对于合成高聚物如聚乙烯、聚丙烯、尼龙、聚脂和环氧树脂的需求巨大增加。Thechemicalindustrytodayisaverydiversesectorofmanufacturingindustry,withinwhichitplaysacentralrole.Itmakesthousandsofdifferentchemicalswhichthegeneralpubliconlyusuallyencounterasendorconsumerproducts.Theseproductsarepurchasedbecausetheyhavetherequiredpropertieswhichmakethemsuitableforsomeparticularapplication,e.g.anon-stickcoatingforpansoraweedkiller.Thuschemicalsareultimatelysoldfortheeffectsthattheyproduce.今天的化学工业已经是制造业中有着许多分支的部门,并且在制造业中起着核心的作用。它生产了数千种不同的化学产品,而人们通常只接触到终端产品或消费品。这些产品被购买是因为他们具有某些性质适合(人们)的一些特别的用途,例如,用于盆的不粘涂层或一种杀虫剂。这些化学产品归根到底是由于它们能产生的作用而被购买的。2.DefinitionoftheChemicalIndustryAttheturnofthecenturytherewouldhavebeenlittledifficultyindefiningwhatconstitutedthechemicalindustrysinceonlyaverylimitedrangeofproductswasmanufacturedandthesewereclearlychemicals,e.g.,alkali,sulphuricacid.Atpresent,however,manyintermediatestoproductsproduced,fromrawmaterialslikecrudeoilthrough(insomecases)manyintermediatestoproductswhichmaybeuseddirectlyasconsumergoods,orreadilyconvertedintothem.Thedifficultyconesindecidingatwhichpointinthissequencetheparticularoperationceasestobepartofthechemicalindustry’ssphereofactivities.Toconsideraspecificexampletoillustratethisdilemma,emulsionpaintsmaycontainpoly(vinylchloride)/poly(vinylacetate).Clearly,synthesisofvinylchloride(oracetate)anditspolymerizationarechemicalactivities.However,ifformulationandmixingofthepaint,includingthepolymer,iscarriedoutbyabranchofthemultinationalchemicalcompanywhichmanufacturedtheingredients,isthisstillpartofthechemicalindustryofdoesitmowbelonginthedecoratingindustry?2.化学工业的定义在本世纪初,要定义什么是化学工业是不太困难的,因为那时所生产的化学品是很有限的,而且是非常清楚的化学品,例如,烧碱,硫酸。然而现在有数千种化学产品被生产,从一些原料物质像用于制备许多的半成品的石油,到可以直接作为消费品或很容易转化为消费品的商品。困难在于如何决定在一些特殊的生产过程中哪一个环节不再属于化学工业的活动范畴。举一个特殊的例子来描述一下这种困境。乳剂漆含有聚氯乙烯/聚醋酸乙烯。显然,氯乙烯(或醋酸乙烯)的合成以及聚合是化学活动。然而,如果这种漆,包括高聚物,它的配制和混合是由一家制造配料的跨国化学公司完成的话,那它仍然是属于化学工业呢还是应当归属于装饰工业中去呢?Itisthereforeapparentthat,becauseofitsdiversityofoperationsandcloselinksinmany3areaswithotherindustries,thereisnosimpledefinitionofthechemicalindustry.Insteadeachofficialbodywhichcollectsandpublishesstatisticsonmanufacturingindustrywillhaveitsdefinitionastowhichoperationsareclassifiedasthechemicalindustry.Itisimportanttobearthisinmindwhencomparingstatisticalinformationwhichisderivedfromseveralsources.因此,很明显,由于化学工业经营的种类很多并在很多领域与其它工业有密切的联系,所以不能对它下一个简单的定义。相反的每一个收集和出版制造工业统计数据的官方机构都会对如何届定哪一类操