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Vol135No1614NEWCHEMICALMATERIALS35620076:(No.03120000800);:(1960-),,,,:(,450002),,,,,ProgressinfunctionandmechanismofsurfactantincontrollingofsizeandshapeofnanomaterialsWangPeiyiZhangXiaoliXuJiaqiang(CollegeofMaterialandChemistryEngineering,ZhengZhouUniversityofLightIndustry,Zhengzhou450002)AbstractThefunctionofsurfactantsincontrollingsizeandshapeofnanomaterialparticles,whicharetemplateac2tionanddispersionproperty,wereintroduced.Organizedsurfactantassembles,includingmicelles,reversemicelles,microe2mulsion,surfactantliquidcrystalandsurfactantvesiclesareintroducedandtheirmechanisminassistantformationofnano2materialsaresummarized.thedirectionofresearchofsurfactantincontrollingofsizeandshapeofnanomaterialsisviewed.Keywordsnanomaterial,controllingshape,surfactant,organizedassemble,mechanism,,,,,,;,,,,,,11.1(cmc),,,,21,(200),[13],,,2[4,5],,,,,,1.2,,,,,©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[1](CTAB),SnO2,CTABcmc0192mmol/L,CTAB20mmol/L,cmcCTABSn(OH)6-CTA+2Sn(OH)6-,[6],Sn(OH)6-CTAB,Sn(OH)6-,16012h,CTAB,CTABSnO2,,,Lee[7]Ag,CTAB(DTAB);,CTAB,Ag,DTABAg,CTABGao[8]CnTAB(n=1012141618):n=10121416,,,;n=18,C18TAB,Liu[9](SDBS)(SDS),80Te,24hTeTe,SDBSSDS10nm20nm2040nmSDBSSDS,,Te(001)SDS,SDSTe20nmSDBS10nm;,Te,(001)SDS212,,,,,Zhang[2]SDS(200,18h)SnO2,Sn(OH)6-,SnO2,SnO2,,,,,20018h,[3]AOT//CTAB//OP210//33CaCO3CaCO3,AOT,CaCl2,Ca2+AOT;Na2CO3,CO2-3CaCO3Pinna[10]AOT//CdS,Cason[11]AOTRuitaoLv[12]AOTZnS,,,ZnS,AOT,,,CTAB,Ca2+,CaCl2CTAB,Na2CO3,CaCO3,,,,CaCO3OP2l0,CaCO3,OP210(PEO),PEO,;,2,Ca2+CO2-32,2.3,1020nm,W/OO/W3,,W/OSong[4]51©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[13]K12AESABS,SnO2,SnO2Xu[5]trixon2100(9)(NP9)tween280SnO2,810SnO2Liu[14]NP5NP9OP210SnO2,820SnO2.,;,,,,;,,,,,Zhang[15]CTAB22,30nm3mZnO,,2.4,,,,,[16]AOT2,Hotz[17],,,,/[18],,,Hubert[19]SiO2,150nm2.5,2,2:[20,21][22],Ryoo[23],,Braun[24]CdS,3nmCdS,5nmCdS,20100nmCdS3,CdS,CdSZnSCdS,,CuSHgSPbS,3(),,,,,,,[1]GuoCX,CaoMH,HuCW.Anovelandlow2temperationhydrothermalsynthesisofSnO2nanorod[J].InorganicChem2istryCommunication,2004,7:9292931.[2]ZhangDF,SunLD,Yin.JL,etal.Low2Temperaturefabri2cationofhighlycrystallineSnO2nanorod[J].AdvMater,2003,15,(12).[3],,.CaCO3[J].,2005,2(2l):1.[4]SongKC,KimJH.Preparationofnanosizetinoxideparticlesfromwater2in2oilmicroemulsions[J].JournalofColloidandIn2terfaceScience,1999,212(1):1932196.[5]XuCK,ZhaoXL,LiuS,etal.Large2scalesynthesisofrutileSnO2nanorods[J].SolidStateCommunication,2003,125:3012304.[6],,.[M]..:,2004.8:4312432.[7]LeeGJ,ShinS,KimYC.PreparationofsilvernanorodsthroughthecontroloftemperatureandpHofreactionmedium[J].MaterialsChemistryandPhysics,2004,84(223):1972204.[8]GaoJX,BenderCM.MurphyCJ.Dependenceofthegoldnanorodaspectratioonthenatureofthedirectingsurfactantinaqueoussolution[J].Langmuir,2003,19(21):906529070.(26)61©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[4]2(1)(2)(S2BPUIR2BPUI),:5h100,BINOLTDI(2)R2BPUIS2BPUI+4515-4014,(3)S2BPUIR2BPUI2591325116,2991530616,(4)011808012445dL/g,[1]JinLiu,DezhuMa.Studyonsynthesisandthermalpropertiesofpolyurethane2imidecopolymerswithmultiplehardsegments[J].JournalofAppliedPolymerScience,2002,84(12):220622215.[2]HamidYeganeh3,MohammadAminShamekhi.Poly(ure2thane2imide2imide),anewgenerationofthermoplasticpolyure2thaneelastomerswithenhancedthermalstability[J].Polymer,2004,45(2):3592365.[3]MallakpourS,RafiemanzelatF.Synthesisandpropertiesofno2velopticallyactivepoly(amide2imide2urethane)thermoplastice2lastomersbythereactionofaL2leucinebaseddiacidchainex2tenderandPEG2terminatedMDI[J].IranianPolymerJournal,2005,14(2):1692180.[4]MallakpourS.RafiemanzelatF,Studyofthemiscibilityofhardandsoftsegmentsofopticallyactivepoly(amide2imide2ether2u2rethane)copolymersbased2L2leucinewithdifferentsoftseg2ments[J].PolymerBulletin,2006,56(1):9218.[5],,.[J].(),1997,37(12):37239.[6].[M].,2002:12217.[7],,.[M].,2004,1:1932196.[8],,.2,2221,12[J].,2005,26(7):126821272.[9]AijunGong,WeihongLiu,YongmingChen,etal.Opticallyac2tivecyclicandlinearpoly(arylesters)basedonchiral1,12bi222naphthol[J].Tetrahedron:Asymmetry,1999,10:207922086.[10]AijunGong,YongmingChen,ZhangXi,etal.Opticallyactivecyclicpoly(ethersulfone)sbasedonchiral1,12bi222naphthol[J].Tetrahedron:Asymmetry,1998,9:417524181.:2005212212(16)[9]LiuZP,HuZK,LiangJB,etal.Size2controlledsynthesisandgrowthmechanismofmonodispersetelluriumnanorodsbyasurfactant2assistedmethod[J].Langmuir,2004,20(1):2142218.[10]PinnaN,WeissK,Sack2KongehlH,etal.TriangularCdSnanocrystals:synthesis,characterization,andstability[J].Langmuir,2001,17:798227987.[11]JoannaPC,MichaelEM,JasonBT,etal.SolventeffectsoncoppernanoparticlegrowthbehaviorinAOTreversemicelleSystems[J].PhysChemB,2001,105(12):229722302.[12]RuitaoLv,CaoCB,ZhuHS.SynthesisandcharacterizationofZnSnanowiresbyAOTmicelle2templateinducingreaction[J].MaterResBul,2004,39(10):151721524.[13],,.SnO2[J].,1999.2,vol:14.[14